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有机化学
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有机化学 ›› 1991, Vol. 11 ›› Issue (4): 420-425. 上一篇    下一篇

研究论文

O-芳基苯基硫代膦酰肼与某些羧基化合物的反应

金桂玉;李云鹏;倪音海   

  1. 南开大学元素有机化学研究所
  • 发布日期:1991-08-25

Reaction of aryloxyphenylthiophosphonyl hydrazine with some carbonyl compounds

JIN GUIYU;LI YUNPENG;NI YINHAI   

  • Published:1991-08-25

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本文报道了O-芳基苯基硫代膦酰肼与几种羧基化合物α-(1,2,4三唑基)片呐酮、邻苯二甲酰氯, 反式菊酰氯和原甲酸三乙酯的反应, 合成了21个新的硫代膦酰肼衍生物。

关键词: 反应机理, 酰氯 P, 磷酰化合物, 有机硫化合物, 原酸酯, 羰基化合物, 酰肼 P

Reaction of the title compounds ROP(S)PhNHNH2 [R = (un)substituted Ph] with tri-Et orthoformate, a-(1,2,4-triazol-1-yl)pinacoline, phthaloyl chloride, and trans-chrysanthemic acid afforded condensation products, e.g., I, ROP(S)PhNHN:CHOEt. The spectra of these compounds were discussed and the biol. activities of some compounds were tested.

Key words: PHOSPHORYL COMPOUNDS, REACTION MECHANISM, ORGANO SULFUR COMPOUNDS, ACYL CHLORIDES P, ORTHO-ESTER, CARBONYL COMPOUNDS, HYDRAZIDE P

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