SIOC English
有机化学
高级检索

有机化学 ›› 1997, Vol. 17 ›› Issue (4): 344-348. 上一篇    下一篇

研究论文

α-羟基二茂铁类衍生物的合成及其晶体结构

王积涛;冯霄;李月明;姚晓杰;唐良富   

  1. 南开大学化学系
  • 发布日期:1997-08-25

Synthesis and crystal structure of derivatives of α-hydroxylferrocene

WANG JITAO;FENG XIAO;LI YUEMING;YAO XIAOJIE;TANG LIANGFU   

  • Published:1997-08-25

被引次数

7

通过甲酰基二茂铁与苯乙酮，硝基甲烷及丙酮的缩合反应，我们制得了其缩合产物-α-羟基-β-羰基化合物。并对甲酰基二茂铁与苯乙酮的缩合产物进行了X射线单晶结构分析。结果表明：该晶体属于单斜晶系，空间群为P 2~1/n，a=0.6022(1)，b=2.735(1)，c=0.9416(1)nm，β=99.02(1)°，V=1.532(1)(nm)^3，Mr=334.20，Z=4，Dx=1.45g/cm^3，μ=9.68cm^-^1，F(000)=696。

关键词: 硝基化合物, 结构分析, 缩合反应, 甲酰基, 环糊精, 甲烷 P, 丙酮, 有机物晶体结构, 有机合成, 羟基化合物

Three compounds were synthesized and characterized by elemental analysis, IR spectra and ^1H NMR spectra. The crystal and molecular structures of C~1~9H~1~8FeO~2 were determinded by single-crystal X-ray diffraction. The unit-cell is monoclinic, space group P 2~1/n with a=0.6022(1), b=2.735(1), c=0.9416(1)nm, β=99.02(1)°, V=1.532(1)(nm)^3, Mr=334.20, Z=4, Dx=1.45g/cm^3, μ=9.68cm^-^1, F(000)=696.

Key words: METHANE P, CYCLODEXTRIN, FORMYL, CRYSTAL STRUCTURE OF ORGANIC SUBSTANCE, HYDROXYL COMPOUNDS, ACETONE, ORGANIC SYNTHESIS, CONDENSATION REACTION, STRUCTURAL ANALYSIS, NITRO COMPOUNDS

中图分类号: