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有机化学
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有机化学 ›› 1998, Vol. 18 ›› Issue (2): 162-165. 上一篇    下一篇

研究论文

(Z)-1-[2-(二苯基碘化锡基)乙烯基]-1-环己醇的合成、晶体结构和性质

朱东升;戴慧聪;单希林;田来进;傅芳信;潘华德;邢彦;林永华   

  1. 东北师范大学化学系;中国科学院长春应用化学研究所;黑龙江省安达市大庆石油学院化工系
  • 发布日期:1998-04-25

Synthesis, crystal structure and properties of (Z)-1-[2- (bisphenyl-iodine-stannyl)vinyl]-1-cyclohexanol

ZHU DONGSHENG;DAI HUICONG;SHAN XILIN;TIAN LAIJIN;FU FANGXIN;PAN HUADE;XING YAN;LIN YONGHUA   

  • Published:1998-04-25

报道了标题化合物的合成、晶体结构及性质。该晶体属于单斜晶系，空间群为P2~1，晶胞参数a=0.9255(3)nm，b=1.0504(3)nm，c=1.0217(3)nm，β=100.99(2)°，V=0.9750nm^3，Z=2，D~c=1.790g/cm^3，R=0.025，晶体结构由直接法解出。标题化合物分子中的锡原子被配体的三个碳、一个碘和一个氧原子配位；配位原子是畸变的三角双锥构型；标题化合物具有与卤素发生取代反应而不发生加成反应的性质。

关键词: 二苯基烃, 晶体结构, 抗癌活性, 有机锡化合物, 有机合成, 环己醇 P, 乙烯基化合物

Synthesis, crystal structure and properties of title molecular are discribed. This crystal is monoclinic, belonging to space group P2~1 with a=0.9255(3)nm, b=1.0504(3)nm, c=1.0217(3)nm, β=100.99(2)°, V=0.9750nm^3, Z=2, D~c=1.790g/cm^3, R=0.025. The structure was solved by direct method. The tin atom of the title molecule exists in a distorted-trigonal-bipyramidal geometry, defined by three carbon, one iodine and one oxygen atoms leading to a five-membered chelate ring. The X-ray analysis show that the title compound has the properties of substitution reaction with halogen rather than addition reaction.

Key words: HYDROCARBON WITH TWO PHENYLS, ORGANIC SYNTHESIS, ORGANO TIN COMPOUNDS, ANTINEOPLASTIC ACTIVITY, VINYL COMPOUNDS, CYCLOHEXANOL P, CRYSTAL STRUCTURE

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