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有机化学
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有机化学 ›› 2008, Vol. 28 ›› Issue (03): 407-415. 上一篇    下一篇

综述与进展

光诱导电子转移环合反应中的立体控制策略

张荣华*，曾原，江致勤   

  1. (同济大学化学系 上海 200092)
  • 收稿日期:2007-03-19 修回日期:2007-09-05 发布日期:2008-03-18
  • 通讯作者: 张荣华

Stereocontrol Strategy in Photoinduced Electron Transfer Cyclization Reaction

ZHANG Rong-Hua*,ZENG Yuan,JIANG Zhi-Qin   

  1. (Department of Chemistry, Tongji University, Shanghai 200092)
  • Received:2007-03-19 Revised:2007-09-05 Published:2008-03-18
  • Contact: ZHANG Rong-Hua

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光诱导电子转移反应(PET)作为有机光化学反应中的一个研究热点, 近年来始终深受众多化学家的关注. 随着这一领域研究的不断深入, 许多具有合成潜力的工作不断涌现. 结合近年来这一领域的最新进展, 总结了在光诱导电子转移环合反应中进行不对称控制的常用策略.

关键词: 光诱导电子转移, 不对称, 立体选择性

As a focus in organic photochemistry, photoinduced electron transfer reaction is always an important concern of chemists in recent years. With the deep study in this area, much work of potential synthetic utility appears continuously. This article combined the recent advancement in this area, and summarized the common stereocontrol strategy in the photoinduced electron transfer cyclization reaction.

Key words: asymmetric, stereoselectivity, photoinduced electron transfer