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有机化学
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有机化学 ›› 2009, Vol. 29 ›› Issue (03): 309-320.    下一篇

综述与进展

碲、硒叶立德在立体选择性小环化反应中的应用

韩 汛a ; 叶龙武b ; 孙秀丽*,b   

  1. (a南京大学强化部 南京 210093)
    (b中国科学院上海有机化学研究所金属有机化学国家重点实验室 上海 200032)
  • 收稿日期:2008-04-18 修回日期:2008-07-18 发布日期:2009-03-20
  • 通讯作者: 孙秀丽

Cyclization Reactions for the Stereoselective Synthesis of Small Ring Compounds via Selenonium and Telluronium Ylides

Han, Xuna ; Ye, Longwub ; Sun, Xiuli*,b   

  1. (a Department for Intensive Instruction, Nanjing University, Nanjing 210093)
    (b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032)
  • Received:2008-04-18 Revised:2008-07-18 Published:2009-03-20
  • Contact: Sun, Xiuli

PDF

1485

被引次数

13

概述了碲及硒叶立德在立体选择性小环化反应中的应用, 包括环丙烷化反应、环氧化反应、氮杂环丙烷化反应等.

关键词: 氮杂环丙烷化, 立体选择性, 叶立德, 环丙烷化, 环氧化

Recent progress in the application of selenonium and telluronium ylide in the stereoselective formation of three-membered ring compounds, such as cyclopropanation, epoxidation, and aziridination are summarized.

Key words: cyclopropanation, stereoselectivity, epoxidation, aziridination, ylide