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有机化学
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有机化学 ›› 2009, Vol. 29 ›› Issue (11): 1719-1727. 上一篇    下一篇

综述与进展

碘作为Lewis酸催化剂在合成中的应用

周 颖   闫鹏飞   李光明   陈正军   

  1. (黑龙江大学化学化工与材料学院 功能有机重点实验室 哈尔滨 150080)
  • 收稿日期:2008-10-21 修回日期:2009-02-13 发布日期:2009-04-15
  • 通讯作者: 陈正军 E-mail:chenzj@hlju.edu.cn
  • 基金资助:

    国家自然科学基金及黑龙江省教育厅基金资助

The Synthesis Application for Iodine as a Lewis Acid Catalyst

  • Received:2008-10-21 Revised:2009-02-13 Published:2009-04-15

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碘催化的有机反应具有价廉易得、操作简单、温和、清洁、高效及高选择性等优点, 广泛应用于亲电反应、亲核反应、多组份反应以及其它涉及复杂官能团化合物的合成反应中, 在环境友好化学合成、复杂化合物合成及选择性合成领域具有应用价值.

关键词: 碘, Lewis酸, 催化, 绿色化学, 多组份反应, 选择性

The synthesis application of iodine used as a Lewis acid catalyst were reviewed including electrophilic and nucleophilic reaction, multi-component reactions as well as reactions for complicated compounds synthesis, these iodine-catalyzed reactions were cheap and commercially available and proceeded facilely, mildly, cleanly, high yield along with high chemo and regioselectivities, these merits promises the applications for environmentally benign processes, complicated compounds synthesis and high selective reactions.

Key words: iodine, Lewis acid, catalysis, green chemistry, multi-component reaction, selectivity