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有机化学
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有机化学 ›› 2011, Vol. 31 ›› Issue (10): 1668-1671. 上一篇    下一篇

研究简报

一种改进的合成Behera胺方法研究

马学美1,2，沈威*,3   

  1. (1华南理工大学工商管理系 广州 510140)
    (2深圳市创新投资集团有限公司博士后工作站 深圳 518000)
    (3华东理工大学精细化工研究所 上海 200237)
  • 收稿日期:2010-11-30 修回日期:2011-04-01 发布日期:2011-05-03
  • 通讯作者: 沈威 E-mail:sw0755@hotmail.com

A Modified Method for the Synthesis of Beheras Amine

Ma Xuemei1,2 Shen Wei*,3   

  1. (1 Department of Business Administration, South China University of Technology, Guangzhou 510140)
    (2 Post-doctoral Workstation, Shenzhen Capital Group CO., LTD, Shenzhen 518000)
    (3 Institute of Fine Chemicals, East China University of Science & Technol-ogy, Shanghai 200237)
  • Received:2010-11-30 Revised:2011-04-01 Published:2011-05-03
  • Contact: shen wei E-mail:sw0755@hotmail.com

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被引次数

2 | 1

以水合肼作为氢源, 以T-1型雷尼镍作为催化剂, 常压的条件下, 在沸腾的甲醇中顺利地还原脂肪族硝基为氨基制备了Behera胺, 反应时间短, 易于操作, 可以替代现有的合成方法. 并制备了第二代树枝形硝基化合物4, 用同样的方法还原4得到第二代树枝形Behera胺.

关键词: Behera胺, 水合肼, 雷尼镍, 还原, 改进

The Beheras amine was synthesized through the reduction of aliphatic nitro-group using hydrazine hydrate as source of hydrogen and T-1 Ranney Ni as catalyst in boiling methanol. With short reaction time, the method is easy to handle, and can substitute for the method at present. The second generation nitro-compound was synthesized, which was then reduced with the same method to give the second generation of Beharas amine.

Key words: Beheraamine, hydrazine hydrate, Ranney Ni, reduction, modification