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有机化学
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有机化学 ›› 2007, Vol. 27 ›› Issue (04): 438-448. 上一篇    下一篇

综述与进展

手性金属配合物催化的不对称环丙烷化反应的新进展

高金山，边庆花，郭洪超，王敏*   

  1. (中国农业大学理学院 北京 100094)
  • 收稿日期:2006-02-21 修回日期:1900-01-01 发布日期:2007-03-29
  • 通讯作者: 王敏

New Advances of Asymmetric Cyclopropanation Reactions Using Chiral Metal Catalysts

GAO Jin-Shan, BIAN Qing-Hua, GUO Hong-Chao, WANG Min*   

  1. (College of Science, China Agricultural University, Beijing 100094)
  • Received:2006-02-21 Revised:1900-01-01 Published:2007-03-29
  • Contact: WANG Min

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1804

被引次数

23 | 3

总结了近年来关于环丙烷化反应中各种手性金属催化剂的研究进展, 包括席夫碱、噁唑啉、卟啉、联吡啶及四吡啶、羧酸酯等类型的手性化合物作为配体的金属催化剂.

关键词: 不对称催化, 环丙烷化, 金属催化剂, 配体

Recent advances of chiral metal catalysts for cyclopropanation are reviewed in this paper. The chiral catalysts include metal complexes with Schiff base, oxazoline, porphyrin metal, bipyridine, terpyridine, carboxylate, etc.

Key words: ligand, chiral metal catalyst, cyclopropanation, asymmetric catalysis