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有机化学
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有机化学 ›› 2006, Vol. 26 ›› Issue (06): 793-802. 上一篇    下一篇

综述与进展

D-葡萄糖衍生物在不对称催化反应中的研究进展

孟祥启，张卫红*，刘云华，冯亚青   

  1. (天津大学化工学院 天津 300072)
  • 收稿日期:2005-05-24 修回日期:2005-11-16 发布日期:2006-05-31
  • 通讯作者: 张卫红

Advances of D-Glucose Derivatives inAsymmetric Catalytic Reactions

MENG Xiang-Qi,ZHANG Wei-Hong*,LIU Yun-Hua,FENG Ya-Qing   

  1. (School of Chemical Engineering, Tianjin University, Tianjin 300072)
  • Received:2005-05-24 Revised:2005-11-16 Published:2006-05-31
  • Contact: ZHANG Wei-Hong

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D-葡萄糖手性衍生物, 在不对称催化反应中的研究进展十分迅速, 综述了近年来D-葡萄糖手性衍生物直接作为催化剂催化不对称相转移Michael加成反应、氢硅烷化自由基链反应等和作为催化剂配体在不对称环氧化、氰硅烷化及Reformatsky等反应中的应用进展.

关键词: D-葡萄糖, 催化, 配体, 不对称合成

The progress of research on chiral derivatives from D-glucose used in asymmetric reactions was rapid. This paper will review recent advances in application of D-glucose derivatives as catalysts to asymmetric phase transfer Michael addition, alkene asymmetric hydrosilylation and catalyst ligands to asymmetric epoxidation, asymmetric cyanosilylation, asymmetric Reformatsky and other asymmetric reactions.

Key words: D-glucose, catalysis, asymmetric synthesis, ligands