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有机化学
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有机化学 ›› 2008, Vol. 28 ›› Issue (10): 1792-1796. 上一篇    下一篇

研究简报

二丁基锡(IV)磺酸酯催化合成缩醛(酮)

赵立芳* ; 王宏社 ; 苗建英   

  1. (宝鸡文理学院化学化工系 宝鸡 721007)
  • 收稿日期:2007-11-25 修回日期:2008-03-17 发布日期:2008-10-20
  • 通讯作者: 赵立芳

Synthesis of Acetals and Ketals Catalyzed by Dibutyltin(IV) Sulfonates

ZHAO, Li-Fang* ; WANG, Hong-She; MIAO, Jian-Ying   

  1. (Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Baoji 721007)

  • Received:2007-11-25 Revised:2008-03-17 Published:2008-10-20
  • Contact: ZHAO, Li-Fang

PDF

1267

被引次数

50

用二丁基氧化锡与苯磺酸、甲磺酸反应制备了两种新的有机锡化合物——二丁基锡(IV)磺酸酯. 以二丁基锡(IV)磺酸酯作催化剂, 合成了一系列缩醛(酮), 并通过正交实验, 优化了有机锡催化缩醛(酮)合成反应的反应条件. 实验表明该催化反应产率高, 反应时间短, 催化剂用量少且能回收再利用.

关键词: 有机锡化合物, 二丁基锡(IV)磺酸酯, 催化, 缩醛(酮)

The reaction of dibutyltin oxide with benzenesulfonic acid or methylsufonic acid gave two new dibutyltin(IV) sulfonates which can be used as the catalysts for the synthesis of acetals and ketals. The opti-mal reaction conditions were obtained by orthogonal experiments. The advantages of the present procedure are high yields and short reaction time. Furthermore, the catalysts could be recovered easily by filtration and reused efficiently.

Key words: dibutyltin(IV) sulfonate, organotin compound, acetal and ketal, catalysis