手性Lewis酸催化的可见光不对称合成研究进展

doi:10.6023/cjoc202205032

有机化学 ›› 2022, Vol. 42 ›› Issue (10): 3335-3350.DOI: 10.6023/cjoc202205032 上一篇下一篇

所属专题：不对称催化专辑

综述与进展

手性Lewis酸催化的可见光不对称合成研究进展

成秀亮^a, 李冬^a, 杨博轩^a, 林玉妹^a, 龚磊^a^,^b^,^*()

a 厦门大学化学化工学院福建省化学生物学重点实验室福建厦门 361005
b 福建省能源材料科学与技术创新实验室(IKKEM) 福建厦门 361005

收稿日期:2022-05-19 修回日期:2022-06-25 发布日期:2022-11-02
通讯作者: 龚磊
作者简介:
†共同第一作者.
基金资助:
国家自然科学基金(22071209); 国家自然科学基金(22071206); 及国家高层次青年人才资助项目

Recent Advances in Visible-Light Photocatalytic Asymmetric Synthesis Enabled by Chiral Lewis Acids

Xiuliang Cheng^a, Dong Li^a, Boxuan Yang^a, Yumei Lin^a, Lei Gong^a^,^b()

a College of Chemistry and Chemical Engineering, Key Laboratory of Chemical Biology of Fujian Province, Xiamen University, Xiamen, Fujian 361005
b Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen, Fujian 361005

Received:2022-05-19 Revised:2022-06-25 Published:2022-11-02
Contact: Lei Gong
About author:
†These authors contributed equally to this work.
Supported by:
National Natural Science Foundation of China(22071209); National Natural Science Foundation of China(22071206); National Youth Talent Support Program

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摘要/Abstract

近年来, 可见光催化不对称合成已在快速构筑结构多样的光活性有机分子上展现了相当的潜力. 手性Lewis酸(CLA), 如手性硼烷化合物、镧系配合物、第一过渡系金属配合物、金属中心手性铱及铑配合物等, 能有效控制可见光驱动自由基反应过程的立体化学. 按照手性Lewis酸双功能催化和手性Lewis酸/可见光催化剂协同催化这两种主要反应类型, 简要介绍了这一领域的最新进展, 以期促进有机合成、光催化、不对称催化领域的发展.

关键词: 可见光催化, 不对称合成, 手性Lewis酸, 协同催化, 双功能催化

In recent years, visible-light photocatalytic asymmetric synthesis has shown considerable potential in the mild and rapid construction of optically active organic molecules with structural diversity. Chiral Lewis acids (CLA), including chiral borane compounds, lanthanum complexes, first-row transition metal complexes, and chiral-at-iridium or rhodium complexes, have been established as one class of the most effective catalysts being capable of controlling the stereochemistry in photo-induced chemical transformations. The recent advances in this emerging field were presented by classifying the reactions into bifunctional CLA photocatalytic reactions and reactions enabled by dual catalysis with a CLA catalyst and an external photosensitizer, expecting that these studies will stimulate progress in organic synthesis, photocatalysis and asymmetric catalysis.

Key words: visible light photocatalysis, asymmetric synthesis, chiral Lewis acid, cooperative catalysis, bifunctional catalysis

引用此文

成秀亮, 李冬, 杨博轩, 林玉妹, 龚磊. 手性Lewis酸催化的可见光不对称合成研究进展[J]. 有机化学, 2022, 42(10): 3335-3350.

Xiuliang Cheng, Dong Li, Boxuan Yang, Yumei Lin, Lei Gong. Recent Advances in Visible-Light Photocatalytic Asymmetric Synthesis Enabled by Chiral Lewis Acids[J]. Chinese Journal of Organic Chemistry, 2022, 42(10): 3335-3350.

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图/表 26

图式1. 手性硼Lewis酸催化的可见光非对映、对映选择性[2+2]环加成反应

Scheme 1. Photocatalytic diastereo-, enantioselective [2+2] cycloaddition enabled by a chiral borane Lewis acid

图式2. 手性硼Lewis酸催化的对映选择性重排反应

Scheme 2. Enantioselective rearrangements reaction enabled by a chiral borane Lewis acid

图式3. 手性硼Lewis酸经EDA配合物催化α,β-不饱和羰基化合物的对映选择性自由基加成反应

Scheme 3. Chiral borane Lewis acid-catalyzed enantioselective addition of α,β-unsaturated carbonyl compounds via EDA complexes

图式4. 八面体铱中心手性Lewis酸双功能催化酮的可见光不对称烷基化

Scheme 4. Photocatalytic enantioselective α-alkylation reaction of ketones enabled by a chiral-at-iridium octahedral Lewis acid

图式5. 铱中心手性Lewis酸双功能催化其他可见光不对称反应

Scheme 5. Other photochemical asymmetric reactions enabled by bifunctional chiral-at-iridium Lewis acids

图式6. 铑中心手性Lewis酸催化剂的设计及应用

Scheme 6. Design of a chiral-at-rhodium Lewis acid and its applications

图式7. 新型双环金属化手性铑Lewis酸催化剂的设计及应用

Scheme 7. Design of a chiral-at-rhodium Lewis acid with a new cyclometalating ligand and its applications

图式8. 铑中心手性Lewis酸催化可见光去对称化反应

Scheme 8. Photocatalytic deracemization enabled by a chiral-at-rhodium Lewis acid

图式9. 铑中心手性Lewis酸催化的可见光不对称[2+2]环加成

Scheme 9. Photocatalytic asymmetric [2+2] cycloaddition enabled by a chiral-at-rhodium Lewis acid

图式10. 铑中心手性Lewis酸催化的可见光不对称环加成反应

Scheme 10. photocatalytic asymmetric cycloaddition enabled by a chiral-at-rhodium Lewis acid

图式11. 双功能手性镍Lewis酸的设计及其在可见光催化β-酮酸酯对映选择性氧化中的应用

Scheme 11. Design of a bifunctional chiral nickel Lewis acid and its application to photocatalytic enantioselective aerobic oxidation of β-ketoesters

图式12. 手性噁唑啉-镍催化的可见光不对称合成

Scheme 12. Photocatalytic asymmetric synthesis enabled by a chiral bisoxazoline-nickel catalyst

图式13. 手性双噁唑啉-铜(II)催化亚胺的可见光对映选择性烷基化反应

Scheme 13. Photocatalytic enantioselective alkylation reaction of imines enabled by a chiral bisoxazoline-copper(II) catalyst

图式14. 手性双噁唑啉-铜(II)催化的其它可见光不对称反应

Scheme 14. Other photocatalytic asymmetric reactions enabled by a chiral bisoxazoline-copper(II) catalyst

图式15. 镧系金属手性Lewis酸与可见催化剂协同催化可见光不对称[2+2]环加成反应

Scheme 15. Photocatalytic asymmetric [2+2] cycloaddition reaction enabled by dual catalysis with a lanthanide-based chiral Lewis acid and a photocatalyst

图式16. 镧系金属手性Lewis酸与可见催化剂协同催化的其它可见光不对称反应

Scheme16. Other photocatalytic asymmetric reactions enabled by dual catalysis with a lanthanide-based chiral Lewis acid and a photocatalyst

图式17. 手性钆Lewis酸和钌联吡啶配合物协同催化催化可见光不对称[3+2]环加成反应

Scheme 17. Photocatalytic asymmetric [3+2] cycloaddition enabled by merging a gadolinium-based chiral Lewis acid and a ruthenium bipyridine complex

图式18. 铑中心手性Lewis酸与外加可见光催化剂协同催化不对称α-胺基化和α-烷基化反应

Scheme 18. Asymmetric α-amination and α-alkylation reactions enabled by dual catalysis with a chiral-at-rhodium Lewis acid and an external photocatalyst

图式19. 铑中心手性Lewis酸与有机可见光催化剂的协同催化

Scheme 19. Dual catalysis enabled by a chiral-at-rhodium Lewis acid and an organophotocatalyst

图式20. 铑中心手性Lewis酸/可见光催化剂协同催化多种可见光不对称合成

Scheme 20. A variety of photocatalytic asymmetric reactions enabled by dual catalysis with a chiral-at-rhodium Lewis acid and an external photocatalyst

图式21. 可见光氧化还原催化剂和手性镍Lewis酸协同催化对映选择性二氟烷基化或全氟烷基化反应

Scheme 21. Photocatalytic enantioselective di/perfluoroalkylation enabled by synergistic catalysis with a photoredox catalyst and a chiral nickel Lewis acid

图式22. 协同催化可见光对映选择性合成对映体邻氨基醇衍生物

Scheme 22. Photocatalytic enantioselective synthesis of chiral amino- alcohol derivatives enabled by synergistic catalysis

图式23. 八面体中心手性钴Lewis酸与有机可见光催化剂共催化可见光不对称Giese反应

Scheme 23. Synergistic catalysis with an octahedral chiral cobalt Lewis acid and an organocatalyst for a photocatalytic asymmetric Giese reaction

图式24. 手性铜Lewis酸和铱可见光催化剂共催化α,β-不饱和酰胺的对映选择性胺基甲基化反应

Scheme 24. Photocatalytic enantioselective aminomethylation reaction enabled by dual catalysis with a copper-based chiral Lewis acid and an Ir photocatalyst

图式25. 可见光氢转移催化/手性铜Lewis酸协同催化区域、立体选择性C(sp3)—H官能化反应

Scheme 25. Photocatalytic region and stereoselective C(sp3)—H functionalization enabled by dual HAT photocatalysis and chiral copper Lewis acid-based catalysis

图式26. 可见光氢转移催化/手性镍Lewis酸协同催化三组分不对称C(sp3)-H磺酰化反应

Scheme 26. Photocatalytic three-component asymmetric C (sp3)-H sulfonylation enabled by dual HAT photocatalysis and chiral nickel Lewis acid-based catalysis

参考文献 70

[1]	Prier, C. K.; Rankic, D. A.; MacMillan, D. W. Chem. Rev. 2013, 113, 5322. doi: 10.1021/cr300503r
[2]	Yoon, T. P.; Ischay, M. A.; Du, J. Nat. Chem. 2010, 2, 527. doi: 10.1038/nchem.687
[3]	Zhang, H.-T.; Gu, L.-J.; Huang, X.-Z.; Wang, R.; Jin, C.; Li, G.-P. Chin. Chem. Lett. 2016, 27, 256. doi: 10.1016/j.cclet.2015.10.012
[4]	Qu, Z.; Wang, P.; Chen, X.; Deng, G.-J.; Huang, H. Chin. Chem. Lett. 2021, 32, 2582. doi: 10.1016/j.cclet.2021.02.047
[5]	Chen, J. R.; Hu, X. Q.; Lu, L. Q.; Xiao, W. J. Chem. Soc. Rev. 2016, 45, 2044. doi: 10.1039/C5CS00655D
[6]	Poplata, S.; Troster, A.; Zou, Y. Q.; Bach, T. Chem. Rev. 2016, 116, 9748. doi: 10.1021/acs.chemrev.5b00723 pmid: 27018601
[7]	Zhou, Q. Q.; Zou, Y. Q.; Lu, L. Q.; Xiao, W. J. Angew. Chem., Int. Ed. 2019, 58, 1586. doi: 10.1002/anie.201803102
[8]	Lipp, A.; Badir, S. O.; Molander, G. A. Angew. Chem., Int. Ed. 2021, 60, 1714. doi: 10.1002/anie.202007668
[9]	Wang, C.; Lu, Z. Org. Chem. Front. 2015, 2, 179. doi: 10.1039/C4QO00306C
[10]	Meggers, E. Angew. Chem., Int. Ed. 2017, 56, 5668. doi: 10.1002/anie.201612516
[11]	Vega-Peñaloza, A.; Paria, S.; Bonchio, M.; Dell’Amico, L.; Companyó, X. ACS Catal. 2019, 9, 6058. doi: 10.1021/acscatal.9b01556
[12]	Jiang, C.; Chen, W.; Zheng, W. H.; Lu, H. Org. Biomol. Chem. 2019, 17, 8673. doi: 10.1039/C9OB01609K
[13]	Schwinger, D. P.; Bach, T. Acc. Chem. Res. 2020, 53, 1933. doi: 10.1021/acs.accounts.0c00379
[14]	Li, S.; Xiang, S. H.; Tan, B. Chin. J. Chem. 2020, 38, 213. doi: 10.1002/cjoc.201900472
[15]	Wang, A.-E.; Huang, P.-Q. Sci. China: Chem. 2020, 63, 871.
[16]	Santelli, M.; Pons, J. M. Lewis Acids and Selectivity in Organic Synthesis, CRC Press, Boca Raton, 1996.
[17]	Fukuzumi, S.; Jung, J.; Lee, Y. M.; Nam, W. Asian J. Org. Chem. 2017, 6, 397. doi: 10.1002/ajoc.201600576
[18]	Yoon, T. P. Acc. Chem. Res. 2016, 49, 2307. doi: 10.1021/acs.accounts.6b00280
[19]	Brimioulle, R.; Lenhart, D.; Maturi, M. M.; Bach, T. Angew. Chem., Int. Ed. 2015, 54, 3872. doi: 10.1002/anie.201411409
[20]	Hong, B. C. Org. Biomol. Chem. 2020, 18, 4298. doi: 10.1039/D0OB00759E
[21]	Yang, K.; Song, Q. Acc. Chem. Res. 2021, 54, 2298. doi: 10.1021/acs.accounts.1c00132
[22]	Lewis, F. D.; Howard, D. K.; Oxman, J. D. J. Am. Chem. Soc. 1983, 105, 3344. doi: 10.1021/ja00348a069
[23]	Stegbauer, S.; Jandl, C.; Bach, T. Angew. Chem., Int. Ed. 2018, 57, 14593. doi: 10.1002/anie.201808919
[24]	Leverenz, M.; Merten, C.; Dreuw, A.; Bach, T. J. Am. Chem. Soc. 2019, 141, 20053. doi: 10.1021/jacs.9b12068 pmid: 31814393
[25]	Miyasaka, H. Acc. Chem. Res. 2013, 46, 248. doi: 10.1021/ar300102t
[26]	Crisenza, G. E. M.; Mazzarella, D.; Melchiorre, P. J. Am. Chem. Soc. 2020, 142, 5461. doi: 10.1021/jacs.0c01416 pmid: 32134647
[27]	Kim, J. Y.; Lee, Y. S.; Ryu, D. H. ACS Catal. 2021, 11, 14811. doi: 10.1021/acscatal.1c04835
[28]	Gong, L.; Wenzel, M.; Meggers, E. Acc. Chem. Res. 2013, 46, 2635. doi: 10.1021/ar400083u
[29]	Huang, X.; Meggers, E. Acc. Chem. Res. 2019, 52, 833. doi: 10.1021/acs.accounts.9b00028
[30]	Huo, H.; Shen, X.; Wang, C.; Zhang, L.; Rose, P.; Chen, L. A.; Harms, K.; Marsch, M.; Hilt, G.; Meggers, E. Nature 2014, 515, 100. doi: 10.1038/nature13892
[31]	Huo, H.; Wang, C.; Harms, K.; Meggers, E. J. Am. Chem. Soc. 2015, 137, 9551. doi: 10.1021/jacs.5b06010
[32]	Wang, C.; Qin, J.; Shen, X.; Riedel, R.; Harms, K.; Meggers, E. Angew. Chem., Int. Ed. 2016, 55, 685. doi: 10.1002/anie.201509524
[33]	Tan, Y.; Yuan, W.; Gong, L.; Meggers, E. Angew. Chem., Int. Ed. 2015, 54, 13045. doi: 10.1002/anie.201506273
[34]	Shen, X.; Harms, K.; Marsch, M.; Meggers, E. Chem.-Eur. J. 2016, 22, 9102. doi: 10.1002/chem.201601572
[35]	Steinlandt, P. S.; Zuo, W.; Harms, K.; Meggers, E. Chem.- Eur. J. 2019, 25, 15333. doi: 10.1002/chem.201903369
[36]	Zhang, C.; Gao, A. Z.; Nie, X.; Ye, C. X.; Ivlev, S. I.; Chen, S.; Meggers, E. J. Am. Chem. Soc. 2021, 143, 13393. doi: 10.1021/jacs.1c06637
[37]	Yoon, T. P. ACS Catal. 2013, 3, 895. doi: 10.1021/cs400088e
[38]	Huang, X.; Quinn, T. R.; Harms, K.; Webster, R. D.; Zhang, L.; Wiest, O.; Meggers, E. J. Am. Chem. Soc. 2017, 139, 9120. doi: 10.1021/jacs.7b04363
[39]	Huang, X.; Li, X.; Xie, X.; Harms, K.; Riedel, R.; Meggers, E. Nat. Commun. 2017, 8, 2245. doi: 10.1038/s41467-017-02148-1
[40]	Hu, N.; Jung, H.; Zheng, Y.; Lee, J.; Zhang, L.; Ullah, Z.; Xie, X.; Harms, K.; Baik, M. H.; Meggers, E. Angew. Chem., Int. Ed. 2018, 57, 6242. doi: 10.1002/anie.201802891
[41]	Dai, X.; Li, Y.; Zhang, S.; Gong, L. Chin. J. Org. Chem. 2019, 39, 1711. (in Chinese). doi: 10.6023/cjoc201902022
	(代雪梅, 李延军, 张少南, 龚磊, 有机化学, 2019, 39, 1711.) doi: 10.6023/cjoc201902022
[42]	Tasker, S. Z.; Standley, E. A.; Jamison, T. F. Nature 2014, 509, 299. doi: 10.1038/nature13274
[43]	Zhang, S.; Cao, S.; Lin, Y.-M.; Sha, L.; Lu, C.; Gong, L. Chin. J. Catal. 2022, 43, 564. doi: 10.1016/S1872-2067(21)63953-0
[44]	Tellis John, C.; Primer David, N.; Molander Gary, A. Science 2014, 345, 433. doi: 10.1126/science.1253647 pmid: 24903560
[45]	Ding, W.; Lu, L. Q.; Zhou, Q. Q.; Wei, Y.; Chen, J. R.; Xiao, W. J. J. Am. Chem. Soc. 2017, 139, 63. doi: 10.1021/jacs.6b11418 pmid: 28001382
[46]	Shen, X.; Li, Y.; Wen, Z.; Cao, S.; Hou, X.; Gong, L. Chem. Sci. 2018, 9, 4562. doi: 10.1039/C8SC01219A
[47]	Cao, S.; Ye, Z.; Chen, Y.; Lin, Y.-M.; Fang, J.; Wang, Y.; Yang, B.; Gong, L. CCS Chem. 2021, 3, 3329.
[48]	Li, Y.; Zhou, K.; Wen, Z.; Cao, S.; Shen, X.; Lei, M.; Gong, L. J. Am. Chem. Soc. 2018, 140, 15850. doi: 10.1021/jacs.8b09251
[49]	Han, B.; Li, Y.; Yu, Y.; Gong, L. Nat. Commun. 2019, 10, 3804. doi: 10.1038/s41467-019-11688-7
[50]	Zhou, K.; Yu, Y.; Lin, Y.-M.; Li, Y.; Gong, L. Green Chem. 2020, 22, 4597. doi: 10.1039/D0GC00262C
[51]	Skubi, K. L.; Blum, T. R.; Yoon, T. P. Chem. Rev. 2016, 116, 10035. doi: 10.1021/acs.chemrev.6b00018
[52]	Du, J.; Skubi Kazimer, L.; Schultz Danielle, M.; Yoon Tehshik, P. Science 2014, 344, 392. doi: 10.1126/science.1251511
[53]	Ruiz Espelt, L.; McPherson, I. S.; Wiensch, E. M.; Yoon, T. P. J. Am. Chem. Soc. 2015, 137, 2452. doi: 10.1021/ja512746q pmid: 25668687
[54]	Dong, X.; Li, Q. Y.; Yoon, T. P. Org. Lett. 2021, 23, 5703. doi: 10.1021/acs.orglett.1c01790
[55]	Amador, A. G.; Sherbrook, E. M.; Yoon, T. P. J. Am. Chem. Soc. 2016, 138, 4722. doi: 10.1021/jacs.6b01728
[56]	Huang, X.; Webster, R. D.; Harms, K.; Meggers, E. J. Am. Chem. Soc. 2016, 138, 12636. doi: 10.1021/jacs.6b07692
[57]	Huo, H.; Harms, K.; Meggers, E. J. Am. Chem. Soc. 2016, 138, 6936. doi: 10.1021/jacs.6b03399
[58]	Wang, C.; Harms, K.; Meggers, E. Angew. Chem., Int. Ed. 2016, 55, 13495. doi: 10.1002/anie.201607305
[59]	Zhou, Z.; Li, Y.; Han, B.; Gong, L.; Meggers, E. Chem. Sci. 2017, 8, 5757. doi: 10.1039/C7SC02031G
[60]	Ma, J.; Xie, X.; Meggers, E. Chem.-Eur. J. 2018, 24, 259. doi: 10.1002/chem.201704619
[61]	Liang, H.; Xu, G. Q.; Feng, Z. T.; Wang, Z. Y.; Xu, P. F. J. Org. Chem. 2019, 84, 60. doi: 10.1021/acs.joc.8b02316 pmid: 30507130
[62]	Liu, J.; Ding, W.; Zhou, Q. Q.; Liu, D.; Lu, L. Q.; Xiao, W. J. Org. Lett. 2018, 20, 461. doi: 10.1021/acs.orglett.7b03826
[63]	Ye, C. X.; Melcamu, Y. Y.; Li, H. H.; Cheng, J. T.; Zhang, T. T.; Ruan, Y. P.; Zheng, X.; Lu, X.; Huang, P. Q. Nat. Commun. 2018, 9, 410. doi: 10.1038/s41467-017-02698-4 pmid: 29379007
[64]	Zhang, K.; Lu, L. Q.; Jia, Y.; Wang, Y.; Lu, F. D.; Pan, F.; Xiao, W. J. Angew. Chem., Int. Ed. 2019, 58, 13375. doi: 10.1002/anie.201907478
[65]	Pagire, S. K.; Kumagai, N.; Shibasaki, M. Chem. Sci. 2020, 11, 5168. doi: 10.1039/D0SC01890B
[66]	Labinger, J.; Bercaw, J. Nature 2002, 417, 507. doi: 10.1038/417507a
[67]	Goldberg, K. I.; Goldman, A. S. Acc. Chem. Res. 2017, 50, 620. doi: 10.1021/acs.accounts.6b00621
[68]	Davies, H. M. L.; Liao, K. Nat. Rev. Chem. 2019, 3, 347. doi: 10.1038/s41570-019-0099-x pmid: 32995499
[69]	Li, Y.; Lei, M.; Gong, L. Nat. Catal. 2019, 2, 1016. doi: 10.1038/s41929-019-0357-9
[70]	Cao, S.; Hong, W.; Ye, Z.; Gong, L. Nat. Commun. 2021, 12, 2377. doi: 10.1038/s41467-021-22690-3

手性Lewis酸催化的可见光不对称合成研究进展

Recent Advances in Visible-Light Photocatalytic Asymmetric Synthesis Enabled by Chiral Lewis Acids

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[13]	向勋, 何照林, 董秀琴. 钯和手性磷酸协同催化高效构建手性分子的研究进展[J]. 有机化学, 2023, 43(3): 791-808.
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