亲电硒催化重排反应的研究进展

doi:10.6023/cjoc202508009

摘要/Abstract

在硒作为催化中心参与的各类反应中,亲电硒催化由于其独特的亲碳性与氧化还原活性等优势,在催化合成中作为一种重要的合成工具,在过去十年间受到越来越多的关注。该催化手段在各类重排反应中也得以应用,并能够顺利构建各种有价值的化合物。本综述简要概括了亲电硒催化在重排反应中的研究进展,从亲核重排和[2,3] σ重排两个方面进行介绍,侧重反应机理的描述,为硒催化新反应的设计提供参考。

关键词: 亲电硒催化, 亲核重排, [2,3]σ重排, 有机催化

Among the various reactions in which selenium serves as a catalytic center, electrophilic selenium catalysis has become an important synthetic tool in catalytic synthesis and has received increasing attention over the past decade due to its unique catalytic advantages such as carbon affinity and redox activity. This catalytic method has also been applied in various rearrangement reactions and can successfully construct a variety of valuable compounds. This review briefly summarizes the research progress of electrophilic selenium catalysis in rearrangement reactions, introducing both nucleophilic rearrangements and [2,3] sigmatropic rearrangements, with a focus on the description of reaction mechanisms, providing references for the design of new selenium-catalyzed reactions.

Key words: electrophilic selenium catalysis, nucleophilic rearrangement, [2,3] σ, rearrangement, organocatalysis

引用此文

仇王朕, 赵晓丹. 亲电硒催化重排反应的研究进展[J]. 有机化学, doi: 10.6023/cjoc202508009.

Qiu Wangzhen, Zhao Xiaodan. Research Progress in Electrophilic Selenium-Catalyzed Rearrangement Reactions[J]. Chinese Journal of Organic Chemistry, doi: 10.6023/cjoc202508009.

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