Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (10): 2063-2067.DOI: 10.6023/cjoc201404012 Previous Articles     Next Articles



李晓微, 周晋, 禚淑萍   

  1. 山东理工大学化学工程学院 淄博 255049
  • 收稿日期:2014-04-06 修回日期:2014-05-11 发布日期:2014-06-09
  • 通讯作者: 禚淑萍
  • 基金资助:

    国家自然科学基金(No. 51302156)资助项目.

Synthesis of N-Heterocyclic Carbene Ruthenium Complex and Application as Catalyst for Suzuki Coupling Reaction

Li Xiaowei, Zhou Jin, Zhuo Shuping   

  1. School of Chemical Engineering, Shandong University of Technology, Zibo 255049
  • Received:2014-04-06 Revised:2014-05-11 Published:2014-06-09
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 51302156).

Two new complexes 1 and 2 were synthesized and characterized by 1H NMR, 13C NMR, IR spectra and elemental analysis, and the crystal structure of cis(I) configuration 2 has been also determined by X-ray crystal diffraction. Complexes 1 and 2 have been found to catalyze the Suzuki coupling reaction of aryl halides and phenylboronic acid with high catalytic activity under the mild reaction conditions.

Key words: N-heterocyclic carbene, ruthenium complex, catalysis, Suzuki coupling