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Abstract

Deoxygenation of sulfoxides, N-oxides of pyridine derivatives, and triphenylarsine oxide with isopropylmagnesium bromide in the presence of bis(cyclopentadienyl)titanium dichloride was described. The possible mechanism is also discussed.

Key words: PYRIDINE P, CATALYSIS, SULFOXIDE, BENZENE P, CYCLOPENTADIENE P, ISOPROPYL GROUP, BROMIDE, TITANIUM COMPLEX, MAGNESIUM COMPOUNDS, DEOXIDIZATION, GRIGNARD REAGENT, AMINE OXIDE, ARSINE OXIDE

CLC Number:

O621
O627

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ZHANG YONGMIN;LIN RONGHUI. null[J]. Chin. J. Org. Chem., 1987, 7(5): 361-364.

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