Chin. J. Org. Chem. ›› 1989, Vol. 9 ›› Issue (6): 555-557. Previous Articles    

零价铜催化含氮杂环的N-芳基化合物的合成

张昭;陈兆斌;杜秋生;冯育林;夏炽中   

  1. 山西大学化学系;山西大学分子科学研究所
  • 发布日期:1989-12-25

Synthesis of N-aryl substituted heterocyclic compounds by copper-(O) catalyst

ZHANG ZHAO;CHEN ZHAOBIN;DU QIUSHENG;FENG YULIN;XIA CHIZHONG   

  • Published:1989-12-25

The Cu(0)-catalyzed reactions of carbazole, phenothiazine, benzimidazole with aryl halides (idobenzene, 1- or 2-bromonaphthalene, 2-bromopyridine) gave rise to corresponding N-arylated products (N-arylcarbazole, N-arylpnenthiazine, N-arylbenzimidazole).

Key words: PYRIDINE P, CATALYSIS, BENZIMIDAZOLE P, CARBAZOLE P, COPPER, NITROGEN HETEROCYCLICS, SUBSTITUTION REACTION, NUCLEOPHILIC REACTION, PHENOTHIAZINE P

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