Chin. J. Org. Chem. ›› 2000, Vol. 20 ›› Issue (1): 1-10.     Next Articles

催化不对称反应新发展: 不对称活化

丁奎岭;林国强   

  1. 中国科学院上海有机化学研究所.上海(200032)
  • 发布日期:2000-02-25

Recent advances in catalytic asymmetric reactions: Asymmetric activation

Ding Kuiling;Lin Guoqiang   

  1. Shanghai Inst Organ Chem., CAS.Shanghai(200032)
  • Published:2000-02-25

A new strategy for asymmetric synthesis, nameld asymmetric activation, is presented and some of its recent advances are reviewed.With asymmetric activation strategy, a chiral or even racemic catalyst may be selectively activated by a chiral activator to yield non-racemic prodlucts. The advantage of this approach over the deactivation strategy is that the activated catalyst can produce angreater enantiometric excess in the products than the enantiomerically pure catalyst can alone.

Key words: CATALYSIS, CHIRALITY, PROPENYL BENZENE

CLC Number: