Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (10): 1260-1261. Previous Articles     Next Articles

三(含氟烷基)磷酸酯的简便合成

李战雄a,b, 唐松青*,a, 刘金涛a, 钱国兴a   

  1. a中国科学院上海有机化学研究所 上海 200032;
    b苏州大学材料工程学院 苏州 215021
  • 收稿日期:2003-10-08 修回日期:2004-03-11 接受日期:2004-04-15 发布日期:2022-09-20

Convenient Synthesis of Triphosphate Fluoroalkyl Esters

LI Zhan-Xionga,b, TANG Song-Qing*,a, LIU Jin-Taoa, QIAN Guo-Xinga   

  1. aShanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032;
    bCollege of Material Engineering, Soochow University, Suzhou 215021
  • Received:2003-10-08 Revised:2004-03-11 Accepted:2004-04-15 Published:2022-09-20
  • Contact: * E-mail: tangsq@mail.sioc.ac.cn

Using lithium chloride as catalyst,four tris(fluoroalkyl)phosphates were synthesized via condensation of fluoroalcohol and phosphorus oxychloride directly. The structures of these phosphates wereidentified by 1H NMR, 19F NMR, IR, MS spectra and elemental analysis.

Key words: fluoroalkyl phosphates, lithium chloride, catalysis