Chin. J. Org. Chem. ›› 2001, Vol. 21 ›› Issue (12): 1102-1111. Previous Articles     Next Articles

Salen Mn(Ⅲ)催化的双键不对称环氧化研究进展

王歆燕;石鸿昌;徐寿颐   

  1. 清华大学化学系.北京(100084)
  • 发布日期:2001-12-25

Advances in the asymmetric epoxidation of double bond using salen manganese (Ⅲ) complexes as catalysts

Wang Xinyan;Shi Hongchang;Xu Shouyi   

  1. Tsing Hua Univ, Dept Chem.Beijing(100084)
  • Published:2001-12-25

Asymmetric epoxidation of unfunctionalized olefins catalyzed by chiral salen manganese (Ⅲ) complexes is reviewed. The type of catalysts, the mechanism of epoxidation, as well as the scope of the reaction are discussed.

Key words: CATALYST, DOUBLE BONDS, MANGANESE COMPLEX, ENANTIOMORPH, ALKENE P, EPOXIDATION REACTION

CLC Number: