Chin. J. Org. Chem. ›› 1998, Vol. 18 ›› Issue (3): 248-252. Previous Articles     Next Articles

Original Articles

分子极化效应与烷烃、醇的空腔表面积

曹晨忠;李志良   

  1. 湘潭师范学院化学系;湖南大学化学化工系
  • 发布日期:1998-06-25

The correlation of the molecular polarizability effect with the cavity surface area for paraffin and alcohol

CAO CHENZHONG;LI ZHILIANG   

  • Published:1998-06-25

The cavity surface area (CSA) of paraffin and alcohol in water can be calculated by the expression: CSA=122.984+ 8.65736SBL-103.862ΔMPEI. Where the parameter SBL is the sum of bond length in the molecule, ΔMPEI is the difference of molecular polarizability effect index between the normal chain isomer and the branched chain isomer which bearing same carbon atom number for the paraffin or alcohol.

Key words: ALCOHOL, ALKANE

CLC Number: