Synthesis of a New Pd(II) Complex with Tridentate Nitrogen Ligands and Investigation of Its Catalytic Property

Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (01): 134-137. Previous Articles

Reports

新型含氮三齿钯(II)配合物的合成及其催化性能研究

高宏飞，郭向前，杨刚*，徐南平

(南京工业大学膜科学技术研究所南京 210009)

收稿日期:2006-03-30 修回日期:2006-05-12 发布日期:2006-12-30
通讯作者: 杨刚

Synthesis of a New Pd(II) Complex with Tridentate Nitrogen Ligands and Investigation of Its Catalytic Property

GAO Hong-Fei,GUO Xiang-Qian,YANG Gang*,XU Nan-Ping

(Membrane Science & Technology Research Center, Nanjing University of Technology, Nanjing 210009)

Received:2006-03-30 Revised:2006-05-12 Published:2006-12-30
Contact: YANG Gang

Abstract

A new tridentate nitrogen ligand with a 4-position substituted active functional group in the pyridine ring was successfully prepared from chelidamic acid via the processes of esterification, reduction, bromization and amination, and then further reacted with palladium chloride to give the palladium(II) complex. The complex was characterized by IR, ¹H, ¹³C NMR spectra, elementary analysis etc. The catalytic properties of the new pincer-type NN'N complex for Heck arylation of aryl halides with alkenes were investigated. The results showed that the complex had high catalytic activities.

Key words: tridentate ligand, Pd complex, catalyst, Heck arylation reaction

Cite this article

GAO Hong-Fei,GUO Xiang-Qian,YANG Gang*,XU Nan-Ping. Synthesis of a New Pd(II) Complex with Tridentate Nitrogen Ligands and Investigation of Its Catalytic Property[J]. Chin. J. Org. Chem., 2007, 27(01): 134-137.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Jianghu Dong, Liangming Xuan, Chi Wang, Chenxi Zhao, Haifeng Wang, Qiongjiao Yan, Wei Wang, Fen'er Chen. Recent Advances in Visible-Light-Induced C(3)—H Functionalization of Quinoxalinones under Transition-Metal-Free or Photocatalyst-Free [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 111-136.
[2]	Qianfan Zhao, Yongzheng Chen, Shiming Zhang. Application and Mechanism Study of Carbon-Based Metal-Free Catalysts in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 137-147.
[3]	Kai Lu, Haoqi Qu, Xi Chen, Hui Qiu, Jing Zheng, Mengtao Ma. Catalyst-Free and Solvent-Free Hydroboration of Alkynes and Alkenes with Catecholborane [J]. Chinese Journal of Organic Chemistry, 2023, 43(6): 2197-2205.
[4]	Baichuan Mo, Chunxia Chen, Jinsong Peng. Research Progress in Application of Lignin and Its Derivatives Supported Metal Catalysts in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2023, 43(4): 1215-1240.
[5]	Tiantian Liu, Xinhong Duan. Recent Progress in the Construction of Chiral 3-Substituted Indoles by Asymmetric Friedel-Crafts Reactions [J]. Chinese Journal of Organic Chemistry, 2023, 43(11): 3695-3712.
[6]	Sining Qin. Research Progress in C—S Coupling Reactions of Aryl Halides [J]. Chinese Journal of Organic Chemistry, 2023, 43(11): 3761-3783.
[7]	Zhiyuan Chen, Mengwei Yang, Jianlin Xu, Yunhe Xu. Regioselective Synthesis of β-Silyl-Substituted Vinylphosphine Oxides via Copper-Catalyzed Protosilylation of Dialkynylphosphine Oxides [J]. Chinese Journal of Organic Chemistry, 2023, 43(10): 3598-3607.
[8]	Xiangkun Meng, Zhengyuan Qi, Lei Yu, Yiyang Zhang. Catalytic System for Poly(lactic acid) Synthesis: Opportunities and Challenges [J]. Chinese Journal of Organic Chemistry, 2023, 43(1): 112-119.
[9]	Xudong Cui, Xiangkun Meng, Ying Chen, Yonghong Liu, Lei Yu. Preparation of L-Lactide with High Optical Purity via the Zinc-Doped Polypyrrole-Catalyzed Lactic Acid Condensation [J]. Chinese Journal of Organic Chemistry, 2022, 42(9): 2954-2960.
[10]	Shouyi Cen, Zhipeng Zhang. Synthesis of Biphenanthrol-Based Confined Chiral Phosphoric Acid [J]. Chinese Journal of Organic Chemistry, 2022, 42(8): 2574-2581.
[11]	Runye Gao, Lingling Zuo, Fang Wang, Chuanying Li, Huajiang Jiang, Pinhua Li, Lei Wang. Recent Advances in Controllable Organic Reactions Induced by Visible Light without External Photocatalyst [J]. Chinese Journal of Organic Chemistry, 2022, 42(7): 1883-1903.
[12]	Tao Li, Yi Liu, Xue Bai, Zunjun Zhou, Peng Zuo, Miaofeng Ma, Chong-Min Zhong, Ya-Jie Zuo. Preparation of Imidazolium Ion Functionalized HG-II Chiral Ruthenium Catalysts and Their Catalytic Performance in Asymmetric Olefin Metathesis [J]. Chinese Journal of Organic Chemistry, 2022, 42(6): 1713-1721.
[13]	Haojie Ma, Fengyuan Zhou, Jinlei Liu, Bo Han, Hua Yang, Yuqi Zhang, Jijiang Wang. Construction of Substituted N-Phenylpyrazoles via a Catalyst- Free and Additive-Free Intermolecular Cyclization Process [J]. Chinese Journal of Organic Chemistry, 2022, 42(6): 1843-1848.
[14]	Zhihao Zhang, Xin Jiang, Qinghan Li. Recent Progress in the Synthesis of Substituted Benzo[b]furan Derivatives [J]. Chinese Journal of Organic Chemistry, 2022, 42(4): 945-964.
[15]	Siyi Ding, Weisai Zu, Zongcheng Miao, Liang Xu. Synthetic and Computational Study of Four-Coordinate B,B-Diaryl 8-Aminoquinolate Complexes [J]. Chinese Journal of Organic Chemistry, 2022, 42(3): 812-818.

新型含氮三齿钯(II)配合物的合成及其催化性能研究

Synthesis of a New Pd(II) Complex with Tridentate Nitrogen Ligands and Investigation of Its Catalytic Property

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments