Synthesis of Acetals and Ketals Catalyzed by Dibutyltin(IV)  Sulfonates

Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (10): 1792-1796. Previous Articles Next Articles

Reports

二丁基锡(IV)磺酸酯催化合成缩醛(酮)

赵立芳* ; 王宏社 ; 苗建英

(宝鸡文理学院化学化工系宝鸡 721007)

收稿日期:2007-11-25 修回日期:2008-03-17 发布日期:2008-10-20
通讯作者: 赵立芳

Synthesis of Acetals and Ketals Catalyzed by Dibutyltin(IV) Sulfonates

ZHAO, Li-Fang* ; WANG, Hong-She; MIAO, Jian-Ying

(Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Baoji 721007)

Received:2007-11-25 Revised:2008-03-17 Published:2008-10-20
Contact: ZHAO, Li-Fang

Abstract

The reaction of dibutyltin oxide with benzenesulfonic acid or methylsufonic acid gave two new dibutyltin(IV) sulfonates which can be used as the catalysts for the synthesis of acetals and ketals. The opti-mal reaction conditions were obtained by orthogonal experiments. The advantages of the present procedure are high yields and short reaction time. Furthermore, the catalysts could be recovered easily by filtration and reused efficiently.

Key words: dibutyltin(IV) sulfonate, organotin compound, acetal and ketal, catalysis

Cite this article

ZHAO, Li-Fang* ; WANG, Hong-She; MIAO, Jian-Ying. Synthesis of Acetals and Ketals Catalyzed by Dibutyltin(IV) Sulfonates[J]. Chin. J. Org. Chem., 2008, 28(10): 1792-1796.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Fakai Zou, Nengzhong Wang, Hui Yao, Hui Wang, Mingguo Liu, Nianyu Huang. Regio- and Stereo-selective Synthesis of 1β-/3R-Aryl Thiosugar [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 593-604.
[2]	Jiyu Liu, Shengyu Li, Kuan Chen, Yin Zhu, Yuan Zhang. Triphenylamine-Based Ordered Mesoporous Polymer as a Metal-Free Photocatalyst for Oxidation of Thiols to Disulfide [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 605-612.
[3]	Shuang Yang, Xinqiang Fang. Kinetic Resolutions Enabled by N-Heterocyclic Carbene Catalysis: An Update [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 448-480.
[4]	Luyao Li, Zhongwen He, Zhenguo Zhang, Zhenhua Jia, Teck-Peng Loh. Application of Triaryl Carbenium in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 421-437.
[5]	Wanting Chen, Xiongwei Zhong, Jiale Xing, Changshu Wu, Yang Gao. Progress in Asymmetric Catalytic Synthesis of C—N Axis Chiral Compounds [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 349-377.
[6]	Jing Huang, Yihua Yang, Zhanhui Zhang, Shouxin Liu. Recent Progress on Green Methods and Technologies for Efficient Formation of Amide Bonds [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 409-420.
[7]	Qinggang Mei, Qinghan Li. Recent Progress of Visible Light-Induced the Synthesis of C(3) (Hetero)arylthio Indole Compounds [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 398-408.
[8]	Yang Li, Yanan Dong, Yuehui Li. Efficient Synthesis of Nitrile Compounds through Amide Conversion via N-Boroamide Intermediates [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 638-643.
[9]	Sida Li, Xin Cui, Xing-Zhong Shu, Lipeng Wu. Titanium-Catalyzed Synthesis of 1,1-Diborylalkanes from Aryl Alkenes [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 631-637.
[10]	Mengzhu Li, Boying Meng, Wenjie Lan, Bin Fu. Synthesis of 2,3-Disubstituted Dihydrobenzofurans from o-Quinone Methides and Sulfur Ylides [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 195-203.
[11]	Hong'en Tong, Hongyu Guo, Rong Zhou. Progress on Visible-Light Promoted Addition Reactions of Inert C—H Bonds to Carbonyls [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 54-69.
[12]	Yanshuo Zhu, Hongyan Wang, Penghua Shu, Ke'na Zhang, Qilin Wang. Recent Advances on Alkoxy Radicals-Mediated C(sp³)—H Bond Functionalization via 1,5-Hydrogen Atom Transfer [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 1-17.
[13]	Hongqiong Zhao, Miao Yu, Dongxue Song, Qi Jia, Yingjie Liu, Yubin Ji, Ying Xu. Progress on Decarboxylation and Hydroxylation of Carboxylic Acids [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 70-84.
[14]	Yukun Jin, Baoyi Ren, Fushun Liang. Visible Light-Mediated Selective C—F Bond Cleavage of Trifluoromethyl Groups and Its Application in Synthesizing gem-Difluoro-Containing Compounds [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 85-110.
[15]	Quanbin Jiang. Progress in Synthesis of Axially Chiral Compounds through aza-Vinylidene o-Quinone Methide Intermediates [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 159-172.

二丁基锡(IV)磺酸酯催化合成缩醛(酮)

Synthesis of Acetals and Ketals Catalyzed by Dibutyltin(IV) Sulfonates

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments