Friedel-Crafts Reaction of Ferrocenyl Alcohol Catalyzed by [BPy][HSO4] in Water Phase

doi:10.6023/cjoc201301057

Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (04): 835-839.DOI: 10.6023/cjoc201301057 Previous Articles Next Articles

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水相中[BPy][HSO₄]离子液体催化二茂铁醇的类Friedel-Crafts反应

盛万里^a, 田福利^a, 杜玉英^b, 吴春雨^a

a 内蒙古大学化学化工学院呼和浩特 010021;
b 内蒙古工业大学化工学院呼和浩特 010051

收稿日期:2013-01-23 修回日期:2013-03-06 发布日期:2013-03-14
通讯作者: 田福利, 杜玉英 E-mail:ftian@imu.edu.com
基金资助:
国家自然科学基金(No. 21265010)资助项目.

Friedel-Crafts Reaction of Ferrocenyl Alcohol Catalyzed by [BPy][HSO₄] in Water Phase

Sheng Wanli^a, Tian Fuli^a, Du Yuying^b, Wu Chunyu^a

a Department of Chemistry, College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021;
b Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051

Received:2013-01-23 Revised:2013-03-06 Published:2013-03-14
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21265010).

A novel, environment friendly and efficient methodology for the synthesis of a series of ferrocenyl compounds using the functionalized acid ionic liquid [BPy][HSO₄] as catalyst in water under mild conditions is reported. The Friedel-Crafts reaction of ferrocenyl alcohol with nucleophiles could be carried out efficiently in an “aqueous dispersion” and the corresponding ferrocenyl compounds were obtained in good to excellent yields. Suitable crystal of 3i was obtained, and the X-ray diffraction analysis indicated that compound 3i belonged to triclinic, space group P-1. The procedure reported here has the advantages of mild reaction conditions, high yields, operational simplicity and catalyst recyclability.

Key words: [BPy][HSO₄] ionic liquid, Friedel-Crafts recation, catalysis, crystal structure

Cite this article

Sheng Wanli, Tian Fuli, Du Yuying, Wu Chunyu. Friedel-Crafts Reaction of Ferrocenyl Alcohol Catalyzed by [BPy][HSO₄] in Water Phase[J]. Chin. J. Org. Chem., 2013, 33(04): 835-839.

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水相中[BPy][HSO₄]离子液体催化二茂铁醇的类Friedel-Crafts反应

Friedel-Crafts Reaction of Ferrocenyl Alcohol Catalyzed by [BPy][HSO₄] in Water Phase

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水相中[BPy][HSO4]离子液体催化二茂铁醇的类Friedel-Crafts反应