Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (7): 1835-1846.DOI: 10.6023/cjoc202003010 Previous Articles     Next Articles

负载型功能离子液体在有机合成中的应用研究进展

李胜男a, 赵雯辛a, 刘玉静a, 刘中秋a, 应安国a,b   

  1. a 曲阜师范大学化学与化工学院 山东曲阜 273100;
    b 台州学院医药化工学院 浙江台州 318000
  • 收稿日期:2020-03-05 修回日期:2020-04-09 发布日期:2020-04-30
  • 通讯作者: 刘中秋, 应安国 E-mail:yinganguo@163.com;liuzhongqiuzs@126.com
  • 基金资助:
    国家自然科学基金(Nos.21978154,21576176)和国家级大学生创新创业训练计划(No.201910446018)资助项目.

Research Progress in the Application of Supported Functional Ionic Liquids in Organic Transformations

Li Shengnana, Zhao Wenxina, Liu Yujinga, Liu Zhongqiua, Ying Anguoa,b   

  1. a Department of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shandong 273100;
    b School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou, Zhejiang 318000
  • Received:2020-03-05 Revised:2020-04-09 Published:2020-04-30
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Nos. 21978154, 21576176) and the National Students' Platform for Innovation and Entrepreneurship Training Programs (No. 201910446018).

Ionic liquids (ILs) have been widely used because of their excellent physical and chemical properties, and environment-friendly properties. However, the high viscosity of ILs causes difficulties in post-reaction separation and low recyclability. As the combination of ionic liquids with a variety of solid materials, supported functional ILs (SFILs) have the coupled advantages of ILs and loaded materials. It has a wide range of applications in the field of catalysis because of its high recovery performance, green economy and high efficiency. This paper mainly reviews the recent achievements over SFILs in respects of the preparation of ILs supported on various carriers like magnetic nanoparticles, graphene oxide, molecular sieves, organic-metal skeleton etc., the applications as the heterogeneous catalysts to organic transformations, and the understanding of the catalytic mechanism.

Key words: ionic liquids, carriers, green chemistry, catalysis, environmentally-friendly