Synthesis of Novel Porous Organic Materials Based on Phloroglucinol and Its Derivatives

doi:10.6023/cjoc202005070

Abstract

Porous organic materials have found many applications, such as catalysis, energy, adsorption and separation., owing to the high specific surface area, pore channel tunability, easy functionalization and structural diversity. The careful selection of specific monomers with polyfunctionality and highly efficient polymerization provides powerful tools for creating novel porous organic materials, and it has become a research topic in this field. Herein the latest progress in the efficient construction of novel porous organic materials is reviewed taking C₃ symmetrical phloroglucinol and its derivatives as examples.

Key words: phoroglucinol, porous organic polymer, metal organic framework, covalent organic framework, functionalization

Cite this article

Hanlin Deng, Xiansheng Luo, Zhihua Li, Jiangying Zhao, Muhua Huang. Synthesis of Novel Porous Organic Materials Based on Phloroglucinol and Its Derivatives[J]. Chinese Journal of Organic Chemistry, 2021, 41(2): 624-641.

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Entry	Polymer	S_BET/(m²?g^–1)	Mean pore size/nm	V_tot/(g?cm^–3)
1^[62]	CE-P2	195	3.39	0.198
2^[63]	CTF-IP10	358	—	0.22
3^[65]	COP-36	11	—	0.032
4^[66]	Si(OAc)₄-based	990	3.51	0.84
5^[66]	HSi(OAc)₃-based	933	5.99	1.36
6^[66]	MeSi(OAc)₃-based	455	2.73	0.285
7^[67]	BoxPOP-1	231	—	0.98
8^[67]	BoxPOP-2	225	—	0.74
9^[67]	BoxPOP-3	46	—	0.17
10^[68]	CPF-T	654	—	0.33

Entry	Polymer	S_BET/(m²?g^–1)	Mean pore size/nm	V_tot/(g?cm^–3)
1^[62]	CE-P2	195	3.39	0.198
2^[63]	CTF-IP10	358	—	0.22
3^[65]	COP-36	11	—	0.032
4^[66]	Si(OAc)₄-based	990	3.51	0.84
5^[66]	HSi(OAc)₃-based	933	5.99	1.36
6^[66]	MeSi(OAc)₃-based	455	2.73	0.285
7^[67]	BoxPOP-1	231	—	0.98
8^[67]	BoxPOP-2	225	—	0.74
9^[67]	BoxPOP-3	46	—	0.17
10^[68]	CPF-T	654	—	0.33

Entry	Polymer	S_BET/(m²?g^–1)	Mean pore size/nm	V_tot/(g?cm^–3)
1^[69]	POF1B, POF1A	917, 773	0.6	—
2^[69]	POF2B, POF2A	769, 658	0.6	—
3^[69]	POF3B, POF3A	608, 115	0.6, —	—
4^[70]	MesoPOF-1	1027	—	0.86
5^[71]	PRP-1	835	—	—
6^[73]	POF-1S	29	—	—
7^[72]	PTF-Cr	106	—	—
8^[72]	PTF-Mg	128	—	—
9^[74]	POF-1ES	57	—	—
10^[76]	HROP	568	—	0.80

Entry	Polymer	S_BET/(m²?g^–1)	Mean pore size/nm	V_tot/(g?cm^–3)
1^[69]	POF1B, POF1A	917, 773	0.6	—
2^[69]	POF2B, POF2A	769, 658	0.6	—
3^[69]	POF3B, POF3A	608, 115	0.6, —	—
4^[70]	MesoPOF-1	1027	—	0.86
5^[71]	PRP-1	835	—	—
6^[73]	POF-1S	29	—	—
7^[72]	PTF-Cr	106	—	—
8^[72]	PTF-Mg	128	—	—
9^[74]	POF-1ES	57	—	—
10^[76]	HROP	568	—	0.80

Entry	Polymer	S_BET/(m²?g^–1)	Mean pore size/nm	V_tot/(g?cm^–3)
1^[77]	HAzo-POP-1	256	—	1.325
2^[77]	HAzo-POP-3	418	—	1.730
3^[79]	Co^Ⅱ-NDI-PG, NDI-PG	88, 93	—	—
4^[80]	Ag@AzoTPE-CMP, AzoTPE-CMP	47, 366	—	0.110, 1.072
5^[81]	TAP1	474	—	0.74
6^[81]	TAP2	772	—	1.41
7^[81]	TAP3	729	—	1.04
8^[22]	TKH-POP-2	437	—	1.4
9^[22]	TKH-POP-3	552	—	2.3
10^[22]	TKH-POP-4	639	—	2.2

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