Chinese Journal of Organic Chemistry ›› 2022, Vol. 42 ›› Issue (5): 1537-1544.DOI: 10.6023/cjoc202112024 Previous Articles Next Articles
Special Issue: 有机氟化学虚拟合辑
ARTICLES
顾清云, 程振凤, 曾小宝*(
)
收稿日期:2021-12-19
修回日期:2022-01-04
发布日期:2022-01-20
通讯作者:
曾小宝
基金资助:
Qingyun Gu, Zhenfeng Cheng, Xiaobao Zeng()
Received:2021-12-19
Revised:2022-01-04
Published:2022-01-20
Contact:
Xiaobao Zeng
Supported by:Share
Qingyun Gu, Zhenfeng Cheng, Xiaobao Zeng. Electrochemical Oxidative Trifluoromethylation of α-Oxoketene Ketene Dithioacetals with CF3SO2Na[J]. Chinese Journal of Organic Chemistry, 2022, 42(5): 1537-1544.
| Entry | Variation from the standard conditions | Yieldb/% |
|---|---|---|
| 1 | None | 77 |
| 2 | C felt (+) | C felt(–) Instead of C felt (+) | Fe (–) | Trace |
| 3 | C felt (+) | Ni felt(–) Instead of C felt (+) | Fe (–) | 62 |
| 4 | n-Bu4NPF6 instead of n-Bu4NClO4 | 74 |
| 5 | n-Bu4NBF4 instead of n-Bu4NClO4 | 71 |
| 6 | Without electrolyte | 61 |
| 7 | DCE instead of MeCN | Trace |
| 8 | DMF instead of MeCN | Trace |
| 9 | AcOH instead of MeCN | 52 |
| 10 | Without H2O | 60 |
| 11 | H2O (20 equiv.) | 75 |
| 12 | 50 ℃ instead of r.t. | 45 |
| 13 | 2a (2 equiv.) | 35 |
| 14 | 5 mA instead of 10 mA | 57 |
| 15 | TMSCF3 instead of CF3SO2Na | Trace |
| 16 | No electric current | N.R. |
| 17 | n-Bu4NClO4 (2 equiv.) | 73 |
| Entry | Variation from the standard conditions | Yieldb/% |
|---|---|---|
| 1 | None | 77 |
| 2 | C felt (+) | C felt(–) Instead of C felt (+) | Fe (–) | Trace |
| 3 | C felt (+) | Ni felt(–) Instead of C felt (+) | Fe (–) | 62 |
| 4 | n-Bu4NPF6 instead of n-Bu4NClO4 | 74 |
| 5 | n-Bu4NBF4 instead of n-Bu4NClO4 | 71 |
| 6 | Without electrolyte | 61 |
| 7 | DCE instead of MeCN | Trace |
| 8 | DMF instead of MeCN | Trace |
| 9 | AcOH instead of MeCN | 52 |
| 10 | Without H2O | 60 |
| 11 | H2O (20 equiv.) | 75 |
| 12 | 50 ℃ instead of r.t. | 45 |
| 13 | 2a (2 equiv.) | 35 |
| 14 | 5 mA instead of 10 mA | 57 |
| 15 | TMSCF3 instead of CF3SO2Na | Trace |
| 16 | No electric current | N.R. |
| 17 | n-Bu4NClO4 (2 equiv.) | 73 |
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