Chinese Journal of Organic Chemistry 2022, 42(10)

- About the Cover:
  
  Replacement of noble-metals by earth-abundant and biocompatible first-row transition metals (manganese, iron, cobalt, nickel, etc.) for the development of new catalysts in asymmetric hydrogenation reactions is of great significance towards sustainable synthesis of chiral N-containing fine chemicals. An overview of earth- abundant metal catalyzed asymmetric hydrogenation of carbon-nitrogen unsaturated bonds categorized according to the types of central meals in catalysts is provided by Liu and Liu on page 3213.
- About the Cover:
  
  Heteroatom-dipole precursors designed based on transi-tion metal-catalyzed allyl or propargyl substitutions have been extensively studied in the past two decades. The research progress in transition metal-catalyzed asymmetric cyclizations with these precursors is summarized by Zhang, Chen, Wang, Sheng, Liu and Deng on page 3051.
- About the Cover:
  
  Metal carbenes have been widely applied in organic synthesis, and they can undergo a variety of chemical transformations due to their versatile reactivities. Ac-cording to the different reaction types of metal carbenes, the desymmetrization of C—H insertion reaction, Bu-chner reaction, Si—H insertion reaction and B—H in-sertion reaction involving metal carbenes is introduced by Teng, Han, Huang, and Ye on page 3295.
- About the Cover:
  
  Compared with traditional redox-neutral alkene difunc-tionalization, the reductive difunctionalization of alkenes can introduce two different electrophiles to both sides of the carbon-carbon double bond, which has the advantages of mild reaction conditions, high functional group tolerance, and no need for pre-prepared organometallic reagents. The latest research progress in nickel- catalyzed reductive difunctionalization of alkenes is summarized by Ping, Song, and Kong on page 3302.
2022, 42(10)

25 October 2022
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ACCOUNT

Application of Chiral Lewis Base/Brønsted Acid Synergistic Catalysis Strategy in Enantioselective Synthesis of Organic Sulfides

Deng Zhu, Zhi-Min Chen

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3015-3032 DOI: 10.6023/cjoc202208032

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REVIEWS

Asymmetric Tandem Reactions Achieved by Chiral Amine & Gold(I) Cooperative Catalysis

Xiaoyuan Cui, Feng Zhou, Haihong Wu, Jian Zhou

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3033-3050 DOI: 10.6023/cjoc202209016

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Transition Metal-Catalyzed Asymmetric Cyclizations Involving Allyl or Propargyl Heteroatom-Dipole Precursors

Jian Zhang, Ying Chen, Quannan Wang, Jiahuan Shen, Yangzi Liu, Weiping Deng

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3051-3101 DOI: 10.6023/cjoc202206028

Abstract( 986) HTML( 47) PDF(2019KB)( 1330 )

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Advances of Chiral Spiro Skeleton-Based Bisnitrogen Ligands in Transition-Metal Catalysis

Xudong Hu, Xinliang Zhang, Wenbo Liu

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3102-3117 DOI: 10.6023/cjoc202210010

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REVIEWS

Development of P, S and Si-Stereogenic Compounds Synthesis via Palladium Catalysis

Jieming Zhang, Hang Ni, Qi Wu, Junfeng Yang, Junliang Zhang

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3118-3128 DOI: 10.6023/cjoc202208043

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Progress in Synthesis of Nitrogen Heterocycles Catalyzed by Chiral Phosphine

Hongxia Ren, Mengmeng Ma, You Huang

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3129-3142 DOI: 10.6023/cjoc202208024

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Chiral Borane-Catalyzed Enantioselective Reactions

Xin Li, Qiuling Song

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3143-3151 DOI: 10.6023/cjoc202208018

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Research Advance on Enantioselective Transition Metal-Catalyzed Hydroacylation Reactions

Haorui Wang, Mengchun Ye

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3152-3166 DOI: 10.6023/cjoc202207036

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Transition Metal Catalyzed Asymmetric Hydroboration of Internal Alkenes

Houxiang Lu, Bijie Li

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3167-3182 DOI: 10.6023/cjoc202207040

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Research Progress on Catalytic Asymmetric Synthesis of P-Chiral Compounds

Hui Li, Liang Yin

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3183-3200 DOI: 10.6023/cjoc202208002

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Recent Advances in Photocatalytic Deracemization

Yiwen Su, Youquan Zou, Wenjing Xiao

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3201-3212 DOI: 10.6023/cjoc202207046

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Earth-Abundant Metal-Catalyzed Asymmetric Hydrogenation of Carbon-Nitrogen Unsaturated Bonds

Chenguang Liu, Qiang Liu

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3213-3220 DOI: 10.6023/cjoc202208003

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Progress in Asymmetric Catalytic Reduction of Diketones

Yuxuan Zhang, Limin Xu, Yan Lu, Zhaoguo Zhang

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3221-3239 DOI: 10.6023/cjoc202207045

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Progress in Transition Metal-Catalyzed Asymmetric Ring-Opening Reactions of Epoxides and Aziridines

Qingfeng Du, Lu Zhang, Feng Gao, Le Wang, Wanbin Zhang

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3240-3262 DOI: 10.6023/cjoc202207034

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Recent Progress in Upgrading of Alcohol and Amine via Asymmetric Dehydrogenative Coupling

Binyang Jiang, Shi-Liang Shi

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3263-3279 DOI: 10.6023/cjoc202207002

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Recent Advances in Synthesis of Chiral Tertiary Amines via Asymmetric Catalysis Involving Metal-Hydride Species

Tianxiang Fan, Yuanyuan Liu

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3280-3294 DOI: 10.6023/cjoc202206032

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Research Progress on Enantioselective Desymmetrization Reactions Involving Metal Carbenes

Ming-Yu Teng, Tao Han, En-He Huang, Long-Wu Ye

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3295-3301 DOI: 10.6023/cjoc202206041

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Recent Advances in Ni-Catalyzed Asymmetric Reductive Difunctionalization of Alkenes

Yuanyuan Ping, Haixia Song, Wangqing Kong

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3302-3321 DOI: 10.6023/cjoc202205046

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Recent Advances in Catalytic Asymmetric 1,3-Dipolar Cycloaddition Reactions with Kinetic Resolution

Huachao Liu, Chong Shen, Xin Chang, Chunjiang Wang

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3322-3334 DOI: 10.6023/cjoc202205037

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Recent Advances in Visible-Light Photocatalytic Asymmetric Synthesis Enabled by Chiral Lewis Acids

Xiuliang Cheng, Dong Li, Boxuan Yang, Yumei Lin, Lei Gong

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3335-3350 DOI: 10.6023/cjoc202205032

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Advances in Catalytic Asymmetric Reactions Using 2-Indolylmethanols as Platform Molecules

Honghao Zhang, Feng Shi

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3351-3372 DOI: 10.6023/cjoc202203018

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ARTICLES

Pd/Novel Axially Chiral Phosphine-Alkene Ligands Catalyzed Asymmetric Allylic Alkylation of Indoles

Shihu Jia, Siyuan Chen, Zeshui Liu, Honggang Cheng, Qianghui Zhou

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3373-3381 DOI: 10.6023/cjoc202209002

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Asymmetric Palladium-Catalyzed Aza-Wacker Reaction of Alkenes: Efficient Synthesis of Chiral 1,3-Oxazinan-2-ones

Xintuo Yang, Pinhong Chen, Guosheng Liu

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3382-3389 DOI: 10.6023/cjoc202208021

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Dirhodium/Xantphos-Catalyzed Tandem C—H Functionalization/Allylic Alkylation: Direct Access to 3-Acyl-3-allyl Oxindole Derivatives from N-Aryl-α-diazo-β-keto Amides

Fangjie Li, Bin Lu, Yang Liu, Xiaoming Wang

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3390-3397 DOI: 10.6023/cjoc202206053

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Electrochemical Oxidative Cross-Dehydrogenative Coupling of Five-Membered Aromatic Heterocycles with NH₄SCN

Hongxia Li, Peng Chen, Zhilin Wu, Yuhan Lu, Junmei Peng, Jingyang Chen, Weimin He

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3398-3404 DOI: 10.6023/cjoc202207009

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Pd(II)-Catalyzed Enantioselective C—H Olefination of 2-(Arylsulfinyl)pyridines through Kinetic Resolution

Lingjie Fan, Tao Zhou, Xu Yang, Mengxue Jiang, Xinquan Hu, Bingfeng Shi

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3405-3418 DOI: 10.6023/cjoc202204058

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HIGHLIGHTS

Rhodium-Catalyzed Asymmetric Hydrogenation of All-Carbon Aromatic Rings

Nan Wang, Wenjun Tang

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3419-3420 DOI: 10.6023/cjoc202200053

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Transition-Metal-Free, Electrophotocatalyzed Selective C—F Arylation of Polyfluoroarenes

Kejin Jiao, Tiansheng Mei

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3421-3422 DOI: 10.6023/cjoc202200054

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Selective Trifluoromethiolation and Difluoromethiolation of Pyridines at C(3) Position

Feng Chen, Fengling Qing

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3423-3424 DOI: 10.6023/cjoc202200055

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Copper-Catalyzed Z-Selective Synthesis of Acrylamides and Polyacrylamides via Alkylidene Ketenimines

Mingyi Jiang, Xiaohua Liu

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3425-3426 DOI: 10.6023/cjoc202200056

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Electrocarboxylation of Aryl Epoxides with CO₂ to Selectively Synthesize β-Hydroxy Acids

Wenjun Xie, Liangnian He

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3427-3428 DOI: 10.6023/cjoc202200057

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Enantioselective Radical Deuteration of Non-Benzylic Positions via Visible Light Catalysis

Bin Zhang, Jiarong Chen

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3429-3430 DOI: 10.6023/cjoc202200058

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Organosulfide-Catalyzed Enantioselective Intermolecular Iodinative Difunctionalization of Allylic Sulfonamides

Ren-Fei Cao, Zhi-Min Chen

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3431-3433 DOI: 10.6023/cjoc202200059

Abstract( 308) HTML( 8) PDF(576KB)( 422 )

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Stepwise Construction of All-Carbon Quaternary Centers Starting from Activated Trichloromethyl Group in Three Steps

Xinglei He, Keyin Ye

Chinese Journal of Organic Chemistry 2022, 42 (10), pp 3434-3435 DOI: 10.6023/cjoc202200060

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