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封面介绍The Ni-catalyzed multi-component coupling of butadiene, aldehydes, alkynes, and Schwartz reagent has been reported by Li and Shi on page 1939. Various skipped dienes were readily synthesized under mild reaction conditions with excellent regio- and stereoselectivity and good functional group tolerance.
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封面介绍The palladium-catalyzed allylic carbonylative reaction with alkyl zinc reagents employing sterically bulky aromatic isocyanides as the CO surrogate has been reported by Weng, Qu and Chen on page 1949. Various synthetically important β,γ-unsaturated ketones were afforded with excellent regio- and seteroselectivities under mild conditions without undesirable β-H elimination.
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