有机化学 ›› 2015, Vol. 35 ›› Issue (5): 961-974.DOI: 10.6023/cjoc201407022 上一篇    下一篇

综述与进展

负载型氮杂环卡宾钯络合物催化C—C偶联反应新进展

袁定重a,b, 张庆华c, 廖世军b, 熊文文b, 元利刚b, 蔡奇胜b, 杨梦梅b, 李雄b, 蒋烨佳b, 刘妍b, 李萍b, 徐贞帅b, 孙盼盼b, 耿会玲d   

  1. a 核资源与环境省部共建国家重点实验室培育基地东华理工大学 南昌 330013;
    b 东华理工大学材料系 南昌 330013;
    c 东华理工大学建筑学院 南昌 330013;
    d 西北农林科技大学理学院 杨凌 712100
  • 收稿日期:2014-11-22 修回日期:2014-12-21 出版日期:2015-05-25 发布日期:2015-01-06
  • 通讯作者: 袁定重, 耿会玲 E-mail:ydz3214@126.com
  • 基金资助:

    江西省自然科学基金(No.20114BAB213011)、江西省教育厅基金(No.GJJ13447)、核资源与环境重点实验室(东华理工大学)开放基金(No.NRE1315)、东华理工大学博士科研启动基金(No.DHBK1010)、核资源与环境省部共建国家重点实验室培育基地(东华理工大学)开放基金(No.NRE1315)、国家自然科学基金(No.31101469)、新世纪优秀人才支持计划(No.NCET-12-0475)、陕西省青年科技新星(No.2012KJXX-16)、中央高校基本科研业务费(No.QN2011035)资助项目.

New Progress in C—C Coupling Reactions Catalyzed by Supported N-Heterocyclic Carbene Palladium Complex

Yuan Dingzhonga,b, Zhang Qinghuac, Liao Shijunb, Xiong Wenwenb, Yuan Ligangb, Cai Qishengb, Yang Mengmeib, Li Xiongb, Jiang Yejiab, Liu Yanb, Li Pingb, Xu Zhenshuaib, Sun Panpanb, Geng Huilingd   

  1. a State Key Laboratory Breeding Base of Nuclear Resources and Environment, East China Institute of Technology, Nanchang 330013;
    b Department of Materials Science and Engineering, East China Institute of Technology, Nanchang 330013;
    c College of Civil and Environment Engineering, East China Institute of Technology, Nanchang 330013;
    d School of Science, Northwest A&F University, Yangling 712100
  • Received:2014-11-22 Revised:2014-12-21 Online:2015-05-25 Published:2015-01-06
  • Supported by:

    Project supported by the Natural Science Foundation of Jiangxi Province (No.20114BAB213011), the Science and Technology Project of Jiangxi Provincial Department of Education (No.GJJ13447), the Open foundation of Key Laboratory of Nuclear Resources and Environment (East China Institute of Technology) (No.NRE1315), the Doctoral Scientific Research Foundation of East China of Technology (No.DHBK1010), the State Key Laboratory Breeding Base of Nuclear Resources and Environment (No.NRE1315), the National Natural Science Foundation of China (No.31101469), the New Century Excellent Talents by Ministry of Education of China (No.NCET-12-0475), the Fund of Youth Science and Technology Stars by Shaanxi Province (No.2012KJXX-16), and the Fundamental Research Funds for the Central Universities (No.QN2011035).

负载型氮杂环卡宾钯催化的C—C偶联反应由于具有反应活性高, 催化剂便于分离和可重复使用等特点, 已引起了人们的广泛关注. 负载型氮杂环卡宾钯催化剂中的载体材料对催化性能和重复使用性能具有较大的影响. 综述了不同类型载体材料制备的负载型氮杂环卡宾钯催化C—C偶联反应的研究进展, 载体类型包括聚合物材料、硅材料、碳材料和磁性纳米粒子材料. 此外, 还对负载型氮杂环卡宾钯催化剂未来的发展前景进行了展望.

关键词: C—C偶联反应, 氮杂环卡宾, 负载型催化剂, 钯催化

The C—C coupling reactions catalyzed by supported N-heterocyclic carbene palladium complex have attracted considerable attention because catalytic activity is excellent and supported catalyst can be separated easily and reused several times. The performance of the carriers has an important effect on the catalytic activity and reusability of the supported catalyst. In this paper, the advances in the C—C coupling reactions catalyzed by supported N-eterocyclic carbene palladium complex have been reviewed. Polymer, silica, carbon and magnetic nanoparticles were used to support the N-heterocyclic carbene palladium catalysts. Finally, the direction of the supported N-heterocyclic carbene palladium complex was also put forward.

Key words: C—C coupling reaction, N-heterocyclic carbene, supported catalyst, palladium catalysis