手性金属有机化合物催化丙交酯聚合反应研究进展

doi:10.6023/cjoc201612011

摘要/Abstract

聚丙交酯因其具有良好的生物相容性、生物可降解性和可再生性，近年来引起了人们的广泛关注.利用手性金属有机化合物催化丙交酯的立体选择性开环聚合反应成为该研究的热点之一.主要介绍了手性金属有机化合物催化丙交酯开环聚合反应的研究进展.

Polylactides have received considerable attention in recent years due to their outstanding properties such as biocompatibility, biodegradability, and renewability. In particular, the studies on ring opening polymerization (ROP) of lactides in stereoselective manner catalyzed by chiral organometallic complexes have been regarded as one of the most significant fields in the synthesis of polylactides. The important advances in the ROP of lactides catalyzed by chiral organometallic complexes are reviewed in this article.

Key words: chiral organometallic complexes, catalysis, polymerization of lactides

引用此文

赵宁. 手性金属有机化合物催化丙交酯聚合反应研究进展[J]. 有机化学, 2017, 37(5): 1139-1159.

Zhao Ning. Progress in Ring Opening Polymerization of Lactides Catalyzed by Chiral Organometallic Complexes[J]. Chin. J. Org. Chem., 2017, 37(5): 1139-1159.

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