有机化学 ›› 2005, Vol. 25 ›› Issue (01): 34-41. 上一篇    下一篇

研究论文

醛的不对称烯丙基化反应研究进展

王成,尹红,陈万锁*,陈志荣   

  1. (浙江大学化工系 杭州 310027)
  • 收稿日期:2004-02-09 修回日期:2001-06-01 发布日期:2004-12-30
  • 通讯作者: 陈万锁

Recent Developments in the Asymmetric Allylation of Aldehydes

WANG Cheng,YIN Hong,CHEN Wan-Suo*,CHEN Zhi-Rong   

  1. (Department of Chemical Engineering, Zhejiang University, Hangzhou 310027)
  • Received:2004-02-09 Revised:2001-06-01 Published:2004-12-30
  • Contact: CHEN Wan-Suo

醛的不对称烯丙基化反应是合成手性烯丙基醇的一类重要方法, 从手性辅基控制反应和化学催化不对称反应两个方面对近20多年来的相关报道进行综述.

关键词: 醛, 不对称, 烯丙基化反应

The asymmetric allylation of aldehydes is one of the most important methods for preparation of chiral homoallylic alcohol, which is a building block in organic synthesis. Herein, the new developments are summarized in two directions, one of which is the chrial auxiliary controlling reaction, and the other is the catalytic asymmetric allylation reaction.

Key words: asymmetric, aldehyde, allylation