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有机化学
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有机化学 ›› 2010, Vol. 30 ›› Issue (04): 506-514. 上一篇    下一篇

综述与进展

铱催化环加成反应的研究进展

边红旭,杨定乔   

  1. (华南师范大学化学与环境学院 广州 510006)
  • 收稿日期:2009-03-30 修回日期:2009-06-27 发布日期:2010-04-28
  • 通讯作者: 杨定乔 E-mail:yangdq@scnu.edu.cn,zqwlh@126.com
  • 基金资助:

    国家级.国家自然科学基金

Progress of Iridium-Catalyzed Cycloaddition Reactions

Bian Hongxu Yang Dingqiao   

  1. (School of Chemistry and Environment, South China Normal University, Guangzhou 51006)
  • Received:2009-03-30 Revised:2009-06-27 Published:2010-04-28
  • Contact: Yang Ding-qiao E-mail:yangdq@scnu.edu.cn,zqwlh@126.com

PDF

2269

被引次数

9 | 4

过渡金属催化环加成反应是合成单环及多环化合物的重要方法, 也是有机化学的研究热点之一. 综述了近年来铱催化环加成反应的研究进展, 主要包括了[2＋2＋1], [2＋2＋2], [4＋2], 1,3-偶极环加成反应等, 及少量关于[3＋2＋2], [3＋2], [5＋1]环加成反应的报道, 并讨论了部分铱催化环加成反应机理.

关键词: 铱催化, 环加成, 铱配合物

Transition metal-catalyzed cycloaddition reaction of unsaturated substances, such as alkynes and alkenes, is one of the most important methods for the synthesis of mono-ring and multi-ring systems. In this paper, the recent progress in iridium-catalyzed cycloaddition reactions is reviewed, mainly including [2＋ 2＋1], [2＋2＋2], [4＋2], 1,3-dipolar cycloaddition reactions. In addition, some iridium-catalyzed [3＋2＋2], [3＋2] and [5＋1] cycloaddition reactions are described. Some parts of cycloaddition reaction mechanisms are also discussed.

Key words: iridium catalysis, cycloaddition, iridium complex