有机化学 ›› 2019, Vol. 39 ›› Issue (9): 2443-2457.DOI: 10.6023/cjoc201901028 上一篇    下一篇

综述与进展

亚砜脱氧还原方法研究进展

李伟林, 陈炫颖, 郑天骄, 邹祺, 陈文博   

  1. 上海电力大学 上海市电力材料防护与新材料重点实验室 上海 200090
  • 收稿日期:2019-01-18 修回日期:2019-03-30 出版日期:2019-09-25 发布日期:2019-04-16
  • 通讯作者: 邹祺, 陈文博 E-mail:qzou@shiep.edu.cn;wenbochen@shiep.edu.cn
  • 基金资助:

    上海市自然科学基金(No.17ZR1447100)和上海市科学技术委员会(No.14DZ2261000)资助项目.

Research Progress on Reduction of Sulfoxides to Thiothers

Li Weilin, Chen Xuanying, Zheng Tianjiao, Zou Qi, Chen Wenbo   

  1. Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power, Shanghai University of Electric Power, Shanghai 200090
  • Received:2019-01-18 Revised:2019-03-30 Online:2019-09-25 Published:2019-04-16
  • Contact: 10.6023/cjoc201901028 E-mail:qzou@shiep.edu.cn;wenbochen@shiep.edu.cn
  • Supported by:

    Project supported by the Natural Science Foundation of Shanghai City (No. 17ZR1447100) and the Science and Technology Commission of Shanghai Munic-ipality (No. 14DZ2261000).

亚砜还原为硫醚作为有机合成中一类重要的转化,其应用一直受到人们的广泛关注.随着金属有机的发展,研究人员发展了许多条件温和、实用有效的亚砜还原方法.从还原剂的种类出发,详细介绍了近二十年里亚砜脱氧还原反应的研究进展,分析了这些还原体系所具有的优势及其潜在不足,并探讨了部分反应机理,最后对亚砜还原领域的发展进行了展望.

关键词: 亚砜, 脱氧还原, 硫醚, 研究进展

As one of the most important transformations in organic synthesis, deoxygenation reduction of sulfoxides to thioethers has attracted wide attention in researches and applications. With the development of organicmetallic chemistry, many mild and practical methods have been developed to reduce sulfoxides. In this review, based on the types of the reducing agents, the research progress on the deoxygenation reduction of sulfoxides to thiothers in recent 20 years is summarized. In addition, the advantages and disadvantages of these reduction systems, some reaction mechanisms and the prospects of research in this field are discussed.

Key words: sulfoxide, deoxygenation reduction, thioether, research progress