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封面介绍The development of catalytic asymmetric Si—H/X—H dehydrogenative coupling reaction (Si-CADC) to construct Si-stereogenic centers is reviewed by Zhao, Ge and He on page 3352. By using dihydrosilanes as the substrates, the Si-CADC strategy has successfully realized the synthesis of various highly functionalized Si-stereogenic silanes with high efficiency and enantioselectivity. Inside Cover -
封面介绍The synthesis of β-silyl substituted vinylphosphine oxides by using the dialkynylphosphine oxides and silaboronate is reported by Xu and coworkers on page 3598. By means of constructing the carbon-silicon bonds, the synthesis of substituted vinylphosphine oxides was realized via copper-catalyzed mono-protosilylation of diynes, affording the products in moderate and high yields with high chemo- and regioselectivity. -
封面介绍Density functional theory (DFT) calculations revealing how electronic effect of substituent affects regioselectivity in C—Si reductive elimination step is reported by Peng, He, Liao, Bai and Lan on page 3608. Electron density of aromatic ring is the main factor to control regioselectivity. Aromatic rings with higher electron density have higher priority for C—Si reductive elimination of Pd(IV) intermediate, and this is in accordance with electron flow in this elementary reaction.
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本期栏目
目录
综述与进展
有机化学
2023, 43 (10), pp 3339-3351
DOI: 10.6023/cjoc202305016
有机化学
2023, 43 (10), pp 3352-3366
DOI: 10.6023/cjoc202305001
有机化学
2023, 43 (10), pp 3367-3387
DOI: 10.6023/cjoc202304030
有机化学
2023, 43 (10), pp 3388-3413
DOI: 10.6023/cjoc202306027
有机化学
2023, 43 (10), pp 3414-3453
DOI: 10.6023/cjoc202307025
有机化学
2023, 43 (10), pp 3454-3469
DOI: 10.6023/cjoc202306028
有机化学
2023, 43 (10), pp 3470-3490
DOI: 10.6023/cjoc202307017
有机化学
2023, 43 (10), pp 3491-3507
DOI: 10.6023/cjoc202306024
有机化学
2023, 43 (10), pp 3508-3525
DOI: 10.6023/cjoc202306019
有机化学
2023, 43 (10), pp 3526-3543
DOI: 10.6023/cjoc202306007
有机化学
2023, 43 (10), pp 3544-3557
DOI: 10.6023/cjoc202306009
有机化学
2023, 43 (10), pp 3558-3568
DOI: 10.6023/cjoc202302031
有机化学
2023, 43 (10), pp 3569-3579
DOI: 10.6023/cjoc202304026
有机化学
2023, 43 (10), pp 3580-3589
DOI: 10.6023/cjoc202303030
研究论文
有机化学
2023, 43 (10), pp 3590-3597
DOI: 10.6023/cjoc202305019
有机化学
2023, 43 (10), pp 3598-3607
DOI: 10.6023/cjoc202307030
有机化学
2023, 43 (10), pp 3608-3613
DOI: 10.6023/cjoc202308009
有机化学
2023, 43 (10), pp 3614-3622
DOI: 10.6023/cjoc202306025
有机化学
2023, 43 (10), pp 3623-3634
DOI: 10.6023/cjoc202304034
有机化学
2023, 43 (10), pp 3635-3643
DOI: 10.6023/cjoc202304035
有机化学
2023, 43 (10), pp 3644-3651
DOI: 10.6023/cjoc202304029
有机化学
2023, 43 (10), pp 3652-3660
DOI: 10.6023/cjoc202305006
亮点述评
有机化学
2023, 43 (10), pp 3661-3663
DOI: 10.6023/cjoc202300055
有机化学
2023, 43 (10), pp 3664-3665
DOI: 10.6023/cjoc202300056
有机化学
2023, 43 (10), pp 3666-3668
DOI: 10.6023/cjoc202300057
有机化学
2023, 43 (10), pp 3669-3671
DOI: 10.6023/cjoc202300058
有机化学
2023, 43 (10), pp 3672-3674
DOI: 10.6023/cjoc202300059
有机化学
2023, 43 (10), pp 3675-3677
DOI: 10.6023/cjoc202300060
