Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (8): 1942-1947.DOI: 10.6023/cjoc201601014 Previous Articles     Next Articles

NOTE

介孔分子筛MCM-41固载席夫碱与醋酸锌共催化“一锅法”合成噻唑啉酮衍生物

邢雪建a, 樊馗a, 庞海霞a, 吴阳a, 杨敬辉a, 石伟a,b, 解正峰a,b, 惠永海a   

  1. a 新疆大学化学化工学院 石油天然气精细化工教育部重点实验室 乌鲁木齐 830046;
    b 西南石油大学化学化工学院 成都 610500
  • 收稿日期:2016-01-14 修回日期:2016-04-02 出版日期:2016-08-25 发布日期:2016-04-15
  • 通讯作者: 惠永海 E-mail:hyhai97@126.com
  • 基金资助:

    国家自然科学基金(Nos. 21161026,21362036)和新疆自治区研究生科研创新(No. XJGRI2015013)资助项目.

One-Pot Synthesis of 4-Thiazolidinone Derivatives Catalyzed by Zinc Acetate-Schiff Base Complex Immobilized on Mesoporous Molecular Sieve MCM-41

Xing Xuejiana, Fan Kuia, Pang Haixiaa, Wu Yanga, Yang Jinghuia, Shi Weia,b, Xie Zhengfenga,b, Hui Yonghaia   

  1. a Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046;
    b School of Chemistry and Chemistry Engineering, Southwest Petroleum University, Chengdu 610500
  • Received:2016-01-14 Revised:2016-04-02 Online:2016-08-25 Published:2016-04-15
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21161026, 21362036) and the Postgraduate Innovative Foundation of Xinjiang Autonomous Region (No. XJGRI2015013).

A new simple and efficient one-pot synthesis of thiazolidinone derivatives via aldehydes, amines and mercaptoacetic acid in the presence of Zn(OAc)2-Schiff base complex immobilized on MCM-41 is described. A variety of aldehydes and amines were engaged in the study and afforded respective thiazolidinones in high yield (up to 98%). Moreover, consistent activity of recovered catalyst was found to be almost same up to five cycles in 80% yield.

Key words: mesoporous molecular sieve MCM-41, Schiff base, one-pot synthesis, thiazolidinone, catalysis