Tetrabutylammonium Iodide/t-Butylhydroperoxide Catalytic/Oxidative Synthesis of Thiazolylidene Derivatives

doi:10.6023/cjoc201701045

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (7): 1800-1807.DOI: 10.6023/cjoc201701045 Previous Articles Next Articles

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四正丁基碘化胺/叔丁基过氧化氢催化氧化合成噻唑啉衍生物的反应研究

于乐, 刘瑞娟, 李明

青岛科技大学化学与分子工程学院生态化工国家重点实验室培育基地青岛 266042

收稿日期:2017-01-22 修回日期:2017-03-05 发布日期:2017-03-08
通讯作者: 李明 E-mail:wenlirong@qust.edu.cn
基金资助:
国家自然科学基金（No.21372137）资助项目.

Tetrabutylammonium Iodide/t-Butylhydroperoxide Catalytic/Oxidative Synthesis of Thiazolylidene Derivatives

Yu Le, Liu Ruijuan, Li Ming

State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042

Received:2017-01-22 Revised:2017-03-05 Published:2017-03-08
Contact: 10.6023/cjoc201701045 E-mail:wenlirong@qust.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (No.21372137).

1. Tetrabutylammonium Iodide/t-Butylhydroperoxide Catalytic/Oxidative Synthesis of Thiazolylidene Derivatives.PDF(1734KB)

Abstract

Two novel N-heterocyclic carbene-palladium (II) complexes were conveniently synthesized through one-pot reactions of imidazolium salts,palladium chloride and acridine.The new complexes have been fully characterized by ¹H NMR,¹³C NMR,elemental analysis,and X-ray single-crystal diffraction.Moreover,the obtained palladium (II) complexes were the effective catalyst precursors for the Suzuki-Miyaura coupling of aryl as well as benzyl chlorides with arylboronic acids.Under the optimal conditions,all reactions proceeded successfully to give the desired products in good to almost quantitative yields.

Key words: thiazolylidenes, β-ketothioamides, TBAI/TBHP, catalysis

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Yu Le, Liu Ruijuan, Li Ming. Tetrabutylammonium Iodide/t-Butylhydroperoxide Catalytic/Oxidative Synthesis of Thiazolylidene Derivatives[J]. Chin. J. Org. Chem., 2017, 37(7): 1800-1807.

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四正丁基碘化胺/叔丁基过氧化氢催化氧化合成噻唑啉衍生物的反应研究

Tetrabutylammonium Iodide/t-Butylhydroperoxide Catalytic/Oxidative Synthesis of Thiazolylidene Derivatives

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