Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (7): 1800-1807.DOI: 10.6023/cjoc201701045 Previous Articles     Next Articles



于乐, 刘瑞娟, 李明   

  1. 青岛科技大学化学与分子工程学院 生态化工国家重点实验室培育基地 青岛 266042
  • 收稿日期:2017-01-22 修回日期:2017-03-05 发布日期:2017-03-08
  • 通讯作者: 李明
  • 基金资助:


Tetrabutylammonium Iodide/t-Butylhydroperoxide Catalytic/Oxidative Synthesis of Thiazolylidene Derivatives

Yu Le, Liu Ruijuan, Li Ming   

  1. State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042
  • Received:2017-01-22 Revised:2017-03-05 Published:2017-03-08
  • Contact: 10.6023/cjoc201701045
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No.21372137).

Two novel N-heterocyclic carbene-palladium (II) complexes were conveniently synthesized through one-pot reactions of imidazolium salts,palladium chloride and acridine.The new complexes have been fully characterized by 1H NMR,13C NMR,elemental analysis,and X-ray single-crystal diffraction.Moreover,the obtained palladium (II) complexes were the effective catalyst precursors for the Suzuki-Miyaura coupling of aryl as well as benzyl chlorides with arylboronic acids.Under the optimal conditions,all reactions proceeded successfully to give the desired products in good to almost quantitative yields.

Key words: thiazolylidenes, β-ketothioamides, TBAI/TBHP, catalysis