Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (5): 1177-1187.DOI: 10.6023/cjoc201910012 Previous Articles     Next Articles

钴配合物催化硅氢加成反应研究进展

代自男, 余泽浩, 白赢, 厉嘉云, 彭家建   

  1. 杭州师范大学有机硅化学及材料技术教育部重点实验室 杭州 311121
  • 收稿日期:2019-10-11 修回日期:2019-12-06 出版日期:2020-05-25 发布日期:2020-01-03
  • 通讯作者: 白赢, 彭家建 E-mail:baiying0912@163.com;jjpeng@hznu.edu.cn
  • 基金资助:
    浙江省自然科学基金(No.LY18B020012)资助项目.

Progress in Catalysis of Hydrosilylation by Cobalt Complexes

Dai Zinan, Yu Zehao, Bai Ying, Li Jiayun, Peng Jiajian   

  1. Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Hangzhou Normal University, Hangzhou 311121
  • Received:2019-10-11 Revised:2019-12-06 Online:2020-05-25 Published:2020-01-03
  • Supported by:
    Project supported by the Natural Science Foundation of Zhejiang Province (No. LY18B020012).

Cobalt is abound in the earth and has advantages of low cost and low toxicity. Cobalt complexes have been widely applied as catalysts in numerous catalytic organic reactions, in which the complexes show excellent catalytic performance and have been recognized as a very important research field. The recent progress in the application of cobalt complexes in the catalytic hydrosilylation of alkenes, alkynes, carbonyl compounds and other unsaturated double bond is summarized. Furthermore, the deficiencies of the catalysts have been discussed. At last, the future development and prospects of these complexes as catalysts are also proposed.

Key words: cobalt complex, catalysis, hydrosilylation