基于含氮杂环配体的金属有机框架材料在电催化CO2还原中的应用与前景展望★

doi:10.6023/A26020053

化学学报 ›› 2026, Vol. 84 ›› Issue (5): 755-774.DOI: 10.6023/A26020053 上一篇下一篇

综述

基于含氮杂环配体的金属有机框架材料在电催化CO₂还原中的应用与前景展望^★

张亚^a^,^*(), 周功兵^a, 孙为银^b^,^*()

^a 重庆师范大学化学与材料科学学院绿色催化材料与技术重庆市重点实验室重庆 401331
^b 南京大学化学学院配位化学全国重点实验室南京 210023

投稿日期:2026-02-10 发布日期:2026-05-06
通讯作者: 张亚, 孙为银

作者简介:

张亚, 重庆师范大学化学与材料科学学院讲师, 2024年于南京大学化学化工学院获博士学位, 主要从事金属有机框架及其复合材料、过渡金属纳米材料的可控合成及其在电催化小分子(CO₂/H₂O/N₂)转化领域的应用.

周功兵, 重庆师范大学化学与材料科学学院教授, 2009年于华南理工大学获学士学位(应用化学专业), 2014年于复旦大学获博士学位(物理化学专业). 目前研究方向为金属纳米催化剂的结构调控及其在生物质小分子催化转化、电催化水分解中的应用.

孙为银, 南京大学化学学院教授, 1986年上海华东师范大学化学系本科毕业, 1990年和1993年在日本大阪大学分别获得硕士和理学博士学位. 近期的研究重点是利用金属有机框架及其衍生材料光/电催化CO₂还原. 已发表超过400篇研究论文, 担任J. Coord. Chem. 编委, CrystEngComm顾问编委, 并自2014年起成为英国皇家化学学会会士(FRSC).

★ 框架材料化学专辑.

基金资助:
国家自然科学基金(22231006); 国家自然科学基金(21703024); 重庆市自然科学基金(CSTB2025NSCQ-GPX0259); 重庆市教委科技项目(KJZD-K202200514); 重庆师范大学基金(24XLB028)

Recent Advance and Perspective of Metal-Organic Frameworks Based on Nitrogen-Containing Heterocyclic Ligands for Electrocatalytic CO₂ Reduction^★

Ya Zhang^a^,^*(), Gongbing Zhou^a, Wei-Yin Sun^b^,^*()

^a Chongqing Key Laboratory of Green Catalysis Materials and Technology, College of Chemistry and Materials Science, Chongqing Normal University, Chongqing 401331, China
^b State Key Laboratory of Coordination Chemistry, School of Chemistry, Nanjing University, Nanjing 210023, China

Received:2026-02-10 Published:2026-05-06
Contact: Ya Zhang, Wei-Yin Sun
About author:
★ For the VSI “Chemistry of Framework Materials”.
Supported by:
National Natural Science Foundation of China(22231006); National Natural Science Foundation of China(21703024); Natural Science Foundation of Chongqing, China(CSTB2025NSCQ-GPX0259); Science and Technology Research Program of Chongqing Municipal Education Commission of China(KJZD-K202200514); Chongqing Normal University Foundation(24XLB028)

文章分享

摘要/Abstract

降低大气中二氧化碳(CO₂)浓度以实现碳中和, 已成为环境科学与可持续发展领域一项紧迫的全球性挑战. 借助电催化CO₂还原反应(electrocatalytic CO₂ reduction reaction, ECRR)可将CO₂转化为高附加值化学品与清洁能源燃料, 为实现碳减排及可再生电能向化学能高效转化提供了极具潜力的技术路径. 金属有机框架(metal-organic frameworks, MOFs)是一种具有潜力的ECRR催化剂, 得益于其多孔、结构清晰且可调节的框架结构, 这有利于CO₂富集, 并有助于探索结构-性能之间关系和催化反应机理. 含氮杂环配体MOFs材料因其独特的物理化学特性在ECRR研究中备受关注, 这些特性包括灵活多样的框架、丰富的活性位点和高稳定性等. 此综述系统评述了基于含氮杂环配体MOFs材料的相关性质和表征手段, 并按含氮杂环结构类别, 即咪唑基、吡唑基、三唑基和四唑基等, 归纳了含氮杂环配体MOFs材料在ECRR领域的最新研究进展. 最后, 剖析了当前制约该类MOFs在ECRR实际应用方面的关键挑战, 包括本征导电性不足、在长时间运行条件下结构和电化学稳定性问题、电解槽系统集成以及催化反应过程中动态结构演变导致的机理模糊等, 并在此基础上对未来研究方向进行了展望.

关键词: 金属有机框架, 含氮杂环配体, CO₂还原反应, 电催化转化

Achieving carbon neutrality through reducing amounts of atmospheric carbon dioxide (CO₂) has emerged as an urgent global challenge in the fields of environmental science and sustainable development. Among the emerging mitigation strategies, electrocatalytic CO₂ reduction reaction (ECRR) stands out for its capacity to convert CO₂ into high-valued chemicals or energy-dense fuels, providing a promising approach for reducing CO₂ emissions and converting renewable electric energy into chemical energy. Metal-organic frameworks (MOFs) represent a promising class of catalysts for ECRR, owing to their intrinsic structural advantages—including well-defined porosity and atomic-level structural tunability—which collectively enhance CO₂ mass transport and adsorption, and enable systematic investigation of structure-activity relationship as well as reaction mechanism. In particular, MOFs constructed from nitrogen-containing heterocyclic ligands have garnered remarkable research interest, attributed to their superior features such as structural flexibility, abundant catalytic active sites and suitable stability. This review outlines the fundamental physicochemical properties and advanced characterization techniques for the nitrogen-containing heterocyclic ligand-based MOFs. Then recent advances in the application of such MOFs to ECRR were summarized categorizing by the nitrogen-containing moieties, namely imidazolyl-, pyrazolyl-, triazolyl- and tetrazolyl-based ligands. Finally, this review analyzed the critical challenges impeding the practical application of nitrogen-containing heterocyclic ligand-based MOFs in ECRR, including intrinsic electronic conductivity limitations, structural and electrochemical stability under prolonged operational conditions, integration of electrolyzer systems and mechanistic ambiguities arising from dynamic structural evolution during the ECRR. On this basis, prospects for future research directions are presented.

Key words: metal-organic frameworks, nitrogen-containing heterocyclic ligands, CO₂ reduction reaction, electrocatalytic conversion

引用此文

张亚, 周功兵, 孙为银. 基于含氮杂环配体的金属有机框架材料在电催化CO₂还原中的应用与前景展望^★[J]. 化学学报, 2026, 84(5): 755-774.

Ya Zhang, Gongbing Zhou, Wei-Yin Sun. Recent Advance and Perspective of Metal-Organic Frameworks Based on Nitrogen-Containing Heterocyclic Ligands for Electrocatalytic CO₂ Reduction^★[J]. Acta Chimica Sinica, 2026, 84(5): 755-774.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

图/表 14

图1. (a) MOF颗粒表面的EDL结构; (b)离子/分子在EDL结构中扩散到MOF框架; (c)中性电解液中MOF电极的截面图; (d)金属节点或有机配体的氧化还原反应导致MOF结构破坏; (e)动态电位扫描导致MOF表面或孔内EDL的形成和离子扩散[54]

Figure 1. (a) The EDL structure on the surface of an MOF particle; (b) ions/molecules diffusion into the MOF framework in the EDL structure; (c) cross-sectional illustration of MOF-coated electrode in neutral electrolyte; (d) structural destruction of MOFs driven by the redox reactions involving metal nodes or organic linkers; (e) EDL formation and ion diffusion on the surface or inside the pores of MOFs due to the dynamic potential sweeping[54] (Copyright 2021 American Chemical Society)

图2. (a) Cu3(DMPz)3的恒电位合成方法及性能示意图; (b) ALPS法在Cu3(DMPz)3上催化生成CH4和C2H4的机理示意图[57]

Figure 2. (a) Potentiostatic synthesis methods and performance of Cu3(DMPz)3; (b) Schematic illustration for the catalytic mechanism of CH4 and C2H4 production on Cu3(DMPz)3 with ALPS methods[57] (Copyright 2023 American Chemical Society)

图3. (a) ZIF-A-LD的合成过程; (b)不同电位下ZIF-8、ZIF-A-LD、ZIF-8/CB和ZIF-A-LD/CB的FECO; (c) ZIF-8和ZIF-A-LD中sp2 C位点上的自由能[77]; (d) ZIF-8/Zn电极合成过程示意图[79]; (e) Cu-MOF-CF的制备过程; (f) CF和Cu-MOF-CF的ECRR产物; (g) CF和Cu-MOF-CF的FEC2H4[83]

Figure 3. (a) Synthesis process of ZIF-A-LD; (b) FECO of ZIF-8, ZIF-A-LD, ZIF-8/CB, and ZIF-A-LD/CB at different potentials; (c) free energy profile of ZIF-8 and ZIF-A-LD on the sp2 C atom sites[77] (Copyright 2019 Wiley-VCH GmbH); (d) schematic diagram of synthesis process for ZIF-8/Zn[79] (Copyright 2022 Wiley-VCH GmbH); (e) preparation of Cu-MOF-CF; (f) ECRR products of CF and Cu-MOF-CF; (g) FEC2H4 of CF and Cu-MOF-CF[83] (Copyright 2023 Wiley-VCH GmbH)

图4. (a) ZIF-P5/In的制备[84]; (b) Cu2O/ZIF-8合成过程示意图; (c) Cu/ZIF-8和Cu NPs的FEC2＋; (d) Cu/ZIF-8和标准物的Cu K-边FT-EXAFS图; (e) Cu/ZIF-8和Cu簇C—C耦合自由能图[69]

Figure 4. (a) Scheme for preparation of ZIF-P5/In[84] (Copyright 2024 Elsevier); (b) schematic illustration of the synthesis process of Cu2O/ZIF-8; (c) FEC2＋ of Cu/ZIF-8 and Cu NPs; (d) Cu K-edge FT-EXAFS curves of Cu/ZIF-8 and the references; (e) C—C coupling free-energy profile of Cu/ZIF-8 and Cu cluster[69] (Copyright 2024 Chinese Chemical Society)

图5. (a) Cu—X的合成和结构; (b) Cu—I在不同电位下不同产物的FE; (c) Cu—Cl, Cu—Br和Cu—I的FECH4; (d) Cu—Cl, Cu—Br和Cu—I的ECRR自由能图[85]

Figure 5. (a) Scheme for preparation and structure of Cu—X; (b) FEs of different products on Cu-I at various potentials; (c) FECH4 of Cu—Cl, Cu—Br, and Cu—I catalysts; (d) free energy profiles of ECRR on Cu—Cl, Cu—Br, and Cu—I[85] (Copyright 2022 Wiley-VCH GmbH)

图6. (a) Ag-MOF1沿c轴互穿3D结构; (b) Ag-MOF2的2D结构; (c)不同电位下Ag-MOFs的FECO[86]; (d) [Cu(TIPE)0.5](ClO4)和(e) [Co(TIPE)(TFA)2]•2DMF的2D结构; (f) [Cu(TIPE)0.5](ClO4)在不同电位下的ECRR产物选择性[87]

Figure 6. (a) Interpenetrated 3D structures of Ag-MOF1 along the c-axis; (b) 2D structure of Ag-MOF2; (c) FECO of Ag-MOFs at different potentials[86] (Copyright 2024 Royal Society of Chemistry); 2D networks of (d) [Cu(TIPE)0.5](ClO4) and (e) [Co(TIPE)(TFA)2]•2DMF; (f) FEs of ECRR products for [Cu(TIPE)0.5](ClO4) at different potentials[87] (Copyright 2024 Royal Society of Chemistry)

图7. (a) Ag@BIF-104NSs(Cu)的合成过程示意图; (b) BIF-104NSs(Cu)上CO脱附和Ag@BIF-104NSs(Cu)上C—C偶联的结构模型[89]; (c)自组装形成四面体笼的示意图; (d) BIC-145的结构图; (e) BIC-145上CO2转化为C2H4可能的ECRR路径[90]

Figure 7. (a) Schematic diagram of the synthesis procedure for Ag@BIF-104NSs(Cu); (b) the calculated structures of CO desorption on BIF-104NSs(Cu) and the C—C coupling on Ag@BIF-104NSs(Cu)[89] (Copyright 2023 Wiley-VCH GmbH); (c) schematic illustration of the post-assembly modification of tetrahedral cages; (d) structural diagram of BIC-145; (e) the possible ECRR pathways for CO2 to C2H4 conversions on BIC-145[90] (Copyright 2025 Science China Press)

图8. (a) ECRR中Cu-PzX (其中X=H, Cl, Br, I)选择性差异示意图[91]; (b) CuBPZ的合成路线及3D结构[92]; (c) NNU-50的3D框架[94]; (d) Cu1Ni-BDP MOF的结构模型; Cu1Ni-BDP MOF的(e) HRTEM图像和(f)模拟结构模型; (g) Cu1Ni-BDP MOF在不同电位下的ECRR产物和H2的FE; (h) Ni-BDP MOF、Cu1Ni-BDP MOF和Cu2Ni-BDP MOF的吉布斯自由能图[95]

Figure 8. (a) Illustration of the difference in selectivity for Cu-PzX (where X=H, Cl, Br, I) in the ECRR[91] (Copyright 2021 Wiley-VCH GmbH); (b) synthetic route and 3D structure of CuBPZ[92] (Copyright 2022 Wiley-VCH GmbH); (c) 3D framework of NNU-50[94] (Copyright 2022 Tsinghua University Press); (d) structural model of the Cu1Ni-BDP MOF; (e) HRTEM image and (f) simulated structure model of Cu1Ni-BDP MOF; (g) FEs toward ECRR products and H2 on the Cu1Ni-BDP MOF at different potentials; (h) calculated Gibbs free energy diagrams on the Ni-BDP MOF, Cu1Ni-BDP MOF, and Cu2Ni-BDP MOF[95] (Copyright 2023 American Chemical Society)

图9. (a) Pd-Cu@CuPz2的合成示意图; (b)在不同电位下不同催化剂的FEC2＋; (c) Cu2O-CuPz2和Cu2O-PdO-CuPz2表面CO2到*OCCO的吉布斯自由能图; (d) Cu2O-PdO-CuPz2(Cu)和Cu2O-PdO-CuPz2(Pd)表面*CH2CHO到EtOH的吉布斯自由能图[58]

Figure 9. (a) Schematic synthesis of Pd-Cu@CuPz2; (b) the FEC2＋ over the different catalysts at various potentials; (c) the Gibbs free energy diagrams of CO2 to *OCCO on Cu2O-CuPz2 and Cu2O-PdO-CuPz2 surface; (d) the Gibbs free energy diagrams of *CH2CHO to EtOH on Cu2O-PdO-CuPz2 (Cu) and Cu2O-PdO-CuPz2 (Pd) surface[58] (Copyright 2024 Wiley-VCH GmbH)

图10. (a)不同尺寸纳米结构CuTrz的合成路线以及CuTrz的化学结构; CuTrz-53 nm, CuTrz-109 nm, CuTrz-307 nm和CuTrz-1335 nm在不同电位下的(b) C2H4和(c) C2＋产物的FE[98]; (d) 配体分子的化学结构; (e) Ln-Cu的结构, 其中X代表取代基, 位于右侧方框中, *表示与三唑离子基团相连的位置; (f) Ln-Cu在－(0.930±0.008) V时的ηC—C coupling[67]

Figure 10. (a) Synthetic route of CuTrz nanostructures with different sizes as well as the chemical structure of the CuTrz; (b) FE of C2H4 and (c) FE of C2＋ products on CuTrz-53 nm, CuTrz-109 nm, CuTrz-307 nm, and CuTrz-1335 nm at different potentials, respectively[98] (Copyright 2023 American Chemical Society); (d) chemical structure of ligand molecules; (e) the structure of Ln-Cu, X represents the substituents and is on the right frame, * indicates the position connecting with triazole rings; (f) ηC—C coupling of Ln-Cu at －(0.930±0.008) V[67] (Copyright 2024 Springer Nature)

图11. (a) Cu-N-S和Cu-I-S的合成和ECRR在Cu-N-S和Cu-I-S上不同产物示意图; (b) Cu-N-S 和 Cu-I-S在不同电位下C2H4和C2＋产物的FE[101]; (c) MAF-2Fa和(d) MAF-2Fb的3D框架; (e) MAF-2Fa和MAF-2Fb在－1.2 V时ECRR性能的比较; (f) 在PD-Cu、BD-Cu、LM-Cu和TM-Cu位点上*CO/*CO-*CO中间体结合模式的变化[56]

Figure 11. (a) Schematic synthesis of Cu-N-S and Cu-I-S and the different products of ECRR on Cu-N-S and Cu-I-S, respectively; (b) The FE of C2H4 and C2＋ products on Cu-N-S and Cu-I-S at different potentials[101] (Copyright 2024 American Chemical Society); 3D frameworks of (c) MAF-2Fa and (d) MAF-2Fb; (e) Comparison of typical performances at －1.2 V for MAF-2Fa and MAF-2Fb; (f) Coordination modes change as *CO/*CO-*CO intermediate binding for PD-Cu, BD-Cu, LM-Cu, and TM-Cu sites[56] (Copyright 2024 Wiley-VCH GmbH)

图12. (a) Cu-btca-c相变示意图; (b) Cu-btca-c和(c) Cu NPs在不同电流密度下ECRR产物分布[109]; (d)化合物1的框架通道和3D结构; 化合物1在(e) 0.5 mol/L NaCl电解液和(f)处理过的天然海水中ECRR产物选择性[110]

Figure 12. (a) Diagram of the phase transformation from Cu-btca-c; ECRR product distributions on (b) Cu-btca-s and (c) Cu NPs at different current densities[109] (Copyright 2024 American Chemical Society); (d) channels in the framework and the 3D framework of compound 1; The products selectivity of ECRR for compound 1 (e) in 0.5 mol/L NaCl electrolyte and (f) in treated natural seawater[110] (Copyright 2025 Wiley-VCH GmbH)

图13. (a) 1和(b) 2的结构图[111]; (c) Cu(4-pt)层内结构示意图; (d) Cu(4-pt)层间堆叠模式[113]; (e)暴露不同晶面的Cu-MMT纳米结构合成示意图; (f) Cu-MMT-H2O和(g) Cu-MMT-IPA在不同电位下的产物分布[115]

Figure 13. Perspective drawings of the structures for (a) 1 and (b) 2[111] (Copyright 2025 American Chemical Society); (c) schematic representation of the intralayer structure for Cu(4-pt); (d) interlayer stacking pattern of Cu(4-pt)[113] (Copyright 2025 Elsevier); (e) schematic illustration of the synthesis for Cu-MMT nanostructures with different exposed facets; Product distributions of (f) Cu-MMT-H2O and (g) Cu-MMT-IPA at different potentials[115] (Copyright 2024 American Chemical Society)

图14. (a) Cu-N2O2和Cu-N2O3合成示意图; (b) Cu-N2O2将CO2转化为C2产物的路径示意图[116]; (c) 2D AgCe-MOF和3D AgCe-MOF的合成; (d) 2D AgCe-MOF中平行吡啶环之间以及六元环中心之间的距离; (e) 2D AgCe-MOF层内π-π作用; 2D AgCe-MOF和3D AgCe-MOF的(f) Nyquist图和(g)不同扫速与充电电流密度比值斜率图; (h) 2D AgCe-MOF和3D AgCe-MOF在不同电位下的C1分布产物图[117]

Figure 14. (a) Schematic diagram of the synthesis of Cu-N2O2 and Cu-N2O3; (b) schematic pathway of CO2 to C2 products on Cu-N2O2[116] (Copyright 2025 Wiley-VCH GmbH); (c) crystal construction strategy of 2D AgCe-MOF and 3D AgCe-MOF; (d) distance between the parallel pyridine rings and the distance between the centers of mass of six-membered rings of 2D AgCe-MOF; (e) intralayer π-π interactions of 2D AgCe-MOF; (f) nyquist plots and (g) charging current density at different rates of the 2D AgCe-MOF nanosheet and 3D AgCe-MOF; (h) the product of C1 distribution for 2D AgCe-MOF and 3D AgCe-MOF at different potentials[117] (Copyright 2024 American Chemical Society)

参考文献 121

[1]	Qiu, L.; Li, H.; He, N. Acc. Chem. Res. 2023, 56, 2225. doi: 10.1021/acs.accounts.3c00316
[2]	Hou, S.; Dong, J.; Zhao, X.; Li, X.; Ren, F.; Zhao, J.; Zhao, B. Angew. Chem. Int. Ed. 2023, 62, e202305213. doi: 10.1002/anie.v62.34
[3]	Yang, Z.; Chen, J.; Qiu, L.; Xie, W.; He, L. Angew. Chem. Int. Ed. 2022, 61, e202205301. doi: 10.1002/anie.v61.44
[4]	Patel, S.; McKelvey, K.; Liu, L. Chem. Mater. 2024, 36, 10054. doi: 10.1021/acs.chemmater.4c01137
[5]	Sun, K.; Qian, Y.; Jiang, H. Angew. Chem. Int. Ed. 2023, 62, e202217565. doi: 10.1002/anie.v62.15
[6]	Nandal, N.; Jain, S. L. Coord. Chem. Rev. 2022, 451, 214271. doi: 10.1016/j.ccr.2021.214271
[7]	Baccour, M.; Lamotte, A.; Sakai, K.; Dubreucq, E.; Mehdi, A.; Kano, K.; Galarneau, A.; Drone, J.; Brun, N. Green Chem. 2020, 22, 3727. doi: 10.1039/D0GC00952K
[8]	Mu, C.; Zhang, Y.; Kou, W.; Xu, L. Acta Chim. Sinica 2021, 79, 925 (in Chinese). doi: 10.6023/A21030104
	(穆春辉, 张艺馨, 寇伟, 徐联宾, 化学学报, 2021, 79, 925.) doi: 10.6023/A21030104
[9]	Zhu, Z.; Liang, Z.; Jiao, Z.; Jiang, X.; Xie, Y.; Xu, H.; Zhao, B. Angew. Chem. Int. Ed. 2022, 61, e202214243. doi: 10.1002/anie.v61.49
[10]	Liang, Z.; Wang, H.; Zheng, H.; Zhang, W.; Cao, R. Chem. Soc. Rev. 2021, 50, 2540. doi: 10.1039/D0CS01482F
[11]	Wang, Z.; She, X.; Yu, Q.; Zhu, X.; Li, H.; Xu, H. Energy Fuels 2021, 35, 8585. doi: 10.1021/acs.energyfuels.1c00700
[12]	Wang, L.; Meng, Q.; Xiao, M.; Liu, C.; Xing, W.; Zhu, J. Renewables 2024, 2, 272. doi: 10.31635/renewables.024.202400064
[13]	Tang, M.; Yang, Z.; Xu, H.; Zhao, B. Adv. Funct. Mater. 2025, 36, e13412. doi: 10.1002/adfm.v36.1
[14]	Zhu, Z.; Zhao, B.; Hou, S.; Jiang, X.; Liang, Z.; Zhang, B.; Zhao, B. Angew. Chem. Int. Ed. 2021, 60, 23394. doi: 10.1002/anie.v60.43
[15]	Li, D.; Huang, L.; Tian, Y.; Liu, T.; Zhen, L.; Feng, Y. Appl. Catal. B: Environ. 2021, 292, 120119. doi: 10.1016/j.apcatb.2021.120119
[16]	Liu, S.; Xiao, J.; Lu, X.; Wang, J.; Wang, X.; Lou, X. (David). Angew. Chem. Int. Ed. 2019, 58, 8499. doi: 10.1002/anie.v58.25
[17]	Ji, L.; Chang, L.; Zhang, Y.; Mou, S.; Wang, T.; Luo, Y.; Wang, Z.; Sun, X. ACS Catal. 2019, 9, 9721. doi: 10.1021/acscatal.9b03180
[18]	Esmaeilirad, M.; Jiang, Z.; Harzandi, A. M.; Kondori, A.; Tamadoni Saray, M.; Segre, C. U.; Shahbazian-Yassar, R.; Rappe, A. M.; Asadi, M. Nat. Energy 2023, 8, 891. doi: 10.1038/s41560-023-01314-8
[19]	Mukherjee, A.; Abdinejad, M.; Mahapatra, S. S.; Ruidas, B. C. J. Mater. Chem. A 2023, 11, 9300. doi: 10.1039/D2TA08209H
[20]	Shah, S. S. A.; Sufyan Javed, M.; Najam, T.; Molochas, C.; Khan, N. A.; Nazir, M. A.; Xu, M.; Tsiakaras, P.; Bao, S.-J. Coord. Chem. Rev. 2022, 471, 214716. doi: 10.1016/j.ccr.2022.214716
[21]	Lei, Y.; Xiong, T.; Yu, X.; Huang, X.; Tang, X.; Yi, H.; Zhou, Y.; Zhao, S.; Sun, L.; Gao, F. Acta Chim. Sinica 2024, 82, 396 (in Chinese). doi: 10.6023/A23120529
	(雷雅茹, 熊廷楷, 于湘涛, 黄秀兵, 唐晓龙, 易红宏, 周远松, 赵顺征, 孙龙, 高凤雨, 化学学报, 2024, 82, 396.) doi: 10.6023/A23120529
[22]	Zhang, E.; Wang, T.; Yu, K.; Liu, J.; Chen, W.; Li, A.; Rong, H.; Lin, R.; Ji, S.; Zheng, X.; Wang, Y.; Zheng, L.; Chen, C.; Wang, D.; Zhang, J.; Li, Y. J. Am. Chem. Soc. 2019, 141, 16569. doi: 10.1021/jacs.9b08259
[23]	Zhang, Y.; Zhou, Q.; Wang, P.; Zhao, Y.; Gong, F.; Sun, W.-Y. ChemSusChem 2022, 15, e202102528. doi: 10.1002/cssc.v15.4
[24]	Zhang, C.; Lin, Z.; Jiao, L.; Jiang, H. Angew. Chem. Int. Ed. 2024, 63, e202414506. doi: 10.1002/anie.v63.50
[25]	Zhang, Y.; Sun, W.-Y. Chem. Commun. 2024, 60, 8824. doi: 10.1039/D4CC02635G
[26]	Duan, X.; Xu, J.; Wei, Z.; Ma, J.; Guo, S.; Wang, S.; Liu, H.; Dou, S. Adv. Mater. 2017, 29, 1701784. doi: 10.1002/adma.v29.41
[27]	Wang, N.; Chen, Y. Acta Chim. Sinica 2024, 82, 621 (in Chinese). doi: 10.6023/A24010040
	(王南南, 陈玉贞, 化学学报, 2024, 82, 621.) doi: 10.6023/A24010040
[28]	Yan, S.; Jiao, L.; He, C.; Jiang, H. Acta Chim. Sinica 2022, 80, 1084 (in Chinese). doi: 10.6023/A22040143
	(闫绍兵, 焦龙, 何传新, 江海龙, 化学学报, 2022, 80, 1084.) doi: 10.6023/A22040143
[29]	Furukawa, H.; Cordova, K. E.; O'Keeffe, M.; Yaghi, O. M. Science 2013, 341, 1230444. doi: 10.1126/science.1230444
[30]	Gao, C.; Zhang, S.; Pang, H. Acta Chim. Sinica 2025, 83, 962 (in Chinese). doi: 10.6023/A25040117
	(高春, 张松涛, 庞欢, 化学学报, 2025, 83, 962.) doi: 10.6023/A25040117
[31]	Wu, Z.; Zhang, C.; Guo, L.; Hu, T.; Zhang, Y.; Zhao, B. ACS Catal. 2024, 14, 15386. doi: 10.1021/acscatal.4c05376
[32]	Gu, A.; Zhang, Y.; Wu, Z.; Cui, H.; Hu, T.; Zhao, B. Angew. Chem. Int. Ed. 2022, 61, e202114817. doi: 10.1002/anie.v61.19
[33]	Bavykina, A.; Kolobov, N.; Khan, I. S.; Bau, J. A.; Ramirez, A.; Gascon, J. Chem. Rev. 2020, 120, 8468. doi: 10.1021/acs.chemrev.9b00685
[34]	Lin, S.; Usov, P. M.; Morris, A. J. Chem. Commun. 2018, 54, 6965. doi: 10.1039/C8CC01664J
[35]	Hou, C.-C.; Wang, H.-F.; Li, C.; Xu, Q. Energy Environ. Sci. 2020, 13, 1658. doi: 10.1039/C9EE04040D
[36]	Chen, S.; Cui, M.; Yin, Z.; Xiong, J.; Mi, L.; Li, Y. ChemSusChem 2021, 14, 73. doi: 10.1002/cssc.v14.1
[37]	Zou, L.; Wei, Y.-S.; Hou, C.-C.; Li, C.; Xu, Q. Small 2021, 17, 2004809. doi: 10.1002/smll.v17.16
[38]	Hinogami, R.; Yotsuhashi, S.; Deguchi, M.; Zenitani, Y.; Hashiba, H.; Yamada, Y. ECS Electrochem. Lett. 2012, 1, H17. doi: 10.1149/2.001204eel
[39]	Kumar, S. R.; Kumar, S. S.; Kulandainathan, M. A. Electrochem. Commun. 2012, 25, 70. doi: 10.1016/j.elecom.2012.09.018
[40]	Loibl, A.; de Krom, I.; Pidko, E. A.; Weber, M.; Wiecko, J.; Muller, C. Chem. Commun. 2014, 50, 8842. doi: 10.1039/C4CC03469D
[41]	Roohi, H.; Khyrkhah, S. J. Mol. Model. 2015, 21, 1. doi: 10.1007/s00894-014-2561-5
[42]	Anwar, M. I.; Asad, M.; Su, X.; Sofer, Z.; Rabbani, M. S.; Ashiq, M. N.; Yang, G.; Gao, Y. Coord. Chem. Rev. 2026, 548, 217158. doi: 10.1016/j.ccr.2025.217158
[69]	Zhang, Y.; Zhou, Q.; Lu, X.; Zhang, X.; Gong, F.; Sun, W.-Y. CCS Chem. 2024, 6, 2950. doi: 10.31635/ccschem.024.202404245
[70]	Lucier, B. E. G.; Chen, S.; Huang, Y. Acc. Chem. Res. 2018, 51, 319. doi: 10.1021/acs.accounts.7b00357
[71]	Jiang, M.; Zhu, M.; Wang, M.; He, Y.; Luo, X.; Wu, C.; Zhang, L.; Jin, Z. ACS Nano 2023, 17, 3209. doi: 10.1021/acsnano.2c11046
[72]	Zhu, H.-L.; Huang, J.-R.; Zhang, M.-D.; Yu, C.; Liao, P.-Q.; Chen, X.-M. J. Am. Chem. Soc. 2024, 146, 1144. doi: 10.1021/jacs.3c12423
[73]	Guo, X.; Xing, T.; Lou, Y.; Chen, J. J. Solid State Chem. 2016, 235, 107. doi: 10.1016/j.jssc.2015.12.021
[74]	Wang, Y.; Hou, P.; Wang, Z.; Kang, P. ChemPhysChem 2017, 18, 3142. doi: 10.1002/cphc.v18.22
[75]	Ahmad, A.; Iqbal, N.; Noor, T.; Hassan, A.; Khan, U. A.; Wahab, A.; Raza, M. A.; Ashraf, S. J. CO₂ Util. 2021, 48, 101523.
[76]	Geng, W.; Chen, W.; Li, G.; Dong, X.; Song, Y.; Wei, W.; Sun, Y. ChemSusChem 2020, 13, 4035. doi: 10.1002/cssc.v13.16
[77]	Dou, S.; Song, J.; Xi, S.; Du, Y.; Wang, J.; Huang, Z.; Xu, Z.; Wang, X. Angew. Chem. Int. Ed. 2019, 58, 4041. doi: 10.1002/anie.v58.12
[78]	Yang, Z.; Zhang, X.; Long, C.; Yan, S.; Shi, Y.; Han, J.; Zhang, J.; An, P.; Chang, L.; Tang, Z. CrystEngComm 2020, 22, 1619. doi: 10.1039/C9CE01517E
[79]	Zhang, R.; Yang, J.; Zhao, X.; Yang, H.; Li, H.; Ji, B.; Zhou, G.; Ma, X.; Yang, D. ChemCatChem 2022, 14, e202101653. doi: 10.1002/cctc.v14.4
[80]	Han, X.; Zhang, T.; Biset-Peiró, M.; Zhao, S.; Murcia Lopez, S.; Daasbjerg, K.; Morante, J. R.; Li, J.; Arbiol, J. Small Struct. 2023, 4, 2200388. doi: 10.1002/sstr.v4.8
[81]	Umar, M.; Abdulazeez, I.; Tanimu, A.; Ganiyu, S. A.; Alhooshani, K. J. Environ. Chem. Eng. 2024, 12, 112899. doi: 10.1016/j.jece.2024.112899
[82]	Zhou, L.; Li, H.; Wang, D.; Jiang, W.; Wu, Y.; Shang, Li.; Guo, C.; Liu, C.; Ren, B. Electroanalysis 2023, 35, 291.
[83]	Yan, T.; Wang, P.; Sun, W.-Y. Small 2023, 19, 2206070. doi: 10.1002/smll.v19.10
[84]	Zou, Y.; Guan, Y.; Liu, Y. J. Electroanal. Chem. 2024, 966, 118400. doi: 10.1016/j.jelechem.2024.118400
[85]	Zhang, Y.; Zhou, Q.; Qiu, Z.-F.; Zhang, X.-Y.; Chen, J.-Q.; Zhao, Y.; Gong, F.; Sun, W.-Y. Adv. Funct. Mater. 2022, 32, 2203677. doi: 10.1002/adfm.v32.36
[86]	Wang, Y.-J.; Qiu, Z.-F.; Zhang, Y.; Wang, F.-F.; Zhao, Y.; Sun, W.-Y. Dalton Trans. 2024, 53, 3685. doi: 10.1039/D3DT04056A
[87]	Wang, F.-F.; Wang, Y.-J.; Qiu, Z.-F.; Zhang, K.-Y.; Zhao, Y.; Sun, W.-Y. CrystEngComm 2024, 26, 6465. doi: 10.1039/D4CE00991F
[88]	Shao, P.; Zhou, W.; Hong, Q.; Yi, L.; Zheng, L.; Wang, W.; Zhang, H.; Zhang, H.; Zhang, J. Angew. Chem. Int. Ed. 2021, 60, 16687. doi: 10.1002/anie.v60.30
[89]	Shao, P.; Zhang, H.; Hong, Q.; Yi, L.; Li, Q.; Zhang, J. Adv. Energy Mater. 2023, 13, 2300088. doi: 10.1002/aenm.v13.19
[90]	Chen, J.-Q.; Li, Q.-H.; Hong, Q.-L.; Shao, P.; Zhang, H.-X.; Zhang, J. Sci. China Chem. 2025, 68, 943. doi: 10.1007/s11426-024-2290-5
[91]	Wang, R.; Liu, J.; Huang, Q.; Dong, L.-Z.; Li, S.-L.; Lan, Y.-Q. Angew. Chem. Int. Ed. 2021, 60, 19829. doi: 10.1002/anie.v60.36
[92]	Liu, Y.-Y.; Wang, Z.-S.; Liao, P.-Q.; Chen, X.-M. Chem. Asian J. 2022, 17, e202200764. doi: 10.1002/asia.v17.21
[93]	Zhang, L.; Li, X.-X.; Lang, Z.-L.; Liu, Y.; Liu, J.; Yuan, L.; Lu, W.-Y.; Xia, Y.-S.; Dong, L.-Z.; Yuan, D.-Q.; Lan, Y.-Q. J. Am. Chem. Soc. 2021, 143, 3808. doi: 10.1021/jacs.0c11450 pmid: 33651597
[94]	Dong, L.-Z.; Lu, Y.-F.; Wang, R.; Zhou, J.; Zhang, Y.; Zhang, L.; Liu, J.; Li, S.-L.; Lan, Y.-Q. Nano Res. 2022, 15, 10185. doi: 10.1007/s12274-022-4681-z
[95]	Huang, L.; Liu, Z.; Gao, G.; Chen, C.; Xue, Y.; Zhao, J.; Lei, Q.; Jin, M.; Zhu, C.; Han, Y.; Francisco, J. S.; Lu, X. J. Am. Chem. Soc. 2023, 145, 26444. doi: 10.1021/jacs.3c10600
[96]	Al-Attas, T. A.; Marei, N. N.; Yong, X.; Yasri, N. G.; Thangadurai, V.; Shimizu, G.; Siahrostami, S.; Kibria, M. G. ACS Catal. 2021, 11, 7350. doi: 10.1021/acscatal.1c01506
[97]	Oh, M.; Mirkin, C. A. Nature 2005, 438, 651. doi: 10.1038/nature04191
[98]	Wang, J.; Liu, J.; Song, Y.; Geng, S.; Peng, Z.; Yu, J.; Liu, F.; Wang, Y.; Xi, S.; Zhang, Z.; Fan, Z. ACS Mater. Lett. 2023, 5, 2121.
[99]	Shekhawat, A.; Das, D.; Zerdoumi, R.; Mahbub, M. A. A.; Eid, B.; Chandra, S.; Seisel, S.; Schuhmann, W. Adv. Funct. Mater. 2025, 35, 2506172. doi: 10.1002/adfm.v35.48
[43]	Wang, D.; Yang, P.; Liu, L.; Wang, W.; Chen, Z. Mater. Today Energy 2022, 26, 101017.
[44]	Saha, R.; Gomez Garcia, C. J. Chem. Soc. Rev. 2024, 53, 9490. doi: 10.1039/D4CS00141A
[45]	Chen, X.-M.; Tong, M.-L. Acc. Chem. Res. 2007, 40, 162. doi: 10.1021/ar068084p
[46]	Zhang, J.-P.; Zhang, Y.-B.; Lin, J.-B.; Chen, X.-M. Chem. Rev. 2012, 112, 1001. doi: 10.1021/cr200139g
[47]	Banerjee, R.; Phan, A.; Wang, B.; Knobler, C.; Furukawa, H.; O'Keeffe, M.; Yaghi, O. M. Science 2008, 319, 939. doi: 10.1126/science.1152516 pmid: 18276887
[48]	Colombo, V.; Galli, S.; Choi, H. J.; Han, G. D.; Maspero, A.; Palmisano, G.; Masciocchi, N.; Long, J. R. Chem. Sci. 2011, 2, 1311. doi: 10.1039/c1sc00136a
[49]	Desai, A. V.; Sharma, S.; Roy, A.; Ghosh, S. K. Cryst. Growth Des. 2019, 19, 7046. doi: 10.1021/acs.cgd.9b00873
[50]	He, T.; Zhang, Y.; Wang, B.; Lv, X.; Xie, L.; Li, J. ChemPlusChem 2016, 81, 864. doi: 10.1002/cplu.v81.8
[51]	Burtch, N. C.; Jasuja, H.; Walton, K. S. Chem. Rev. 2014, 114, 10575. doi: 10.1021/cr5002589
[52]	Devic, T.; Serre, C. Chem. Soc. Rev. 2014, 43, 6097. doi: 10.1039/C4CS00081A
[53]	Zhao, H.; Qu, Z.; Ye, H.; Xiong, R. G. Chem. Soc. Rev. 2008, 37, 84. doi: 10.1039/B616738C
[54]	Zheng, W.; Lee, L. Y. S. ACS Energy Lett. 2021, 6, 2838. doi: 10.1021/acsenergylett.1c01350
[55]	Zheng, W.; Liu, M.; Lee, L. Y. S. ACS Catal. 2019, 10, 81. doi: 10.1021/acscatal.9b03790
[56]	Zheng, K.; Hu, D.-Y.; Wang, C.; Liang, Z.-Y.; Zhang, X.-W.; Xiao, X.-X.; Wu, J.-X.; Zhuo, L.-L.; Lin, D.-Y.; Zhou, D.-D.; Zhang, J.-P. Small 2024, 21, 2408510. doi: 10.1002/smll.v21.4
[57]	Zhang, X.; Liu, T.; Liu, C.; Zheng, D.; Huang, J.; Liu, Q.; Yuan, W.; Yin, Y.; Huang, L.; Xu, M.; Li, Y.; Gu, Z. J. Am. Chem. Soc. 2023, 145, 2195. doi: 10.1021/jacs.2c09501
[58]	Xie, G.; Guo, W.; Fang, Z.; Duan, Z.; Lang, X.; Liu, D.; Mei, G.; Zhai, Y.; Sun, X.; Lu, X. Angew. Chem. Int. Ed. 2024, 63, e202412568. doi: 10.1002/anie.v63.47
[59]	Geng, Y.; Lin, X.; Sun, Y.; Li, H.; Qin, Y.; Li, C. Acta Chim. Sinica 2022, 80, 748 (in Chinese). doi: 10.6023/A21120617
	(耿元昊, 林小秋, 孙亚昕, 李惠雨, 秦悦, 李从举, 化学学报, 2022, 80, 748.) doi: 10.6023/A21120617
[60]	Narváez-Celada, D.; Varela, A. S. J. Mater. Chem. A 2022, 10, 5899. doi: 10.1039/D1TA10440C
[61]	Katritzky, A. R.; Ramsden, C. A.; Joule, J. A.; Zhdankin, V. V. Handbook of Heterocyclic Chemistry, 3rd ed., Elsevier, Amsterdam, 2010.
[62]	Yan, T.; Wang, P.; Xu, Z.; Sun, W.-Y. ACS Appl. Mater. Interfaces 2022, 14, 13645. doi: 10.1021/acsami.2c00487
[63]	Li, Z.; Zhang, C.; Liu, C.; Zhang, H.; Song, H.; Zhang, Z.; Wei, G.; Bao, X.; Yu, C.; Yuan, P. Angew. Chem. Int. Ed. 2024, 63, e202314266. doi: 10.1002/anie.v63.2
[64]	Ogunbanjo, O.; Rodríguez, P.; Anderson, P. Mater. Chem. Front. 2025, 9, 1650. doi: 10.1039/D4QM01060D
[65]	Wu, Z.; Zhang, L.; Chen, Y.; Li, J.; Li, L. Acta Chim. Sinica 2025, 83, 917 (in Chinese). doi: 10.6023/A25040140
	(吴子林, 张璐, 陈杨, 李晋平, 李立博, 化学学报, 2025, 83, 917.) doi: 10.6023/A25040140
[66]	Guo, F.; Li, R.; Yang, S.; Zhang, X.; Yu, H.; Urban, J.; Sun, W.-Y. Angew. Chem. Int. Ed. 2023, 62, e202216232. doi: 10.1002/anie.v62.14
[67]	Yang, Y.; Zhang, C.; Zhang, C.; Shi, Y.; Li, J.; Johannessen, B.; Liang, Y.; Zhang, S.; Song, Q.; Zhang, H.; Huang, J.; Ke, J.; Zhang, L.; Song, Q.; Zeng, J.; Zhang, Y.; Geng, Z.; Wang, P.; Wang, Z.; Zeng, J.; Li, F. Nat. Commun. 2024, 15, 6316. doi: 10.1038/s41467-024-50791-2 pmid: 39060325
[68]	Liu, C.; Zhang, X.; Huang, J.; Guan, M.; Xu, M.; Gu, Z. ACS Catal. 2022, 12, 15230. doi: 10.1021/acscatal.2c04275
[100]	Zhuo, L.-L.; Chen, P.; Zheng, K.; Zhang, X.-W.; Wu, J.-X.; Lin, D.-Y.; Liu, S.-Y.; Wang, Z.-S.; Liu, J.-Y.; Zhou, D.-D.; Zhang, J.-P. Angew. Chem. Int. Ed. 2022, 61, e202204967. doi: 10.1002/anie.v61.28
[101]	Wang, J.; Sun, M.; Xu, H.; Hao, F.; Wa, Q.; Su, J.; Zhou, J.; Wang, Y.; Yu, J.; Zhang, P.; Ye, R.; Chu, S.; Huang, B.; Shao, M.; Fan, Z. ACS Nano 2024, 18, 7192. doi: 10.1021/acsnano.3c12389
[102]	Huang, D.-S.; Zhu, H.-L.; Zhao, Z.-H.; Huang, J.-R.; Liao, P.-Q.; Chen, X.-M. ACS Catal. 2022, 12, 8444. doi: 10.1021/acscatal.2c01681
[103]	Zhu, H.-L.; Chen, H.-Y.; Han, Y.-X.; Zhao, Z.-H.; Liao, P.-Q.; Chen, X.-M. J. Am. Chem. Soc. 2022, 144, 13319. doi: 10.1021/jacs.2c04670
[104]	Zheng, K.; Hu, D.-Y.; Zhang, X.-W.; Xiao, X.-X.; Liang, Z.-J.; Wu, J.-X.; Lin, D.-Y.; Zhuo, L.-L.; Yi, H.; Gong, L.; Zhou, D.-D.; Zhang, J.-P. J. Mater. Chem. A 2024, 12, 16396. doi: 10.1039/D4TA01982B
[105]	Zhang, Y.; Zhang, L.; Feng, X.; Zhang, G.; Zhang, Y. Small 2025, 21, e05892. doi: 10.1002/smll.v21.39
[106]	Kim, J. Y. T.; Zhu, P.; Chen, F.-Y.; Wu, Z.-Y.; Cullen, D. A.; Wang, H. Nat. Catal. 2022, 5, 288. doi: 10.1038/s41929-022-00763-w
[107]	Xie, Y.; Ou, P.; Wang, X.; Xu, Z.; Li, Y.; Wang, Z.; Huang, J.; Wicks, J.; McCallum, C.; Wang, N.; Wang, Y.; Chen, T.; Lo, B. T. W.; Sinton, D.; Yu, J.; Wang, Y.; Sargent, E. H. Nat. Catal. 2022, 5, 564. doi: 10.1038/s41929-022-00788-1
[108]	Ma, Z.; Yang, Z.; Lai, W.; Wang, Q.; Qiao, Y.; Tao, H.; Lian, C.; Liu, M.; Ma, C.; Pan, A.; Huang, H. Nat. Commun. 2022, 13, 7596. doi: 10.1038/s41467-022-35415-x
[109]	Yu, J.; Xiao, J.; Guo, L.; Xie, Z.; Wang, K.; Wang, Y.; Hao, F.; Ma, Y.; Zhou, J.; Lu, P.; Wang, G.; Meng, X.; Zhu, Z.; Li, Q.; Ling, C.; Sun, J.; Wang, Y.; Song, S.; Fan, Z. ACS Nano 2024, 18, 33602. doi: 10.1021/acsnano.4c12245
[110]	Li, L.; Zhao, X.; Tang, M.; Yang, Z.; Ren, F.; Liang, Z.; Guo, P.; Xu, H.; Zhang, X.; Zhao, J.; Zhao, B. Angew. Chem. Int. Ed. 2025, 64, e202512100. doi: 10.1002/anie.v64.37
[111]	Liu, J.; Peng, D.; Liu, S.; Wen, H.; Zhu, Z.; Zhao, J.; Chen, J. ACS Sustainable Chem. Eng. 2025, 13, 2564. doi: 10.1021/acssuschemeng.4c09723
[112]	Majidi, L.; Ahmadiparidari, A.; Shan, N.; Misal, S. N.; Kumar, K.; Huang, Z.; Rastegar, S.; Hemmat, Z.; Zou, X.; Zapol, P.; Cabana, J.; Curtiss, L. A.; Salehi-Khojin, A. Adv. Mater. 2021, 33, e2004393.
[113]	Han, Y.-P.; Wang, Z.-R.; Yan, Y.-Y.; Li, Q.-H.; Shao, P.; Zhang, H.-X.; Han, L.-L.; Wang, F.; Zhang, J. Chem. Eng. J. 2025, 507, 160493. doi: 10.1016/j.cej.2025.160493
[114]	Xue, H.; Huang, J.-R.; Wang, Z.-S.; Zhao, Z.-H.; Shi, W.; Liao, P.-Q.; Chen, X.-M. Chin. J. Catal. 2023, 53, 102. doi: 10.1016/S1872-2067(23)64519-X
[115]	Lu, P.; Lv, J.; Chen, Y.; Ma, Y.; Wang, Y.; Lyu, W.; Yu, J.; Zhou, J.; Yin, J.; Xiong, Y.; Wang, G.; Ling, C.; Xi, S.; Zhang, D.; Fan, Z. Nano Lett. 2024, 24, 1553. doi: 10.1021/acs.nanolett.3c04092
[116]	Meng, F.; Yao, X.; He, J.; Gu, J.; Li, W.; Sun, C.; Wang, X.; Su, Z. ChemSusChem 2025, 18, e202402120. doi: 10.1002/cssc.v18.8
[117]	Yao, X.; Cui, D.; Zhu, C.; He, J.; Meng, F.; Yang, S.; Dong, M.; Shan, G.; Zhang, M.; Sun, C.; Wang, X.; Su, Z. ACS Mater. Lett. 2024, 6, 5112.
[118]	Heng, J.-M.; Zhu, H.-L.; Zhao, Z.-H.; Yu, C.; Liao, P.-Q.; Chen, X.-M. J. Am. Chem. Soc. 2023, 145, 21672. doi: 10.1021/jacs.3c08571
[119]	Jiao, S.; Fu, X.; Huang, H. Adv. Funct. Mater. 2021, 32, 2107651. doi: 10.1002/adfm.v32.4
[120]	Nam, D. H.; Shekhah, O.; Lee, G.; Mallick, A.; Jiang, H.; Li, F.; Chen, B.; Wicks, J.; Eddaoudi, M.; Sargent, E. H. J. Am. Chem. Soc. 2020, 142, 21513. doi: 10.1021/jacs.0c10774
[121]	Liu, L.; Cai, Y.; Du, H.; Lu, X.; Li, X.; Liu, F.; Fu, J.; Zhu, J. ACS Appl. Mater. Interfaces 2023, 15, 16673. doi: 10.1021/acsami.2c21902

基于含氮杂环配体的金属有机框架材料在电催化CO₂还原中的应用与前景展望^★

Recent Advance and Perspective of Metal-Organic Frameworks Based on Nitrogen-Containing Heterocyclic Ligands for Electrocatalytic CO₂ Reduction^★

RichHTML

PDF

可视化

摘要/Abstract

引用此文

分享此文

图/表 14

参考文献 121

相关文章 15

编辑推荐

相关统计

本文评价

[1]	陈慧滢, 黄宁宇, 廖培钦. 基于银−碳键的新型金属有机框架用于高效光催化合成过氧化氢^★[J]. 化学学报, 2026, 84(5): 626-630.
[2]	王炙韬, 林雨珂, 万妍, 黄鑫伟, 李云斌, 吉定豪, 项生昌, 张章静. 快速、绿色机械化学合成UTSA-16(Zn)用于高效碳捕获^★[J]. 化学学报, 2026, 84(5): 631-637.
[3]	刘璐, 赵砚珑, 白薛峰, 张鑫, 李建荣. 可宏量制备的层叠配位聚合物用于CH₄/N₂分离^★[J]. 化学学报, 2026, 84(5): 638-642.
[4]	丁宝童, 蔡俊凯, 郭绍杰, 段春迎. 基于拓扑固定的铜卤簇金属有机框架的稳定性与发光调控研究^★[J]. 化学学报, 2026, 84(5): 682-688.
[5]	张伟宏, 马亚男, 方翰, 薛东旭. 面向乙烯一步纯化的多组分金属有机框架: 金属配体导向合成与C₂混合气高效分离^★[J]. 化学学报, 2026, 84(5): 659-666.
[6]	何乾龙, 胡洁颖, 钟礼匡, 何军. 基于金属有机框架的中性介质硝酸盐电催化还原制氨: 设计策略与机理研究^★[J]. 化学学报, 2026, 84(5): 775-804.
[7]	邬佳悦, 王文伯, 谢玉龙, 方伟慧. 铝基金属有机框架材料的主客体化学研究进展^★[J]. 化学学报, 2026, 84(5): 697-708.
[8]	彭天资, 沈嘉克, 郭淑雅, 夏潇潇, 李炜. 迁移学习预测金属/共价有机骨架材料内小分子气体自扩散系数研究[J]. 化学学报, 2026, 84(3): 305-315.
[9]	叶舣, 黄正义, 赵兴雷, 赵娅俐, 刘龙杰, 吴武凤, 魏嫣莹. 垂直排列金属有机框架纳米片膜实现高效H₂传输[J]. 化学学报, 2026, 84(1): 129-134.
[10]	税子怡, 尹书睿, 邓锦涛, 许留云, 郭莉. 聚乙烯吡咯烷酮辅助金属有机框架衍生分级多孔碳材料的制备及其双功能催化性能研究[J]. 化学学报, 2026, 84(1): 53-63.
[11]	翁惠琼, 黄河, 王雯菲, 李和国, 李晓鹏, 张守鑫, 李树华, 赵越, 吴玉芳, 乔智威. 基于MOFid赋能下的AI大数据挖掘高性能化学战剂吸附材料[J]. 化学学报, 2026, 84(1): 8-19.
[12]	江惠星, 郑丽彬, 陈小丰, 张珍珍, 陈秋水, 杨黄浩. 基于钛基金属有机框架的孔径调控策略及其在海水提铀中的应用^★[J]. 化学学报, 2025, 83(9): 987-992.
[13]	朱永朝, 刘冰洁, 梁文杰, 徐海. 多功能MOFs隔离膜用于锂硫电池的研究[J]. 化学学报, 2025, 83(8): 861-867.
[14]	高春, 张松涛, 庞欢. 金属有机框架复合材料^★[J]. 化学学报, 2025, 83(8): 962-980.
[15]	吴子林, 张璐, 陈杨, 李晋平, 李立博. 乙烷选择性金属有机框架材料的结构设计与分离应用^★[J]. 化学学报, 2025, 83(8): 917-936.