有机化学 ›› 2013, Vol. 33 ›› Issue (01): 66-75.DOI: 10.6023/cjoc201206011 上一篇    下一篇

综述与进展

过渡金属催化肟类化合物的反应研究进展

冉陇飞, 梁浩, 关正辉   

  1. 合成与天然功能分子化学教育部重点实验室 西北大学化学与材料科学学院 西安 710069
  • 收稿日期:2012-06-09 修回日期:2012-08-29 发布日期:2012-09-10
  • 通讯作者: 关正辉 E-mail:guanzhh@nwu.edu.cn
  • 基金资助:

    国家自然科学基金(Nos. 21272183, 21002077);陕西省科技厅“陕西省青年科技新星”基金(No. 2012KJXX-26)和陕西省教育厅基金(No. 12JK0611)资助项目.

Progress in Transition Metal-Catalyzed Reactions of Oximes and Their Derivatives

Ran Longfei, Liang Hao, Guan Zhenghui   

  1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry & Materials Science, Northwest University, Xi'an 710069
  • Received:2012-06-09 Revised:2012-08-29 Published:2012-09-10
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21272183, 21002077), the Fund of New Scientific Stars of Shanxi Province (No. 2012KJXX-26) and the Fund of Education Department of Shaanxi Provincial Government (No. 12JK0611).

按照反应类型的不同, 对近年来过渡金属催化肟类化合物反应的研究进展进行了综述, 主要包括酮肟的还原酰化反应, 肟类化合物的催化偶联反应, 胺化反应以及肟类化合物与炔烃的环化反应.

关键词: 肟, 过渡金属, 还原酰化, 催化偶联, 胺化, 环化

The recent progress in transition metal-catalyzed reactions of oximes and their derivatives is reviewed in this paper. The reactions mainly based on reductive acylation, catalyzed coupling, amination, and cyclization of oximes and their derivatives.

Key words: oximes, transition metal, reductive acylation, cross coupling, amination, cyclization