有机化学 ›› 2013, Vol. 33 ›› Issue (05): 971-981.DOI: 10.6023/cjoc201211021 上一篇    下一篇

综述与进展

席夫碱修饰的介孔分子筛MCM-41催化有机反应的研究进展

谢绍雷, 惠永海, 王长春, 解正峰   

  1. 石油天然气精细化工教育部&新疆维吾尔自治区重点实验室 新疆大学化学化工学院 乌鲁木齐 830046
  • 收稿日期:2012-11-12 修回日期:2012-12-03 发布日期:2012-12-06
  • 通讯作者: 解正峰,xiezhf72@yahoo.com.cn E-mail:xiezhf72@yahoo.com.cn
  • 基金资助:

    国家自然科学基金(Nos. 21162026, 20962018)及新疆自治区青年基金(No. 2011211B05)资助项目.

Research Progress of Schiff Base Modified MCM-41 Catalyst in Organic Reactions

Xie Shaolei, Hui Yonghai, Wang Changchun, Xie Zhengfeng   

  1. Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046
  • Received:2012-11-12 Revised:2012-12-03 Published:2012-12-06
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21162026, 20962018), and the Xinjiang Autonomous Region Youth Science Foundation (No. 2011211B05).

介孔分子筛MCM-41在催化、吸附和分离等方面具有优异的性能, 而席夫碱在催化、生物活性和医药等方面也表现出很好的活性, 席夫碱配合物修饰的介孔分子筛MCM-41催化有机反应的应用已成为有机化学研究的热点之一. 针对近年来席夫碱修饰的介孔分子筛MCM-41在烯烃的氧化、醇的氧化、Suzuki偶联、不对称催化及其它反应中的应用研究进行了综述.

关键词: MCM-41, 席夫碱, 非均相催化, 有机合成

Mesoporous molecular sieves MCM-41 has showed excellent activity in catalysis, adsorption and separation, and Schiff base also revealed good activity in catalysis, biological activity and medicine. The catalytic application of Schiff base modified MCM-41 has become one of the hot issues in the research of organic chemistry. The application of Schiff base modified MCM-41 as heterogeneous catalyst to oxidation of olefin, alcohols, Suzuki reaction, asymmetry catalysis and other reactions is presented in this review.

Key words: MCM-41, Schiff base, heterogeneous catalysis, organic synthesis