有机化学 ›› 2017, Vol. 37 ›› Issue (2): 251-266.DOI: 10.6023/cjoc201609022 上一篇    下一篇

综述与进展

可见光促进氧气参与的均相氧合反应

程骁恺a,b, 胡新根a, 陆展b   

  1. a 温州大学化学与材料工程学院 温州 3250035;
    b 浙江大学化学系 杭州 31000058
  • 收稿日期:2016-09-22 修回日期:2016-10-20 发布日期:2016-11-03
  • 通讯作者: 胡新根, 陆展 E-mail:hxgwzu@126.com;luzhan@zju.edu.cn
  • 基金资助:

    科技部国家重点基础研究计划(973计划,No.2015CB856600)、国家自然科学基金(Nos.21472162,21573161)资助项目.

Visible-Light-Promoted Aerobic Homogenous Oxygenation Reactions

Cheng Xiaokaia,b, Hu Xingena, Lu Zhanb   

  1. a College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 3250035;
    b Department of Chemistry, Zhejiang University, Hangzhou 31000058
  • Received:2016-09-22 Revised:2016-10-20 Published:2016-11-03
  • Supported by:

    Project supported by the National Basic Research Program of China (973 Program, No. 2015CB856600) and the National Natural Science Foundation of China (Nos. 21472162, 21573161).

可见光促进利用氧气作为最终氧化剂的氧合反应,具有反应条件温和,环境友好等优点.综述了可见光促进的使用氧气作为氧化剂的均相氧合反应,包括烷烃、烯烃、炔烃、醇、醛和一些其他官能团化合物的氧合反应.

关键词: 可见光, 均相氧合反应, 氧气

Visible-light-promoted oxygenation reactions using dioxygen as a terminal oxidant have the advantage of mild reaction conditions and environmental-friendly. Visible-light-promoted aerobic oxygenation reactions of alkanes, alkenes, alkynes, alcohols, aldehydes and other hetero-atom containing functional groups are reviewed.

Key words: visible light, homogeneous, oxygenation, dioxygen