过渡金属催化1，3-二羰基化合物不对称烯丙基烷基化反应的研究进展

doi:10.6023/cjoc201702013

摘要/Abstract

1，3-二羰基化合物的不对称烯丙基烷基化反应是构筑手性中心的重要方法.综述了过渡金属催化1，3-二羰基化合物不对称烯丙基烷基化反应的进展.按照烯丙基化试剂的不同，主要讨论了以烯丙基酯类、烯丙醇、烯丙基卤化物、烯烃、联烯作为烯丙基化试剂或其他烯丙基化方法合成手性α-烯丙基取代的1，3-二羰基化合物.

关键词: 过渡金属催化, 1, 3-二羰基化合物, 不对称烯丙基烷基化反应

Asymmetric allylic alkylation reaction of 1,3-dicarbonyl compounds is one of the most important methods for forming chiral carbon center. This review summarizes the progress on transition metal-catalyzed asymmetric allylic alkylation reaction of 1,3-dicarbonyl compounds. Different allylating reagents such as allylic esters, allylic alcohols, allylic halides, olefins, allenes and others for the synthesis of α-allyl substituted 1,3-dicarbonyl compounds are discussed.

Key words: transition-metal catalysis, 1,3-dicarbonyl compounds, asymmetric allylic alkylation reaction

引用此文

郑楠, 宋汪泽. 过渡金属催化1，3-二羰基化合物不对称烯丙基烷基化反应的研究进展[J]. 有机化学, 2017, 37(5): 1099-1110.

Zheng Nan, Song Wangze. Progress on Transition Metal-Catalyzed Asymmetric Allylic Alkylation Reaction of 1,3-Dicarbonyl Compounds[J]. Chin. J. Org. Chem., 2017, 37(5): 1099-1110.

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