镍催化均相不对称氢化反应研究进展

doi:10.6023/cjoc201912025

有机化学 ›› 2020, Vol. 40 ›› Issue (5): 1096-1104.DOI: 10.6023/cjoc201912025 上一篇下一篇

所属专题：镍催化有机反应虚拟合辑

综述与进展

镍催化均相不对称氢化反应研究进展

刘元华^a, 董秀琴^a, 张绪穆^b

a 武汉大学化学与分子科学学院生物医用高分子材料教育部重点实验室有机硅化合物及材料教育部工程中心武汉 430072;
b 南方科技大学化学系广东深圳 518055

收稿日期:2019-12-19 修回日期:2020-01-20 发布日期:2020-02-15
通讯作者: 董秀琴 E-mail:xiuqindong@whu.edu.cn
基金资助:
国家自然科学基金（No.21502145）、武汉市青年科技晨光计划（No.2017050300307）和江苏省自然科学基金（No.SBK2019041078）资助项目.

Recent Advances of Nickel-Catalyzed Homogeneous Asymmetric Hydrogenation

Liu Yuanhua^a, Dong Xiu-Qin^a, Zhang Xumu^b

a Key Laboratory of Biomedical Polymers, Engineering Research Center of Organosilicon Compounds & Materials, Ministry of Education, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072;
b Department of Chemistry, Southern University of Science and Technology, Shenzhen, Guangdong 518055

Received:2019-12-19 Revised:2020-01-20 Published:2020-02-15
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21502145), the Wuhan Morning Light Plan of Youth Science and Technology (No. 2017050300307) and the National Natural Science Foundation of Jiangsu Province (No. SBK2019041078).

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摘要/Abstract

过渡金属络合物催化的均相不对称氢化反应是合成手性化合物的重要方法之一，目前主要集中于钌、铑、铱和钯等贵重过渡金属催化体系，这些贵重过渡金属催化体系面临着地球储量有限、价格昂贵和重金属污染环境等问题，因而发展地球储量丰富、价格低廉、无毒或低毒且对环境友好的铁、钴、镍和铜的均相不对称氢化反应催化体系符合现代化学可持续发展的要求和趋势.简要综述了近些年来廉价金属镍催化的均相不对称氢化反应研究领域的新进展，基于前手性不饱和化合物双键的不同类型，即碳-氧双键（C=O）、碳-碳双键（C=C）以及碳-氮双键（C=N）等，依次介绍它们的研究现状，目前已经取得了突破和可观的研究成果，系统地分析了镍催化体系中催化氢化不同类型底物的优势与不足，并展望了未来的研究方向.

关键词: 不对称氢化, 镍催化, 手性双膦配体, 手性化合物, 立体选择性

Transition metal complexes-catalyzed homogeneous asymmetric hydrogenation is an important method for the synthesis of chiral compounds. At present, it is mainly focused on precious transition metal catalytic systems, such as ruthenium, rhodium, iridium and palladium. However, they are suffered from the difficulties of limited resource, high cost and environmental contamination. Therefore, it is important and necessary to develop catalytic systems based on cheap, non-toxic or low toxic, environmentally friendly and earth-abundant iron, cobalt, nickel, copper transition metal, which are in accordance with the requirements and research trend of the sustainable development of modern chemistry. The recent progress of nickel-catalyzed homogeneous asymmetric hydrogenation of prochiral unsaturated compounds containing carbon oxygen double bond (C=O), carbon carbon double bond (C=C) and carbon nitrogen double bond (C=N) is reviewed, and some breakthroughs and considerable research results achieved are introduced. In addition, the advantages and disadvantages of different types of substrates in nickel catalyst system are analyzed, and the future research direction is prospected.

Key words: asymmetric hydrogenation, nickel catalysis, chiral diphosphine ligand, chiral compounds, stereoselectivity

引用此文

刘元华, 董秀琴, 张绪穆. 镍催化均相不对称氢化反应研究进展[J]. 有机化学, 2020, 40(5): 1096-1104.

Liu Yuanhua, Dong Xiu-Qin, Zhang Xumu. Recent Advances of Nickel-Catalyzed Homogeneous Asymmetric Hydrogenation[J]. Chinese Journal of Organic Chemistry, 2020, 40(5): 1096-1104.

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镍催化均相不对称氢化反应研究进展

Recent Advances of Nickel-Catalyzed Homogeneous Asymmetric Hydrogenation

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