具有光活性的铬、钴配合物的设计及其在有机合成中的应用进展

doi:10.6023/cjoc202512031

有机化学 ›› 2026, Vol. 46 ›› Issue (4): 1513-1528.DOI: 10.6023/cjoc202512031 上一篇下一篇

综述与进展

具有光活性的铬、钴配合物的设计及其在有机合成中的应用进展

孟令旭^a, 申霖^a, 罗祥玲^a, 林玉妹^a^,^*(), 龚磊^a^,^b^,^*()

^a 厦门大学化学化工学院福建厦门 361005
^b 福建省能源材料科学与技术创新实验室(IKKEM) 福建厦门 361005

收稿日期:2025-12-22 修回日期:2026-02-02 发布日期:2026-03-06
通讯作者: 林玉妹, 龚磊
基金资助:
国家自然科学基金(22371237); 国家自然科学基金(22571265); 国家自然科学基金(22571263); 福建省自然科学基金(2024J010002); 及大学生创新创业训练计划(202510384058); 及大学生创新创业训练计划(2025X803)

Design of Photoactive Cr- and Co-Based Complexes and Their Applications in Organic Synthesis

Lingxu Meng^a, Lin Shen^a, Xiangling Luo^a, Yumei Lin^a^,^*(), Lei Gong^a^,^b^,^*()

^a College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005
^b Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen, Fujian 361005

Received:2025-12-22 Revised:2026-02-02 Published:2026-03-06
Contact: Yumei Lin, Lei Gong
Supported by:
National Natural Science Foundation of China(22371237); National Natural Science Foundation of China(22571265); National Natural Science Foundation of China(22571263); Natural Science Foundation of Fujian Province(2024J010002); College Students’ Innovative Entrepreneurial Training Plan(202510384058); College Students’ Innovative Entrepreneurial Training Plan(2025X803)

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摘要/Abstract

可见光催化是构建结构多样有机分子的重要方法. 目前, 金属光催化剂以铱、钌等贵金属配合物为主, 相比之下, 铬和钴具有地壳丰度高及价格便宜等优势, 其配合物通过可调控的配位环境和丰富的氧化还原性质, 在光催化有机合成中展现出广阔的应用前景. 系统综述了光活性铬、钴配合物的结构设计及其在各类有机转化中的应用进展, 并简要评述了当前面临的挑战与未来发展方向.

关键词: 可见光催化, 光氧化还原催化, 铬配合物, 钴配合物, 催化有机合成

Visible-light photocatalysis has become a powerful method for constructing structurally diverse organic molecules. Currently, metal-based photocatalysts are predominantly rely on noble-metal complexes of iridium and ruthenium. In contrast, chromium and cobalt offer advantages of earth abundance and low cost, and their complexes, featuring tunable coordination environments and rich redox properties, have shown promising potential in photocatalytic organic synthesis. The structural design of photoactive Cr- and Co-based complexes and their applications in various organic transformations are systematically summarized, and the current challenges and future perspectives in this field are briefly discussed.

Key words: visible-light photocatalysis, photoredox catalysis, chromium complex, cobalt complex, catalytic organic synthesis

引用此文

孟令旭, 申霖, 罗祥玲, 林玉妹, 龚磊. 具有光活性的铬、钴配合物的设计及其在有机合成中的应用进展[J]. 有机化学, 2026, 46(4): 1513-1528.

Lingxu Meng, Lin Shen, Xiangling Luo, Yumei Lin, Lei Gong. Design of Photoactive Cr- and Co-Based Complexes and Their Applications in Organic Synthesis[J]. Chinese Journal of Organic Chemistry, 2026, 46(4): 1513-1528.

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图/表 14

图1. 调控光活性配合物性能的配体设计策略

Figure 1. Ligand design strategies for regulating the performance of photoactive complexes

图2. 联吡啶和菲咯啉类配体的Cr配合物的光物理和电化学性质

Figure 2. Photophysical and electrochemical properties of chromium complexes with bipyridine and phenanthroline ligands

图3. 异氰化物类配体的Cr配合物的光物理和电化学性质

Figure 3. Photophysical and electrochemical properties of chromium complexes with isocyanide ligands

图式1. 光氧化[Cr(Ph2phen)3](BF4)3促进自由基阳离子环加成反应

Scheme 1. Photooxidizing [Cr(Ph2phen)3](BF4)3 for promoting radical cation cycloadditions

图式2. 光氧化[Cr(Ph2phen)3](BF4)3用于二烯烃与缺电子烯烃的[4＋2]环加成反应

Scheme 2. Photooxidizing [Cr(Ph2phen)3](BF4)3 for [4＋2] cycloaddition reactions of dienes with electron-deficient olefins

图式3. 通过[Cr(Ph2phen)3](BF4)3进行的自由基阳离子环丙烷化反应

Scheme 3. Radical cation cyclopropanations via [Cr(Ph2phen)3](BF4)3

图式4. 通过[Cr(Ph2phen)3](BF4)3进行的自由基阳离子环丙烷化反应

Scheme 4. Radical cation cyclopropanations via [Cr(Ph2phen)3](BF4)3

图式5. 吲哚与乙烯基重氮物种之间的去芳构化[3＋2]环加成反应

Scheme 5. Dearomative [3＋2] cycloadditions between indoles and vinyldiazo species

图式6. 可见光诱导的氧化C—H键氰基化反应及光化学促进的aza-Diels-Alder反应

Scheme 6. Visible light-induced oxidative C—H bond cyanogenation and photochemically promoted aza-Diels-Alder-type reaction

图式7. 可见光诱导下Cr(III)光催化剂催化SO2固定合成砜或磺酰胺

Scheme 7. Visible-light mediated fixation of SO2 into sulfones or sulfonamides with Cr(III) photocatalysts

图4. Co配合物的光物理和电化学性质

Figure 4. Photophysical and electrochemical properties of cobalt complexes

图式8. 光催化多环芳烃的三氟甲基化反应

Scheme 8. Photocatalytic trifluoromethylation of polycyclic aromatic hydrocarbons

图式9. 钴光催化芳基酰胺与芳基硼酸的C(sp2)—N交叉偶联反应

Scheme 9. Cobalt photocatalyzed C(sp2)—N cross-coupling of aryl amides and aryl boronic acids

图式10. 钴光催化芳基卤代物与吡咯的偶联反应

Scheme 10. Cobalt photocatalyzed coupling reaction of aryl halides with pyrroles

参考文献 29

[30]	Wegeberg, C.; Häussinger, D.; Wenger, O. S. J. Am. Chem. Soc. 2021, 143, 15800.
[31]	Yang, Y.; Liu, Q.; Zhang, L.; Yu, H.; Dang, Z. Organometallics 2017, 36, 687.
[32]	Britton, L.; Skrodzki, M.; Nichol, G. S.; Dominey, A. P.; Pawluć P.; Docherty, J. H.; Thomas, S. P. ACS Catal. 2021, 11, 6857.
[33]	Huang, T.; Du, P.; Cheng, X.; Lin, Y.-M. J. Am. Chem. Soc. 2024, 146, 24515.
[34]	Jamatia, R.; Mondal, A.; Srimani, D. Adv. Synth. Catal. 2021, 363, 2969.
[35]	Laru, S.; Bhattacharjee, S.; Hajra, A. Chem. Commun. 2022, 58, 13604.
[36]	Liu, R.-Z.; Li, J.; Sun, J.; Liu, X.-G.; Qu, S.; Li, P.; Zhang, B. Angew. Chem.,Int. Ed. 2020, 59, 4428.
[37]	Nuhant, P.; Oderinde, M. S.; Genovino, J.; Juneau, A.; Gagné Y.; Allais, C.; Chinigo, G. M.; Choi, C.; Sach, N. W.; Bernier, L.; Fobian, Y. M.; Bundesmann, M. W.; Khunte, B.; Frenette, M.; Fadeyi, O. O. Angew. Chem.,Int. Ed. 2017, 56, 15309.
[1]	Arias-Rotondo, D. M. Nat. Chem. 2022, 14, 716.
[2]	Beatty, J.; Stephenson, C. Acc. Chem. Res. 2015, 48, 1474.
[3]	Corrigan, N.; Shanmugam, S.; Xu, J.; Boyer, C. Chem. Soc. Rev. 2016, 45, 6165.
[4]	DiLuzio, S.; Connell, T.; Mdluli, V.; Kowalewski, J.; Bernhard, S. J. Am. Chem. Soc. 2022, 144, 1431.
[5]	Fu, X.; Liang, H.; Wei, Z.; Liu, G.; Hong, C.; Qiu, H.; Kang, Z.; Hu, W. Green Synth. Catal. 2025, https:/doi.org/10.1016/j.gresc.2025.11.005.
[6]	Koike, T.; Akita, M. Inorg. Chem. Front. 2014, 1, 562.
[7]	Larsen, C.; Wenger, O. S. Chem.-Eur. J. 2018, 24, 2039.
[8]	Ma, X.; Zhang, Y.; Cai, X.; Xu, H.; Huang, L.; Huo, H.; Shu, C. Green Synth. Catal. 2025, https:/doi.org/10.1016/j.gresc.2025.07.005.
[9]	Mi, X.; Wang, C.; Zhang, J.; Chauvin, R.; Cui, X. Chin. Chem. Lett. 2025, 36, 111485.
[38]	Auböck, G.; Chergui, M. Nat. Chem. 2015, 7, 629.
[39]	Aydogan, A.; Bangle, R. E.; De Kreijger, S.; Dickenson, J. C.; Singleton, M. L.; Cauët, E.; Cadranel, A.; Meyer, G. J.; Elias, B.; Sampaio, R. N.; Troian-Gautier, L. Catal. Sci. Technol. 2021, 11, 8037.
[40]	Bansal, A.; Kumar, P.; Sharma, C. D.; Ray, S. S.; Jain, S. L. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 2739.
[41]	Büldt, L. A.; Guo, X.; Vogel, R.; Prescimone, A.; Wenger, O. S. J. Am. Chem. Soc. 2017, 139, 985.
[42]	de Groot, L. H. M.; García-Mateos, C.; Johnson, C. E.; Freyr Hlynsson, V.; Sharma, A. K.; Lomoth, R.; Wärnmark, K. Chem.- Eur. J. 2025, 31, e202500409.
[43]	Ilic, A.; Schwarz, J.; Johnson, C.; de Groot, L. H. M.; Kaufhold, S.; Lomoth, R.; Wärnmark, K. Chem. Sci. 2022, 13, 9165.
[44]	Ilic, A.; Strücker, B. R.; Johnson, C. E.; Hainz, S.; Lomoth, R.; Wärnmark, K. Chem. Sci. 2024, 15, 12077.
[10]	Narayanam, J.; Stephenson, C. Chem. Soc. Rev. 2011, 40, 102.
[11]	Wang, Q.; Wang, Y.; Liu, M.; Chu, G.; Qiu, Y. Chin. J. Chem. 2024, 42, 2249.
[12]	Wang, T.; Cao, J.; Li, J.; Li, D.; Ao, Z. Chin. Chem. Lett. 2025, 36, 110078.
[13]	Wenger, O. S. J. Am. Chem. Soc. 2018, 140, 13522.
[14]	Wenger, O. S. Nat. Chem. 2020, 12, 323.
[15]	Xie, J.; Jin, H.; Xu, P.; Zhu, C. Tetrahedron Lett. 2014, 55, 36.
[16]	Zimmerman, J.; Anastas, P.; Erythropel, H.; Leitner, W. Science 2020, 367, 397.
[17]	Holmberg-Douglas, N.; Nicewicz, D. A. Chem. Rev. 2022, 122, 1925.
[18]	Li, J.; Zhao, J.; Loh, T. Synlett 2024, 35, 840.
[19]	Prier, C.; Rankic, D.; MacMillan, D. Chem. Rev. 2013, 113, 5322.
[45]	Jang, Y. J.; An, H.; Choi, S.; Hong, J.; Lee, S. H.; Ahn, K.-H.; You, Y.; Kang, E. J. Org. Lett. 2022, 24, 4479.
[46]	Lindroth, R.; Ondrejková A.; Wallentin, C.-J. Org. Lett. 2022, 24, 1662.
[47]	Liu, H.; Lei, Y.; Tian, P.; Wang, H.; Zhao, X.; Li, Z.; Zhang, D. J. Mater. Chem. A 2021, 9, 6361.
[48]	Parisien-Collette, S.; Hernandez-Perez, A. C.; Collins, S. K. Org. Lett. 2016, 18, 4994.
[49]	Chi, Z.; Liao, J.; Cheng, X.; Ye, Z.; Yuan, W.; Lin, Y.; Gong, L. J. Am. Chem. Soc. 2024, 146, 10857.
[50]	Märsch, J.; Reiter, S.; Rittner, T.; Rodriguez-Lugo, R.; Whitfield, M.; Scott, D.; Kutta, R.; Nuernberger, P.; de Vivie-Riedle, R.; Wolf, R. Angew. Chem., Int. Ed. 2024, 63, e202405780.
[51]	Pal, A.; Li, C.; Hanan, G.; Zysman-Colman, E. Angew. Chem., Int. Ed. 2018, 57, 8027.
[20]	Ramani, A.; Desai, B.; Dholakiya, B.; Naveen, T. Chem. Commun. 2022, 58, 7850.
[21]	Arai, N.; Ohkuma, T. J Org. Chem. 2017, 82, 7628.
[22]	Gall, B. K.; Smith, A. K.; Ferreira, E. M. Angew. Chem., Int. Ed. 2022, 61, e202212187.
[23]	Higgins, R. F.; Fatur, S. M.; Damrauer, N. H.; Ferreira, E. M.; Rappé A. K.; Shores, M. P. ACS Catal. 2018, 8, 9216.
[24]	Higgins, R. F.; Fatur, S. M.; Shepard, S. G.; Stevenson, S. M.; Boston, D. J.; Ferreira, E. M.; Damrauer, N. H.; Rappé A. K.; Shores, M. P. J. Am. Chem. Soc. 2016, 138, 5451.
[25]	Otto, S.; Nauth, A. M.; Ermilov, E.; Scholz, N.; Friedrich, A.; Resch-Genger, U.; Lochbrunner, S.; Opatz, T.; Heinze, K. Chem- PhotoChem 2017, 1, 344.
[26]	Sarabia, F. J.; Ferreira, E. M. Org. Lett. 2017, 19, 2865.
[27]	Sarabia, F. J.; Li, Q.; Ferreira, E. M. Angew. Chem., Int. Ed. 2018, 57, 11015.
[52]	Chavda, H.; Liang, K.; Megna, T.; Taylor, O.; Kim, G.; López, A.; Bahamonde, A. ACS Catal. 2025, 15, 10760.
[53]	Dai, L.; Shen, C.; Wang, J.; Li, Y.; Dong, K. Angew. Chem., Int. Ed. 2025, 64, e202505719.
[54]	Li, J.; Wang, P.; Bai, B.; Xiao, Y.; Wan, Y.; Yan, Y.; Li, F.; Song, G.; Li, G.; Wang, C.; Zhang, X.; Dong, J.; Kang, T.; Xue, D. J. Am. Chem. Soc. 2025, 147, 5851.
[55]	Ni, S.; Halder, R.; Ahmadli, D.; Reijerse, E.; Cornella, J.; Ritter, T. Nat. Catal. 2024, 7, 733.
[56]	Cui, M.; Wang, D.; Guo, J.; Dai, M.; Sun, M. Y.; Li, Z.; Wun, C. K. T.; Bachmann, S.; Chow, W. Y.; Lo, T. W. B.; Zhou, M.; Xu, W. W.; He, J. J. Am. Chem. Soc. 2025, 147, 32982.
[57]	Cai, Y.; Dawor, M.; Gaurav, G.; Ritter, T. J Am Chem Soc. 2025, 147, 18438.
[58]	Caron, A.; Morin, É.; Collins, S. K. ACS Catal. 2019, 9, 9458.
[59]	Hossain, A.; Bhattacharyya, A.; Reiser, O. Science 2019, eaav9713.
[60]	Li, S.; Li, J.; Zhang, H.; Zhang, G.; Guo, R. Org. Lett. 2025, 27, 5057.
[61]	Sardana, S.; Pattanaik, A.; Rehbein, J.; Reiser, O Angew. Chem., Int. Ed. 2025, 64, e202509658.
[62]	Shen, X.; Chen, X.; Xiao, Y.; Brown, J. B.; Zhang, J. G.; Ji, X.; Rui, J.; Garcia-Borràs, M.; Rao, Y.; Yang, Y.; Huang, X. Science 2025, 389, 741.
[63]	Zhong, F.; Anderson, R. L.; Oyala, P. H.; Fu, G. C. J. Am. Chem. Soc. 2025, 147, 32963.
[64]	Dierks, P.; Vukadinovic, Y.; Bauer, M. Inorg. Chem. Front. 2022, 9, 206.
[65]	Kitzmann, W.; Heinze, K. Angew. Chem., Int. Ed. 2023, 62, e202213207.
[66]	Wenger, O. S. Chem.-Eur. J. 2019, 25, 6043.
[67]	Sinha, N.; Wenger, O. S. J. Am. Chem. Soc. 2023, 145, 4903.
[68]	Wegeberg, C.; Wenger, O. S. JACS Au 2021, 1, 1860.
[69]	Gong, Z.; Zhang, H.; Cheng, Y.; Liu, J.; Ai, Y.; Li, Y.; Feng, Z.; Zhang, Q.; Gong, S.; Chen, Y.; Yao, C.; Zhu, Y.; Xu, L.; Zhong, Y. Sci. China: Chem. 2025, 68, 46.
[70]	Zhou, W.; Thompson, J. R.; Leznoff, C. C.; Leznoff, D. B. Chem.- Eur. J. 2016, 23, 2323.
[71]	Bories, C. C.; Sodreau, A.; Barbazanges, M.; Petit, M. Organometallics 2024, 43, 895.
[72]	Planes, O. M.; Scopelliti, R.; Fadaei‐Tirani, F.; Severin, K. Z. Anorg. Chem. 2021, 647, 1065.
[73]	Wang, B.; Lee, Y.-M.; Tcho, W.-Y.; Tussupbayev, S.; Kim, S.-T.; Kim, Y.; Seo, M. S.; Cho, K.-B.; Dede, Y.; Keegan, B. C.; Ogura, T.; Kim, S. H.; Ohta, T.; Baik, M.-H.; Ray, K.; Shearer, J.; Nam, W. Nat. Commun. 2017, 8, 14839.
[74]	Morselli, G.; Reber, C.; Wenger, O. S. J. Am. Chem. Soc. 2025, 147, 11608.
[75]	Sinha, N.; Pfund, B.; Wegeberg, C.; Prescimone, A.; Wenger, O. S. J. Am. Chem. Soc. 2022, 144, 9859.
[76]	Sinha, N.; Yaltseva, P.; Wenger, O. S. Angew. Chem., Int. Ed. 2023, 62, e202303864.
[77]	Yaltseva, P.; Maisuradze, T.; Prescimone, A.; Kupfer, S.; Wenger, O. S. J. Am. Chem. Soc. 2025, 147, 29444.
[78]	Kumar, N.; Sharma, T.; Thakur, N.; Jain, R.; Sinha, N. Chem.-Eur. J. 2025, 31, e202500365.
[79]	Singh, P. P.; Sinha, S.; Singh, J.; Singh, P. K.; Srivastava, V. ChemistrySelect 2025, 10, e03155.
[80]	Serpone, N.; Jamieson, M. A.; Henry, M. S.; Hoffman, M. Z.; Bolletta, F.; Maestri, M. J. Am. Chem. Soc. 1979, 101, 2907.
[81]	Wang, Z.; Li, M.; Zuo, W. J. Am. Chem. Soc. 2024, 146, 26416.
[82]	Huang, T.; Du, P.; Lin, Y. Chin. J. Chem. 2025, 43, 2566.
[83]	Cebrián, C.; Pastore, M.; Monari, A.; Assfeld, X.; Gros, P.; Haacke, S. ChemPhysChem 2022, 23, e202100659.
[84]	Chábera, P.; Kjaer, K.; Prakash, O.; Honarfar, A.; Liu, Y.; Fredin, L.; Harlang, T.; Lidin, S.; Uhlig, J.; Sundström, V.; Lomoth, R.; Persson, P.; Warnmark, K. J. Phys. Chem. Lett. 2018, 9, 459.
[85]	de Groot, L.; Ilic, A.; Schwarz, J.; Waernmark, K. J. Am. Chem. Soc. 2023, 145, 9369.
[86]	Dierks, P.; Kruse, A.; Bokareva, O.; Al-Marri, M.; Kalmbach, J.; Baltrun, M.; Neuba, A.; Schoch, R.; Hohloch, S.; Heinze, K.; Seitz, M.; Kühn, O.; Lochbrunner, S.; Bauer, M. Chem. Commun. 2021, 57, 6640.
[87]	Forster, L. Coord. Chem. Rev. 2006, 250, 2023.
[88]	Harlang, T.; Liu, Y.; Gordivska, O.; Fredin, L.; Ponseca, C.; Huang, P.; Chábera, P.; Kjaer, K.; Mateos, H.; Uhlig, J.; Lomoth, R.; Wallenberg, R.; Styring, S.; Persson, P.; Sundström, V.; Wärnmark, K. Nat. Chem. 2015, 7, 883.
[89]	Heinze, K. Nat. Chem. 2021, 13, 926.
[90]	Heinze, K.; Reinhart, A. Dalton Trans. 2008, 469.
[91]	Kaufhold, S.; Rosemann, N.; Chábera, P.; Lindh, L.; Losada, I.; Uhlig, J.; Pascher, T.; Strand, D.; Wärnmark, K.; Yartsev, A.; Persson, P. J. Am. Chem. Soc. 2021, 143, 1307.
[92]	Kaul, N.; Asempa, E.; Valdez-Moreira, J.; Smith, J.; Jakubikova, E.; Hammarström, L. J. Am. Chem. Soc. 2024, 146, 24619.
[93]	Kenney, J.; Boone, D.; Striplin, D.; Chen, Y.; Hamar, K. Organometallics 1993, 12, 3671.
[94]	Kjmer, K.; Kaul, N.; Prakash, O.; Chábera, P.; Rosemann, N.; Honarfar, A.; Gordivska, O.; Fredin, L.; Bergquist, K.; Häggstrom, L.; Ericsson, T.; Lindh, L.; Yartsev, A.; Styring, S.; Huang, P.; Uhlug, J.; Bendix, J.; Strand, D.; Sundstrom, V.; Persson, P.; Lomoth, R.; Wärnmark, K. Science 2019, 363, 249.
[95]	Larsen, C.; Braun, J.; Lozada, I.; Kunnus, K.; Biasin, E.; Kolodziej, C.; Burda, C.; Cordones, A.; Gaffney, K.; Herbert, D. J. Am. Chem. Soc. 2021, 143, 20645.
[96]	Leis, W.; Cordero, M.; Lochbrunner, S.; Schubert, H.; Berkefeld, A. J. Am. Chem. Soc. 2022, 144, 1169.
[97]	Liang, Y.; Steinbock, R.; Yang, L.; Ackermann, L. Angew. Chem., Int. Ed. 2018, 57, 10625.
[98]	Lindh, L.; Gordivska, O.; Persson, S.; Michaels, H.; Fan, H.; Chábera, P.; Rosemann, N.; Gupta, A.; Benesperi, I.; Uhlig, J.; Prakash, O.; Sheibani, E.; Kjaer, K.; Boschloo, G.; Yartsev, A.; Freitag, M.; Lomoth, R.; Persson, P.; Wärnmark, K. Chem. Sci. 2021, 12, 16035.
[99]	Liu, L.; Duchanois, T.; Etienne, T.; Monari, A.; Beley, M.; Assfeld, X.; Haacke, S.; Gros, P. Phys. Chem. Chem. Phys. 2016, 18, 12550.
[100]	Liu, Y.; Harlang, T.; Canton, S.; Chábera, P.; Suárez-Alcántara, K.; Fleckhaus, A.; Vithanage, D.; Göransson, E.; Corani, A.; Lomoth, R.; Sundström, V.; Wärnmark, K. Chem. Commun. 2013, 49, 6412.
[101]	Liu, Y.; Kjær, K.; Fredin, L.; Chábera, P.; Harlang, T.; Canton, S.; Lidin, S.; Zhang, J.; Lomoth, R.; Bergquist, K.; Persson, P.; Wärnmark, K.; Sundström, V. Chem.-Eur. J. 2015, 21, 3628.
[102]	London, H.; Whittemore, T.; Gale, A.; McMillen, C.; Pritchett, D.; Myers, A.; Thomas, H.; Shields, G.; Wagenknecht, P. Inorg. Chem. 2021, 60, 14399.
[103]	Long, W.; Lian, P.; Li, J.; Wan, X. Org. Biomol. Chem. 2020, 18, 6483.
[104]	Duchanois, T.; Etienne, T.; Beley, M.; Assfeld, X.; Perpète, E.; Monari, A.; Gros, P. Eur. J. Inorg. Chem. 2014, 2014, 3747.
[105]	Fatur, S.; Shepard, S.; Higgins, R.; Shores, M.; Damrauer, N. J. Am. Chem. Soc. 2017, 139, 4493.
[106]	Förster, C.; Heinze, K. Chem. Soc. Rev. 2020, 49, 1057.
[107]	Hockin, B.; Li, C.; Robertson, N.; Zysman-Colman, E. Catal. Sci. Technol. 2019, 9, 889.
[108]	Marri, A.; Marekha, B.; Penfold, T.; Haacke, S.; Gros, P. Inorg. Chem. Front. 2022, 10, 118.
[109]	McCusker, J. Science 2019, 363, 484.
[110]	McCusker, J.; Walda, K.; Dunn, R.; Simon, J.; Magde, D.; Hendrickson, D. J. Am. Chem. Soc. 1993, 115, 298.
[111]	Monat, J.; McCusker, J. J. Am. Chem. Soc. 2000, 122, 4092.
[112]	Mourao, H.; Gomes, C.; Realista, S.; Royo, B. Appl. Organomet. Chem. 2024, 38, e6846.
[113]	McDaniel, A. M.; Tseng, H.-W.; Damrauer, N. H.; Shores, M. P. Inorg. Chem. 2010, 49, 7981.
[114]	Stevenson, S. M.; Shores, M. P.; Ferreira, E. M. Angew. Chem., Int. Ed. 2015, 54, 6506.
[115]	Sinha, N.; Wegeberg, C.; Häussinger, D.; Prescimone, A.; Wenger, O. S. Nat. Chem. 2023, 15, 1730.
[116]	Burton, S. T.; Lee, G.; Moore, C. E.; Sevov, C. S.; Turro, C. J. Am. Chem. Soc. 2025, 147, 13315.
[117]	Chan, A.; Ghosh, A.; Yarranton, J.; Twilton, J.; Jin, J.; Arias-Rotondo, D.; Sakai, H.; McCusker, J.; MacMillan, D. Science 2023, 382, 191.
[28]	Sittel, S.; Sell, A. C.; Hofmann, K.; Wiedemann, C.; Nau, J. P.; Kerzig, C.; Manolikakes, G.; Heinze, K. ChemCatChem 2023, 15, e202201562.
[29]	Stevenson, S. M.; Higgins, R. F.; Shores, M. P.; Ferreira, E. M. Chem. Sci. 2017, 8, 654.

具有光活性的铬、钴配合物的设计及其在有机合成中的应用进展

Design of Photoactive Cr- and Co-Based Complexes and Their Applications in Organic Synthesis

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