铁催化电化学转化研究进展

doi:10.6023/cjoc202602024

摘要/Abstract

近年来, 有机电化学因其具有条件温和、绿色高效的优点, 得到了快速发展. 与此同时, 铁催化剂因其成本低廉、储量丰富且价态、自旋态多变可调, 有效弥补了传统贵金属催化剂价格高、可持续性差的不足. 铁催化电化学转化的发展, 为现代有机合成化学提供了绿色、高效且可持续的合成工具, 目前已广泛应用于氧化、还原及偶联等各类反应体系中. 本文综述了该领域的最新研究进展, 总结了铁催化氧化反应、还原反应以及氧化还原配对反应三类反应体系, 阐述了相应的催化机制和代表性反应, 并对铁催化的电化学转化进行了展望.

关键词: 铁催化, 有机电化学, 氧化还原反应

In recent years, organic electrochemistry has developed rapidly due to its mild conditions, environmental friendliness and high efficiency. Meanwhile, iron catalysts have effectively compensated for the high cost and poor sustainability of traditional noble-metal catalysts due to their low price, abundant reserves, and tunable of their valence and spin states. The development of iron-catalyzed electrochemical transformations has provided green, efficient, and sustainable synthetic tools for modern organic synthesis. Presently, such strategies have been widely applied in various reaction systems including oxidation, reduction, and coupling reactions. This review summarizes the latest advances in this field, focusing on three categories of iron-catalyzed electrochemical reactions: oxidative, reductive, and redox-paired transformations. The corresponding catalytic mechanisms and representative reactions are discussed, and an outlook on iron-catalyzed electrochemical transformations is also provided.

Key words: iron catalysis, organic electrochemistry, redox reaction

引用此文

杨林静, 赵志伟, 石安仔, 杨国庆, 仇友爱. 铁催化电化学转化研究进展[J]. 有机化学, doi: 10.6023/cjoc202602024.

Yang Linjing, Zhao Zhiwei, Shi Anzai, Yang Guoqing, Qiu Youai. Advances in iron-catalyzed electrochemical transformations[J]. Chinese Journal of Organic Chemistry, doi: 10.6023/cjoc202602024.

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