有机化学 ›› 1997, Vol. 17 ›› Issue (4): 370-373. 上一篇    下一篇

研究论文

应用亲核性离子交换树脂(PhS^-型)制备苯硫醚

张万轩;王卫仁;钟建华;黄锦霞;陈家威   

  1. 湖北大学化学系
  • 发布日期:1997-08-25

Synthesis of phenyl sulfides by using nucleophilic ion exchange resin (PhS^-)

ZHANG WANXUAN;WANG WEIREN;ZHAONG JIANHUA;HUANG JINXIA;CHEN JIAWEI   

  • Published:1997-08-25

用强碱性离子交换树脂(^-OH型)与PhSH反应,得到一种离子交换树脂支载的PhS^-试剂,它与卤代物和α,β-不饱和醛酮很容易反应,得到相应的苯硫醚,产率较高或中等。

关键词: 不饱和化合物, 卤化物, 不饱和醛, 苯硫酚, 离子交换树脂, 有机合成, 硫醚 P

Strongly basic exchange resin (^-OH) reacted with PhSH giving a nucleophilic ion exchange resin (PhS^-), it readily reacted with halides or α,β-unsaturated aldehydes and ketones to give phenyl alkyl sulfides in moderate to good yields.

Key words: ION EXCHANGE RESINS, UNSATURATED COMPOUND, BENZENETHIOL, UNSATURATED ALDEHYDE, ORGANIC SYNTHESIS, SULFUR ETHER P, HALIDE

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