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有机化学
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有机化学 ›› 1998, Vol. 18 ›› Issue (2): 119-123. 上一篇    下一篇

研究论文

新型膦酰基取代的脂环化合物的合成研究及手性拆分

王永梅;张慧萍;卫芳;李金亮;王磊;孟继本   

  1. 南开大学化学系;云南师范大学化学系
  • 发布日期:1998-04-25

Synthesis of some new phoshonyl substituted alicyclic compounds and enantiomer resolution

WANG YONGMEI;ZHANG HUIPING;WEI FANG;LI JINLIANG;WANG LEI;MENG JIBEN   

  • Published:1998-04-25

被引次数

6

研究了二(二苯基氧化膦)乙炔同取代环戊二烯的Diels-Alder反应，合成了四个新型有机膦脂环化合物，并用^1H NMR，MS和元素分析确定了它们的结构，同时以(±)-二苯甲酰酒石酸为拆分剂，对外消旋9,10-二氢-9,10-亚乙烯基-2,3-苯并蒽-11,12-二(二苯基氧化膦)进行了拆分，得到了两个有光学活性的产物。

关键词: 消旋体拆分, 酒石酸 P, 乙炔 P, 手征性, 有机磷化合物, 有机合成, 二苯基, 环戊二烯 P, 二苯基, 环加成反应

In this article Diels-Alder reaction of ethyldiyl-bis(diphenyl phosphine oxide) with substituted cyclopentadiene was studied. Four new organophosphorous ring compounds were synthesized. By using (±)-dibenzoyltartaric acid as the resolution agent, racemic 9,10-dihydro-9,10-etheno-2,3-benzoanthracene-11,12-bis (diphenyl phosphine oxide) was resolved and two optical activity products were obtained.

Key words: MESOTOMY, ACETYLENE P, TARTARIC ACID P, CYCLOPENTADIENE P, CHIRALITY, DIPHENYL GROUP, ORGANIC SYNTHESIS, CYCLOADDITION REACTION, DIPHENYL GROUP, ORGANO PHOSPHORUS COMPOUNDS

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