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有机化学
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有机化学 ›› 2002, Vol. 22 ›› Issue (1): 1-10. 上一篇    下一篇

研究论文

低价钒试剂促进的有机反应及其在有机合成中的应用

范学森;张永敏;张永敏   

  1. 河南师范大学化学系.新湘(453002);浙江大学西溪校区化学系.杭州(310027)
  • 发布日期:2002-01-25

Organic reactions mediated by low-valent vanadium reagents and their applications in organic synthesis

Fan Xuesen;Zhang Yongmin;Zhang Yongmin   

  1. Henan Normal Univ, Dept Chem.Xinxiang(453002);Zhejiang Univ, Xixi campus, Dept of chem.Hangzhou(310027);Shanghai Inst Organ Chem., CAS. Shanghai(200032)
  • Published:2002-01-25

PDF

589

被引次数

4

综述了近年来低价钒试剂促进的有机反应及其在有机合成中的应用。重点讨论了低价钒试剂促进下的碳-碳键的形成反应，如卤代烃的还原偶联、醛(酮)的还原偶联、羰基化合物的脱氧烷基化及脱氧偶联反应等。另外，还介绍了催化量的低价钒度剂在促进有机反应方面的应用。

关键词: 钒试剂, 促进剂, 碳-碳键, 钒化合物, 有机钒化合物, 化学反应, 有机合成

Some organic reactions mediated by low-valent vanadium reagents and their applications in organic synthesis are reviewed with an emphasis on the carbon-carbon bond formation reactions such as reuctive coupling of alkyl halides, reductive coupling of aldehydes and ketones, deoxygenative alkylation and deoxygenatie coupling of carbonyl compounds. Those reactions that are mediated by catalytic amounts of low-valent vanadium reagents are given special attention.

Key words: CARBON-CARBON BOND, VANADIUM COMPOUNDS, CHEMICAL REACTION, ORGANIC SYNTHESIS, ACCELERATORS

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