有机化学 ›› 2002, Vol. 22 ›› Issue (2): 91-100. 上一篇    下一篇

研究论文

冠醚的分子设计及其识别性质研究进展

刘育;张衡益   

  1. 南开大学化学系.天津(300071)
  • 发布日期:2002-02-25

Progress in molecular design and recognition of crown ethers

Liu Yu;Zhang Hengyi   

  1. Department of Chemistry, Nankai University.Tianjin(300071)
  • Published:2002-02-25

综述了冠醚化学研究的最新进展:包括低对称冠醚、臂式冠醚、双冠醚等的分 子设计和离子键合、离子识别的热力学起源和分子组装的研究进展。

关键词: 冠醚, 分子, 离子, 识别, 焓, 熵, 补偿, 组装

This article describes the research progress of crown ether chemistry in recent years, including molecular design and cation binding of low symmetric crown ethers, lariat ethers, bis (crown ether) s, thermodynamic origin of ion recognition, and molecular assembly.

Key words: CROWN ETHER;MOLECULAR;IONS;IDENTIFICATION;ENTHALPY;ENTROPY, COMPENSATION;ASSEMBLING

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