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有机化学
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有机化学 ›› 2006, Vol. 26 ›› Issue (05): 618-626. 上一篇    下一篇

综述与进展

有机小分子催化的不对称羟醛缩合反应

姜丽娟1，张兆国*,1,2   

  1. (1上海交通大学化学化工学院 上海 200240)
    (2中国科学院上海有机化学研究所金属有机化学国家重点实验室 上海 200032)
  • 收稿日期:2005-09-13 修回日期:2005-10-27 发布日期:2006-04-28
  • 通讯作者: 张兆国

Small Organic Molecules Catalyzed Asymmetric Aldol Reaction

JIANG Li-Juan1,ZHANG Zhao-Guo*,1,2   

  1. (1 College of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240)
    (1 State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry,
    Chinese Academy of Sciences, Shanghai 200032)
  • Received:2005-09-13 Revised:2005-10-27 Published:2006-04-28
  • Contact: ZHANG Zhao-Guo

PDF

2900

被引次数

21

总结了近年来用于不对称催化羟醛缩合反应的各种有机小分子催化剂, 简要阐述了每种类型的催化剂的催化机理以及它们的优缺点, 同时对有机小分子催化反应的发展进行了展望.

关键词: 有机小分子, 不对称催化, 羟醛缩合反应

Small organic molecules catalyzed asymmetric aldol reaction is reviewed. The characteristics of the catalysts and the catalytic mechanism involved in the asymmetric induction are briefly summarized, and small molecules catalyzed asymmetric reaction is prospected.

Key words: asymmetric catalysis, aldol reaction, small organic molecules