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有机化学
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有机化学 ›› 2007, Vol. 27 ›› Issue (12): 1479-1490. 上一篇    下一篇

综述与进展

聚合物负载的手性联二萘酚的合成及其在不对称催化中的应用进展

袁小亚*,a,b，张政朴b   

  1. (a重庆交通大学理学院 重庆 400074)
    (b南开大学高分子化学研究所 功能高分子材料教育部重点实验室 天津 300071)
  • 收稿日期:2006-10-16 修回日期:2007-03-19 发布日期:2007-12-04
  • 通讯作者: 袁小亚

Polymer-Supported 1,1'-Bi-2-naphthol: Synthesis and Application in Asymmetric Catalysis

YUAN Xiao-Ya*,a,b, ZHANG Zheng-Pub   

  1. (a College of Science, Chongqing Jiaotong University, Chongqing 400074)
    (b Key Laboratory of Functional Polymer Materials, Ministry of Education,
    Institute of Polymer Chemistry, Nankai University, Tianjin 300071)
  • Received:2006-10-16 Revised:2007-03-19 Published:2007-12-04
  • Contact: YUAN Xiao-Ya

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被引次数

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作为一种有机配体, 手性1,1'-联二萘酚(BINOL)被广泛应用于过渡金属催化的均相不对称有机反应. 为克服均相催化剂不易回收重复使用等缺陷, 人们深入研究了聚合物负载手性BINOL催化剂的方法. 总结了近年来聚合物负载手性BINOL催化剂的合成及其在不对称有机催化中的应用, 并对负载型BINOL催化剂进行了展望.

关键词: 1,1'-联二萘酚, 负载, 不对称催化

Chiral 1,1'-bi-2-naphthol (BINOL) has been extensively studied as a ligand in transition-metal- catalyzed asymmetric organic reaction. To overcome the difficulty to recover and reuse the homogeneous chiral catalysts, polymer-supported chiral BINOL catalysts were significantly explored. A comprehensive review on the recent development of the synthesis of polymer-immobilized BINOL and its application in asymmetric catalysis is given in this paper and polymer-supported BINOL catalysts are also prospected.

Key words: immobilization, asymmetric catalysis, 1,1'-bi-2-naphthol